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Progress in Chemistry 2010, Vol. 22 Issue (01): 241-247 Previous Articles   Next Articles

• Invited Article •

Hydrogen Storage Properties of Complex Hydrides Loaded in Porous Materials

Li Yongtao1;  Zhou Guangyou1;  Fang Fang1;  Chen Guorong1;  Sang Ge2;  Sun Dalin1**   

  1. (1. Department of Materials Science, Fudan University, Shanghai 200433, China; 2. China Academy of Engineering Physics, Mianyang 621900, China)
  • Received: Revised: Online: Published:
  • Contact: Sun Dalin E-mail:dlsun@fudan.edu.cn
  • Supported by:

    National Natural Science Foundation of China

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Complex hydrides have been extensively studied because of their higher gravimetric hydrogen density than that of conventional metal hydrides. It has been found that an improved hydrogen storage property is obtained by loading complex hydrides into porous materials which have attracted much attention owing to their high specific surface area, uniform and controllable pore diameter and good thermostability. This paper begins with a brief introduction to the structural characteristics and physical and chemical properties of porous materials, and then the advances in the study of complex hydrides incorporated into porous materials, including preparation methods, catalytic effect and mechanism on the dehydrogenation/rehydrogenation performance, are outlined. The key issues needed to be solved are discussed.

Contents
1 Introduction
2 Structural characteristics and physical and chemical properties of porous materials
3 Complex hydrides loaded into porous materials
3.1 Methods to load complex hydrides into porous materials
3.2 Dehydrogenation/rehydrogenation performance of complex hydrides loaded into porous materials
3.3 Catalytic mechanisms of complex hydrides loaded into porous materials
4 Summary and outlook

Key words: porous materials, complex hydrides, nano-scale adjustment, dehydrogenation/ rehydrogenation properties

CLC Number: 

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