中文
Earlier issues
Announcement
More
Progress in Chemistry 2010, Vol. 22 Issue (01): 248-254 Previous Articles   

• Invited Article •

The Study of Adsorption of Hydrogen on Zeolites

Du Xiaoming1; Li Jing2; Wu Erdong2*   

  1. (1. School of Materials Science and Engineering, Shenyang Ligong University, Shenyang 110159, China;
    2. Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 , China)
  • Received: Revised: Online: Published:
  • Contact: Wu Erdong E-mail:ewu@imr.ac.cn
PDF ( 2470 ) Cited
Export

EndNote

Ris

BibTeX

Microporous zeolites as media for hydrogen storage have been paid more and more attention in recent years. However, the reports on hydrogen adsorption mechanism, hydrogen storage capacity of the materials and its relevant factors are quite controversial. In this review, the results of adsorption experiments as well as theoretical modeling for hydrogen storage of various structure-type zeolites are briefly reviewed. The influence of many factors on hydrogen storage capacity is emphatically analyzed, such as the zeolitic structures, Si/Al ratio, type of cations in zeolites and the difference of adsorption experimental conditions, etc. And the progress of supercritical adsorption theory models also is discussed. Finally, the possibility and the research trend of zeolites for hydrogen storage are discussed.

Contents
1 Introduction
2 Zeolite structures
3 Supercritical adsorption of hydrogen on zeolites
3.1 Progress of experimental study
3.2 Progress of theoretical modeling
4 Encapsulation of hydrogen in zeolites
5 Conclusion

Key words: zeolites, hydrogen storage, adsorption

CLC Number: 

