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Progress in Chemistry 2009, Vol. 21 Issue (6): 1292-1298 Previous Articles   Next Articles

• Review •

Emulsion Atom Transfer Radical Polymerization

Liu Hu; |Wang Wenhao; |Hu Xiaoxi; |Peng Hui; |Yi Changfeng|Xu Zushun**   

  1. (College of Materials Science and Engineering, Hubei University, Wuhan 430062, China)
  • Received: Revised: Online: Published:
  • Contact: Xu Zushun E-mail:zushunxu@hubu.edu.cn
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The main challenge of the application of atom transfer radical polymerization(ATRP)  to emulsion polymerizationsystems is the latex stability and the controllability of the polymerization. This paper reviews a series of factors that affect the controllability of the polymerization and the stability of the latex, the mechanistic aspect and applications of the emulsion atom transfer radical polymerization. The hydrophilic-lipophilic features of surfactants and chemical nature of the hydrophobic and hydrophilic moieties, partitioning of the catalyst/ligand complex between monomer and water, solubility of initiators, temperature, and reactant concentrations are the main aspects that affect the latex stability and the controllability of the polymerization. The emulsion atom transfer radical polymerization mechanism is complicated by the solubility and partitioning of various species in aqueous and organic phases. The emulsion atom transfer radical polymerization combines the characteristics of the living radical polymerization and emulsion polymerization, which will lead to a great perspective in theoretical researches and industrial applications.

Contents
1 ATRP mechanism
2 Factors affecting the latex stability and the controllability of the polymerization
2.1 Surfactants
2.2 Catalyst/Ligand
2.3 Initiators
2.4 Temperature
3 Mechanistic understandings of emulsion atom transfer radical polymerization
4 Applications of emulsion atom transfer radical polymerization
4.1 Preparation of copolymers
4.2 Preparation of polymer particles with peculiar composition,architecture, and functionality
4.3 Preparation of hyperbranched polymers with high molecular weight
5 Summary

Key words: atom transfer radical polymerization, emulsion polymerization, living polymerization

CLC Number: 

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