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Progress in Chemistry 2010, Vol. 22 Issue (01): 234-240 Previous Articles   Next Articles

• Invited Article •

Mg-Based Transition-Metal Complex Hydrides with 18-Electronic Structure

Wang Yan; Tao Zhanliang; Chen Jun**   

  1. (Institute of New Energy Materials Chemistry, Engineering Research Center of Energy Storage and Conversion (Ministry of Education), Chemistry College, Nankai University, Tianjin 300071, China)
  • Received: Revised: Online: Published:
  • Contact: Chen Jun E-mail:chenabc@nankai.edu.cn
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The recent progress of research and development on Mg-based transition-metal complex hydrides Mg2NiH4, Mg2CoH5 and Mg2FeH6 with 18-electrons structure and high hydrogen storage capacities is reviewed. In particular, the composition, synthesis technology, thermodynamic and kinetic properties of Mg2NiH4, Mg2CoH5 and Mg2FeH6 have been addressed. The pending problems on Mg2NiH4, Mg2CoH5 and Mg2FeH6 for practical applications are stated in the aspects of the high-temperature absorption/desorption for hydrogen, the slow reaction kinetics, the difficult preparation of Mg2CoH5 and Mg2FeH6, and the poor reversibility. Finally, the development trend on Mg-based transition-metal complex hydrides Mg2NiH4, Mg2CoH5 and Mg2FeH6 in the future is prospected.

Contents
1 Introduction
2 The Mg-Ni-H system
3 The Mg-Co-H system
4 The Mg-Fe-H system
5 Conclusion and prospects

Key words: Mg-based transition-metal hydrides, 18-electrons structure, thermodynamics, kinetics, ionic-covalent bond

CLC Number: 

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