[ 1 ] 　ZüttelA, Sudan P, Maurona P, et al. Int. J. Hydrogen Energy,2002, 27: 203—212
[ 2 ] 　周亚平( Zhou Y P) , 冯奎( Feng K) , 周理( Zhou L)等. 化学进展( Progress in Chemistry) , 2003, 15 (5) : 345—350
[ 3 ] 　Radhakrishnan R, Gubbins K E, Watanabe A, et al. J. Chem.Phys. , 1999, 111: 9058—9067
[ 4 ] 　周理( Zhou L) , 周亚平( Zhou Y P) . 中国科学B辑( Science in China, SeriesB) , 1996, 26 (5) : 473—480
[ 5 ] 　Darkrim F L, Malbrunot P, Tartaglia G P. Int. J. Hydrogen Energy, 2002, 27: 193—202
[ 6 ] 　Chambers A, Park C, Baker R T K, et al. J. Phys. Chem. B,1998, 102: 4253—4256
[ 7 ] 　Weitkamp J, Fritz M, Ernst S. Int. J. Hydrogen Energy, 1995,20: 967—970
[ 8 ] 　Nijkamp M G, Raaymakers J EM J, van Dillen A J, et al. App l. Phys. A: Materials Science and Processing, 2001, 72:619—623
[ 9 ] 　Langmi H W, Book D, Harris I R, et al. J. Alloys Comp. ,2003, 356/357: 710—715
[ 10 ] 　Sheppard A D, Maitland C F, Buckley C E. J. Alloys Comp. ,2005, 404/406: 405—408
[ 11 ] 　WardM D. Science, 2003, 300: 1104—1105
[ 12 ] 　Rosi L N, Eckert J, Yaghi O M, et al. Science, 2003, 300:1127—1129
[ 13 ] 　Wu H, Zhou W, Taner Y. J. Am. Chem. Soc. , 2007, 129:5314—5315
[ 14 ] 　Basmadjian D. Can. J. Chem. , 1960, 38: 141—156
[ 15 ] 　Kotoh K, Nishikawa T, Kashio Y. J. Nucl. Sci. Technol. ,2002, 39: 435—441
[ 16 ] 　Skazyvaev V E, Khovshchev S S, Zhdanov S P. Russ. Chem.Bull. , 1975, 24: 1143—1146
[ 17 ] 　Kazansky V B, Borovkov V Y, Serich A, Karge H G. Microporous Mesoporous Mater. , 1998, 22: 251—259
[ 18 ] 　Kazansky V B. J. Mol. Catal. A: Chem. , 1999, 141: 83—94
[ 19 ] 　Jhung S H, Yoon J W, Lee J S, et al. Chem. Eur. J. , 2007,13: 6502—6507
[ 20 ] 　Li Y W, Yang R T. J. Phys. Chem. B, 2006, 110:17175—17181
[ 21 ] 　Bae D H, Park H, Tai N K, et al. J. Phys. Chem. Solids,2008, 69: 1152—1154
[ 22 ] 　Makarova M A, Zholobenko V L, Dwyer J, et al. J. Chem.Soc. Faraday Trans. , 1994, 90: 1047—1054
[ 23 ] 　Jhung S H, Yoon J W, Kim H K, et al. Bull. Korean Chem.Soc. , 2005, 26: 1075—1078
[ 24 ] 　Levin M A, Fomkin A A, Serp inskii V V, et al. Russ. Chem.Bull. , 1986, 35: 2594—2594
[ 25 ] 　Levin M A, Gorbunov M B, Serp inskiiV V, et al. Russ. Chem.Bull. , 1986, 35: 2406—2408
[ 26 ] 　Golden T C, Sircar S. J. Colloid Interface Sci. , 1994, 162:182—188
[ 27 ] 　Langmi H W, Book D, Harris I R, et al. J. Alloys Comp. ,2005, 404 /406: 637—642
[ 28 ] 　Kayiran S B, Darkrim F L. Surf. Interface Anal. , 2002, 34:100—104
[ 29 ] 　Du X M, Wu E D. Chin. J. Chem. Phys. , 2006, 19 ( 5 ) :457—462
[ 30 ] 　杜晓明(Du XM) , 吴尔冬(Wu E D) . 2006年材料科学与工程新进展( The New Progress on Materials and Engineering 2006) , 北京(Beijing) : 化学工业出版社(Chemical Industrial Press) , 2006. 541—546
[ 31 ] 　杜晓明(Du XM) . 中国科学院金属研究所博士论文(Doctoral Dissertation of Institute of Metal Research, Chinese Academy of Sciences) , 2007
[ 32 ] 　Li J, Wu E D. J. Supercrit. Fluids, 2009, 49: 196—202
[ 33 ] 　Li J, Wu E D. Int. J. Hydrogen Energy, 2009, 34:5458—5465
[ 34 ] 　Stephanie-Victoire F, Goulay A M, de Lara E C. Langmuir,1998, 14: 7255—7259
[ 35 ] 　van der Berg A W C, Bromley S T, Jansen J C, et al. Microporous Mesoporous Mater. , 2005, 87: 235—242
[ 36 ] 　Zhan L, Li K X, Ling L C, et al. J. Supercrit. Fluid, 2004,28: 37—45
[ 37 ] 　杜晓明(Du XM) , 吴尔冬(Wu E D) . 物理化学学报(Acta Phys. Chim. Sin. ) , 2007, 23 (6) : 813—819
[ 38 ] 　杜晓明(Du XM) , 吴尔冬(Wu E D) . 物理化学学报(Acta Phys. Chim. Sin. ) , 2009, 25 (3) : 549—554
[ 39 ] 　Darkrim F, Aoufi A, Malbrunot P, et al. J. Chem. Phys. ,2000, 112: 5991—5999
[ 40 ] 　vander Berg AW C, Bromley S T, Jansen J C, et al. J. Chem.Phys. , 2004, 120: 10285—10289
[ 41 ] 　vander Berg AW C, Bromley S T, Jansen J C, et al. J. Chem.Phys. , 2004, 121: 10209—10216
