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Progress in Chemistry 2009, Vol. 21 Issue (6): 1217-1228 Previous Articles   Next Articles

• Review •

Organic Reactions with Carbon Dioxide

Dong Dongyin; |Yang Liping; |Hu Wenhao**   

  1. (Department of Chemistry, East China Normol University, Shanghai 200062, China)
  • Received: Revised: Online: Published:
  • Contact: Hu Wenhao E-mail:whu@chem.ecnu.edu.cn
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Chemical fixation of carbon dioxide is a very attractive subject not only from viewpoint of carbon resource utilization, but also from increasing environmental concerns. The latest progress in the research of organic reactions utilizing carbon dioxide is reviewed, particularly including the reactions with epoxides, amines, unsaturated compounds, alcohols, hydrocarbons, etc. This review summarizes the organic reactions with carbon dioxide including catalyst design and corresponding reaction mechanism. The outlook of the research area is also provided.

Contents
1 Introduction
2 Reaction with epoxides
2.1 Synthesis of cyclic carbonates
2.2 Synthesis of polycarbonates
3 Reaction with amines
3.1 Synthesis of chain carbamates
3.2 Synthesis of cyclic carbamates
4 Reaction with unsaturated hydrocarbons
5 Reaction with hydrogen
5.1 Synthesis of methanol
5.2 Synthesis of formic acid
5.3 Synthesis of formic ester
5.4 Synthesis of methylic amide
5.5 Synthesis of alcohols from olefins
6 Reaction with alcohols
6.1 Reaction with unsaturated alcohols
6.2 Reaction with unsaturated alcohols
7 Reaction with hydrocarbons
8 Summary and outlook

Key words: carbon dioxide, reactions, catalysis

CLC Number: 

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Abstract

Organic Reactions with Carbon Dioxide