中文
Earlier issues
Announcement
More
Progress in Chemistry 2010, Vol. 22 Issue (01): 119-124 Previous Articles   Next Articles

• Invited Article •

Nanofiltration Membranes Prepared by Layer-by-Layer Self-Assembly of Polyelectrolyte

Ji Yanli2; An Quanfu1**;  Qian Jinwen1;  Chen Huanlin2;  Gao Congjie2,3   

  1. (1.Key Laboratory of Macromolecular Synthesis and Functionalization, Ministry of Education, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China,  2. Department of Chemical Engineering and Bioengineering, Zhejiang University, Hangzhou 310027, China, 3. Development Center of Water Treatment Technology, Hangzhou 310012, China)
  • Received: Revised: Online: Published:
  • Contact: An Quanfu E-mail:anqf@zju.edu.cn
PDF ( 2719 ) Cited
Export

EndNote

Ris

BibTeX

Ultrathin composite nanofiltration (NF) membranes fabricated by layer-by-layer (LbL) assembly technique, which can precisely control structures and compositions, has received a rapid development. In this paper, a review is presented on LbL assembly methods, types of polyelectrolytes and influencing factors of LbL assembly NF membranes in recent years. Three different approaches for LbL assembly are mainly introduced, including the conventional electrostatic deposition method, the pressure-driven LbL assembly and the electric field enhanced LbL assembly. The types of the self-assembled polyelectrolyte materials, which can be classified into homopolymer, copolymer, and organic-inorganic hybrid polyelectrolytes are carried out. Separation performances of NF membrane influenced by various factors, such as the charge character, the charge density and the ionization degree of the polyelectrolyte are discussed. The applications of LbL assembly NF membrane for water-treatment and substances separation from organic solvent are summarized. At the same time, some propose of speeding up the assembly process, improving the performance and development orientation of NF membranes are presented.

Contents
1 Introduction
2 Methods of polyelectrolytes LbL assembly
2.1 Electrostatic deposition LbL assembly
2.2 Pressure-driven LbL assembly
2.3 Electric field enhanced LbL assembly
3 Types of polyelectrolytes for preparing LbL assembly NF membranes
3.1 Homopolymer polyelectrolytes
3.2 Copolymer polyelectrolytes
3.3 Organic-inorganic hybrid polyelectrolytes
4 Applications of LbL assembly NF membranes
4.1 Production and living water softening
4.2 Seawater and brackish water desalination
4.3 Organic compounds separation from water
4.4 Substances separation from organic solvent
5 Conclusion

Key words: polyelectrolyte, layer-by-layer self-assembly, nanofiltration membranes

CLC Number: 