[ 42 ] 　vander Berg AW C, Bromley S T, Jansen J C. Microporous Mesoporous Mater. , 2005, 78: 63—71
[ 43 ] 　Vitillo J G, Ricchiardi G, Zecchina A, et al. Phys. Chem.Chem. Phys. , 2005, 7: 3948—3954
[ 44 ] 　Cook G A. Argon, Helium and the Rare Gases. NY: Interscience, 1961, 228—230
[ 45 ] 　Fraenkel B D. The Potential of Zeolite Molecular Sieves as Hydrogen Storage Media. Alternative Energy Sources. Washington DC: Hemisphere Publishing Corporation, 1977, 3771—3802
[ 46 ] 　Franekel B D, Shabtai J. J. Am. Chem. Soc. , 1977, 14:7074—7076
[ 47 ] 　Franekel B D. J. Chem. Soc. Faraday Trans. 1, 1981, 77:2029—2039
[ 48 ] 　Franekel B D. J. Chem. Soc. Faraday Trans. 1, 1981, 77:2041—2052
[1] Shuai Li, Na Zhu, Yangjian Cheng, Di Chen. Performance of Resistance to Sulfur Oxide and Regeneration over Copper-Based Small-Pore Zeolites Catalysts for the Selective Catalytic Reduction of NOx with NH3 [J]. Progress in Chemistry, 2023, 35(5): 771-779.
[2] Yiling Tan, Shichun Li, Xi Yang, Bo Jin, Jie Sun. Strategies of Improving Anti-Humidity Performance for Metal Oxide Semiconductors Gas-Sensitive Materials [J]. Progress in Chemistry, 2022, 34(8): 1784-1795.
[3] Shiyu Li, Yongguang Yin, Jianbo Shi, Guibin Jiang. Application of Covalent Organic Frameworks in Adsorptive Removal of Divalent Mercury from Water [J]. Progress in Chemistry, 2022, 34(5): 1017-1025.
[4] Yaoyu Qiao, Xuehui Zhang, Xiaozhu Zhao, Chao Li, Naipu He. Preparation and Application of Graphene/Metal-Organic Frameworks Composites [J]. Progress in Chemistry, 2022, 34(5): 1181-1190.
[5] Jie Zhao, Shuai Deng, Li Zhao, Ruikai Zhao. CO2 Adsorption Capture in Wet Gas Source: CO2/H2O Co-Adsorption Mechanism and Application [J]. Progress in Chemistry, 2022, 34(3): 643-664.
[6] Wei Li, Tiangui Liang, Yuanchuang Lin, Weixiong Wu, Song Li. Machine Learning Accelerated High-Throughput Computational Screening of Metal-Organic Frameworks [J]. Progress in Chemistry, 2022, 34(12): 2619-2637.
[7] Baoyou Yan, Xufei Li, Weiqiu Huang, Xinya Wang, Zhen Zhang, Bing Zhu. Synthesis of Metal-Organic Framework-NH2/CHO and Its Application in Adsorption Separation [J]. Progress in Chemistry, 2022, 34(11): 2417-2431.
[8] Kang Chun, Lin Yanxin, Jing Yuanju, Wang Xinbo. Preparation and Environmental Applications of 2D Nanomaterial MXenes [J]. Progress in Chemistry, 2022, 34(10): 2239-2253.
[9] Yun Lu, Hongjuan Shi, Yuefeng Su, Shuangyi Zhao, Lai Chen, Feng Wu. Application of Element-Doped Carbonaceous Materials in Lithium-Sulfur Batteries [J]. Progress in Chemistry, 2021, 33(9): 1598-1613.
[10] Zhao Ding, Weijie Yang, Kaifu Huo, Leon Shaw. Thermodynamics and Kinetics Tuning of LiBH4 for Hydrogen Storage [J]. Progress in Chemistry, 2021, 33(9): 1586-1597.
[11] Xiaoxiao Xiang, Xiaowen Tian, Huie Liu, Shuang Chen, Yanan Zhu, Yuqin Bo. Controlled Preparation of Graphene-Based Aerogel Beads [J]. Progress in Chemistry, 2021, 33(7): 1092-1099.
[12] Liqing Li, Panwang Wu, Jie Ma. Construction of Double Network Gel Adsorbent and Application for Pollutants Removal from Aqueous Solution [J]. Progress in Chemistry, 2021, 33(6): 1010-1025.
[13] Yubing Wang, Jie Chen, Wei Yan, Jianwen Cui. Preparation and Application of Conjugated Microporous Polymers [J]. Progress in Chemistry, 2021, 33(5): 838-854.
[14] Xiansheng Luo, Hanlin Deng, Jiangying Zhao, Zhihua Li, Chunpeng Chai, Muhua Huang. Synthesis and Application of Holey Nitrogen-Doped Graphene Material(C2N) [J]. Progress in Chemistry, 2021, 33(3): 355-367.
[15] Jixiu Zhu, Qiaofen Chen, Titong Ni, Aimin Chen, Jianmin Wu. Application for Exhaled Gas Sensor Based on Novel Mxenes Materials* [J]. Progress in Chemistry, 2021, 33(2): 232-242.