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Progress in Chemistry 2009, Vol. 21 Issue (6): 1287-1291 Previous Articles   Next Articles

• Review •

Development of Two-Staged Seeded Swelling Polymerization

Lei Jinhua1,2; |Wang Honghua1; |Li Dongliang1,2;   |Zhou Guangyuan1**   

  1. (1.Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China；2.Graduate University of Chinese Academy of Sciences, Beijing 100049, China)
  • Received: Revised: Online: Published:
  • Contact: Zhou Guangyuan E-mail:gyzhou@ciac.jl.cn
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Monodisperse micron-sized polymeric particles can be achieved by two-staged seeded polymerization(also known as the activated swelling polymerization). Because of the controllable particles size, pore size and pore size distribution, particles synthesized by this method are widely used as chromatographic supports, ion exchangers, size exclusion chromatography, biological separation, catalytic supports, etc. This paper introduces polymerization process of two-staged seeded swelling polymerization, mechanism of two-staged swelling and pore formation. Then we give a detailed analysis on the impact of two-step seeded swelling polymerization, including control of polymerization process and effect of each component in two-staged seeded swelling polymerization. Preparation of porous polymer microspheres by this method is summarized likewise. Finally, the future trend of two-step seed swelling polymerization is discussed.

Contents
1 Introduction
2 Process of two-staged seeded swelling polymerization
3 Mechanism of two-staged seeded swelling polymerization
3.1 Mechanism of seeded swelling
3.2 Mechanism of pore formation
4 Control of two-staged seeded swelling polymerization
4.1 Control of polymerization process
4.2 Effect of recipe of two-staged seeded polymerization on obtained particles
5 Application of two-staged seeded swelling polymerization
6 Outlook and summary

Key words: two-staged seeded swelling, polymerization process, swelling mechanism, pore formation mechanism

CLC Number: 

[ 1 ] 　Bilici Z, Camli S T, Unsal E , Tuncel A. Anal . Chim. Acta , 2004 ,516 : 125 —133
[ 2 ] 　Caglayan B , Unsal E , Camli S T, Tuncel M, Tuncel A. J . Sep.Sci . , 2006 , 29 : 936 —944
[ 3 ] 　Unsal E , Camli S T, Irmak T, Tuncel M, Tuncel A.Chromatographia , 2004 , 60 : 553 —560
[ 4 ] 　Unsal E , Camli S T, Tuncel M, Senel S , Tuncel A. React Funct .Polym. , 2004 , 61 : 353 —368
[ 5 ] 　Unsal E , Elmas B , Camli S T, Tuncel M, Senel S , Tuncel A. J .Appl . Polym. Sci . , 2005 , 95 : 1430 —1438
[ 6 ] 　Coutinho F M B , Carvalho D L , Aponte M L L , Barbosa C C R.Polymer , 2001 , 42 : 43 —48
[ 7 ] 　Gong B L , Li L , Zhu J X, Qiang KJ , Ren L. J . Sep. Sci . , 2005 ,28 : 2546 —2550
[ 8 ] 　Gong B L , Li L , Zhu J X. Anal . Bioanal . Chem. , 2005 , 382 :1590 —1594
[ 9 ] 　Gong B L , Wang C , Wang L , Geng X D. Chin. J . Anal . Chem. ,2004 , 32 : 565 —568
[10 ] 　Gong B L , Ke C Y, Geng XD. Chin. J . Chem. , 2004 , 22 : 283 —289
[11 ] 　Coutinho F MB , Rezende SM, Soares B G. J . Appl . Polym. Sci . ,2006 , 102 : 3616 —3627
[12 ] 　马光辉(Ma G H) , 苏志国( Su Z G) . 高分子微球材料(Polymeric Microspheres Material ) . 北京: 化学工业出版社(Beijin: Chemical Industry Press) , 2005. 63 —68
[13 ] 　Thomson B , Rudin A , Lajoie G. J . Appl . Polym. Sci . , 1996 , 59 :2009 —2028
[14 ] 　Song J S , Chagal L , Winnik M A. Macromolecules , 2006 , 39 :5729 —5737
[15 ] 　Song J S , Winnik M A. Macromolecules , 2005 , 38 , 8300 —8307
[16 ] 　Ugelstad J , Kaggerud K H , Hansen F K, Berge A. Makromol .Chem. , 1979 , 180 : 737 —744
[17 ] 　Ugelstad J , Berge A , Ellingsen T, Schmid R , Nilsen T N , Mork P C , Stenstad P , Hornes E , Olsvik O. Prog. Polym. Sci . , 1992 , 17 :87 —161
[18 ] 　Ugelstad J , Mork P C , Schmid R , Ellingsen T, Berge A. Polym.Int . , 1993 , 30 : 157 —168
[19 ] 　Cheng C M, Vanderhoff J W, El-Aasser M S. J . Polym. Sci . Pol .Chem. , 1992 , 30 : 245 —256
[20 ] 　Tuncel A , Tuncel M, Salih B. J . Appl . Polym. Sci . , 1999 , 71 :2271 —2290
[21 ] 　Wang Q C , ˇSvec F , Fréchet J MJ . J . Polym. Sci . Polym. Chem. ,1994 , 32 : 2577 —2588
[22 ] 　Lee D H , KimJ W, Suh KD. J . Mater. Sci . , 2000 , 35 : 6181 —6188
[23 ] 　Unsal E , Camli S T, Senel S , Tuncel A. J . Appl . Polym. Sci . ,2004 , 92 : 607 —618
[24 ] 　Tuncel A. J . Appl . Polym. Sci . , 1999 , 71 : 2291 —2302
[25 ] 　Luz C T L , Coutinho F M B. J . Appl . Polym. Sci . , 2004 , 91 :666 —669
[26 ] 　Luz C TL , Coutinho F MB. Polymer , 2001 , 42 : 4931 —4938
[27 ] 　Luz C TL , Coutinho FMB. Eur. Polym. J . , 2000 , 36 : 547 —553
[28 ] 　KimJ W, Ryu J H , Suh K D. Colloid Polym. Sci . , 2001 , 279 :146 —152
[29 ] 　Kim J W, Park J G, Ryu J H , Chang I S , Suh KD. Colloid Polym.Sci . , 2005 , 283 : 1233 —1240
[30 ] 　NamJ B , Ryu J H , Kim J W, Chang I S , Suh K D. Polymer ,2005 , 46 : 8956 —8963
[31 ] 　Tuncel A , Tuncel M, Ergun B , Alagoz C , Bahar T. Colloid Surf .A-Physicochem. Eng. Asp. , 2002 , 197 : 79 —94
[32 ] 　Cho S H , Ryu J H , Park J G, Suh K D. Eur. Polym. J . , 2005 ,41 : 2209 —2215
[33 ] 　Senel S , Camli S T, Tuncel M, Tuncel A. J . Chromatogr. B ,2002 , 769 : 283 —295
[34 ] 　Kim K S , Lee J H , Kim M H , Cho S H. Polym. J . , 2005 , 37 :669 —676
[35 ] 　Ferreira A , Bigan M, Blondeau D. React . Funct . Polym. , 2003 ,56 : 123 —136
[36 ] 　Park J G, Kim J W, Suh K D. Colloid Polym. Sci . , 2001 , 279 :638 —645
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