[ 1 ] 　Decher G, Hong J D, Schmitt J. Thin Solid Films, 1992, 831:210—211
[ 2 ] 　Decher G. Science, 1997, 277: 1232—1237
[ 3 ] 　Saremi F, Tieke B. Adv. Mater. , 1998, 10: 388—391
[ 4 ] 　Kolarik L, Furlong D N, Joy H, et al. Langmuir, 1999, 15:8265—8275
[ 5 ] 　Bertrand P, Jonas A, Laschewsky A, et al. Macro. Rapid Commun. , 2000, 21: 319—348
[ 6 ] 　Kleinfeld E R, Ferguson G S. Science, 1994, 265: 370—373
[ 7 ] 　Sun J Q, Wu T, Sun Y P, et al. Chem. Commun. , 1998,1853—1854
[ 8 ] 　Pei R J, Cui X, Wang E. Biomacromolecules, 2001, 2:463—468
[ 9 ] 　Stroeve P, Vasquez V, Coelho M A N, et al. Thin Solid Films,1996, 708: 284—285
[ 10 ] 　Van Ackern F, Krasemann L, Tieke B. Thin Solid Films, 1998,329: 762—766
[ 11 ] 　张鹏( Zhang P) , 钱锦文(Qian J W) , 宣理静(Xuan L J )等.高等学校化学学报(Chemical Journal Of ChineseUniversities) ,2008, 29 (9) : 1885—1889
[ 12 ] 　Krasemann L, Tieke B. J. Membr. Sci. , 1998, 150: 23—30
[ 13 ] 　J in W, Toutianoush A, Tieke B. Langmuir, 2003, 19:2550—2553
[ 14 ] 　Miller M D, Bruening M L. Langmuir, 2004, 20:11545—11551
[ 15 ] 　Stanton B W, Harris J J, BrueningM L. Langmuir, 2003, 19:7038—7042
[ 16 ] 　时钧( Shi J) , 袁权(Yuan Q) , 高从堦( Gao C J ) . 膜技术手册(Handbook Of Membrane Technology) . 北京: 化学工业出版社(Beijing: Chemical Industry Press) , 2001. 247[ 17 ] 　Su Y, J ian X G, Zhang S H, et al. J. Membr. Sci. , 2004,241: 225—233
[ 18 ] 　Peterson R J. J. Membr. Sci. , 1993, 83: 81—150
[ 19 ] 　Huang R H, Chen G H, SunM, et al. J. Membr. Sci. , 2006,286: 237—244
[ 20 ] 　Wang X L, Tsuru T, Nakao S, et al. J. Membr. Sci. , 1997,135: 19—32
[ 21 ] 　Wang D X, Su M, Yu Z Y, et al. Desalination, 2005, 175:219—225
[ 22 ] 　Ladam G, Schaad P, Voegel J C, et al. Langmuir, 2000, 16:1249—1255
[ 23 ] 　Steitz R, LeinerV, Siebrecht R, et al. Colloids Surf. A, 2000,163: 63—70
[ 24 ] 　Shiratori S S, RubnerM F. Macromolecules, 2000, 33: 4213—4219
[ 25 ] 　纪树兰( J i S L) , 张国俊( Zhang G J ) , 谷维梁(GuW L)等.CN 1895756, 2007
[ 26 ] 　Zhang G J, Gu W L, J i S L, et al. J. Membr. Sci. , 2006,280: 727—733
[ 27 ] 　Zhang G J, Yan H H, J i S L, et al. J. Membr. Sci. , 2007,292: 1—8
[ 28 ] 　Deng H Y, Xu Y Y, Zhu B K, et al. J. Membr. Sci. , 2008,323: 125—133
[ 29 ] 　Dobrynin A V, Rubinstein M. Prog. Polym. Sci. , 2005, 30:1049—1118
[ 30 ] 　Zhang P, Qian J W, Yang Y, et al. J. Membr. Sci. , 2008,320: 73—77
[ 31 ] 　Zhang P, Qian J W, An Q F, et al. J. Membr. Sci. , 2009,328: 141—147
[ 32 ] 　Zhang G J, Gao X, J i S L, et al. J. Membr. Sci. , 2008, 307:151—155
[ 33 ] 　Ouyang L, Malaisamy R, Bruening M L. J. Membr. Sci. ,2008, 310: 76—84
[ 34 ] 　Zhang P, Qian JW, An Q F, et al. Langmuir, 2008, 24 ( 5) :2110—2117
[ 35 ] 　方建慧( Fang J H) , 曹志源(Cao Z Y) , 赖特明(Lai TM)等.功能高分子学报( Journal of Functional Polymers) , 2008, 21(2) : 218—222
[ 36 ] 　Hong S U, Malaisamy R, BrueningM L. Langmuir, 2007, 23:1716—1722
[ 37 ] 　方建慧( Fang J H) , 刘达(Liu D) , 施利益( Shi L Y)等. CN1010537802A, 2007
[ 38 ] 　Hong SU, Miller M D, Bruening M L. Ind. Eng. Chem. Res. ,2006, 45: 6284—6288
[ 39 ] 　Hong S U, Bruening M L. J. Membr. Sci. , 2006, 280: 1—5
[ 40 ] 　Vandezande P, Gevers L E M, Vankelecom I F. Chem. Soc.Rev. , 2008, 37: 365—405
[ 41 ] 　Li X F, Feyter S D, Chen D J, et al. Chem. Mater. , 2008,20: 3876—3883
[1] Saihui Zhan, Yue Wang, Kaipeng Liu, Jie Wang. Polyelectrolyte-Based Draw Solution in Forward Osmosis [J]. Progress in Chemistry, 2019, 31(7): 969-979.
[2] Xiong Lina, Zhang Xueqin, Sun Ying, Yang Hong. Synthesis, Self-Assembly and Application of All-Conjugated Block Copolymers [J]. Progress in Chemistry, 2015, 27(12): 1774-1783.
[3] He Xiaoyan*, Zhou Wenrui, Xu Xiaojun, Yang Wu*. Preparation and Application of Zwitterionic Polymers [J]. Progress in Chemistry, 2013, 25(06): 1023-1030.
[4] Yin Mingjie, An Quanfu, Qian Jinwen, Zhang Aping. Preparation and Application of Fiber-Optic Sensors Based on Layer-by-Layer Self-Assembly Multilayers [J]. Progress in Chemistry, 2011, 23(12): 2568-2575.
[5] wang lingyun derong cao. Detection of Biological Molecule Based on Fluorescent Conjugated Polyelectrolytes [J]. Progress in Chemistry, 2010, 22(05): 905-915.
[6] Liu Xiudong1,2|Yu Weiting1|Wang Wei1|Xiong Ying1|Ma Xiaojun1** |Yuan Quan1. Polyelectrolyte Microcapsules Prepared by Alginate and Chitosan for Biomedical Application [J]. Progress in Chemistry, 2008, 20(01): 126-139.
[7] Shang Jing,Chen Xin**,Shao Zhengzhong. The Electric-Field-Sensitive Hydrogels [J]. Progress in Chemistry, 2007, 19(9): 1393-1399.
[8] Cui Zheng,Xiang Yan**,Zhang Tao. Chitosan-Based Solid Polyelectrolyte Membranes for Cell Application [J]. Progress in Chemistry, 2007, 19(04): 583-589.
[9] Tian Binghui**|Pan Gang|Luan Zhaokun. Chemical Characteristics of Enhanced Flocculation Removal of Organic Pollutants by Cationic Polyelectrolytes [J]. Progress in Chemistry, 2007, 19(0203): 205-211.
[10] Lijing Xuan,Jinwen Qian**,Youfang Chen,Peng Zhang. Preparation of Self-Assembled Polyelectrolyte Multilayer Membrane and Their Applications in Membrane Separation [J]. Progress in Chemistry, 2006, 18(0708): 950-956.
[11] Qiang Yang1, Li Wang1**, Weidong Xiang2, Chiliang Wang1, Junfeng Zhou1. Stabilization and Its Mechanisms of the Metal Nanoparticles/Polymer Systems [J]. Progress in Chemistry, 2006, 18(0203): 290-297.
[12] Liang Zhenpeng,Wang Chaoyang,Sun Qilong,Tong Zhen**. Novel Microcapsule Fabricated by LbL Nano Self-Assembly [J]. Progress in Chemistry, 2004, 16(04): 485-.