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Progress in Chemistry 2009, Vol. 21 Issue (6): 1199-1206 Previous Articles   Next Articles

• Review •

Synthesis, Structure and Biological Activity of Vanadium Complexes Containing Acylhydrazone Ligands

Xing Jing; |Zhou Yinzhuang**   

  1. (Department of Chemistry, Capital Normal University, Beijing 100048, China)
  • Received: Revised: Online: Published:
  • Contact: Zhou Yinzhuang E-mail:zhouyz7813@x263.net
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Mononuclear and binuclear vanadium complexes containing acylhydrazone ligands have attracted wide attention since they possess various structures and biological activity. The synthesis, characterization and biological activity of these complexes are of growing interest. The research achievements are worthy of being summarized. This review on vanadium complexes containing acylhydrazone ligands is carried out from the following three aspects: (1) the synthesis of these complexes; (2) coordination environment; (3) various biological activities of some mononuclear and binuclear vanadium complexes containing acylhydrazone ligands , such as anti-amoebic, anti-tumor, and insulin-mimetic, inhibitory action on Na+, K+—ATPase and interaction with DNA. The present review is emphasized on making a summary on the relationship between the structure and biological activity of these complexes. Finally, the scarcities and the developing trend in this field are also depicted.

Contents
1 Synthetic method of vanadium complexes containing acylhydrazone ligands
1.1 Complexes prepared from acylhydrazone
1.2 Complexes prepared from hydrazide
1.3 Complexes prepared from other vanadium complexes containing acylhydrazone ligands
2 The coordination mode of vanadium complexes containing acylhydrazone ligands
2.1 Mononuclear vanadium complexes
2.2 Binuclear vanadium complexes
3 Biological activities of vanadium complexes containing acylhydrazone ligands
3.1 Anti-amoebic activity
3.2 Anti-tumor activity
3.3 Insulin-mimetic activity
3.4 The activity of inhibitory action on Na+, K+—ATPase
3.5 Interaction with DNA
4 Conclusions

Key words: vanadium complexes, acylhydrazone, synthesis, structure, biological activity

CLC Number: 

[ 1 ] 　Maurya M R , Kumar A , Bhat A R , et al . Inorg. Chem. , 2006 ,45 : 1260 —1269
[ 2 ] 　Baran E J . J . Inorg. Biochem. , 2000 , 80 : 1 —10
[ 3 ] 　Thompson K H , Orvig C. J . Inorg. Biochem. , 2006 , 100 : 1925 —1935
[ 4 ] 　Tamasi G, Chiasserini L , Savini L , et al . J . Inorg. Biochem. ,2005 , 99 : 1347 —1359
[ 5 ] 　Ainscough E W, Brodie A M, Dobbs A J , et al . Inorg. Chim.Acta , 1998 , 267 : 27 —38
[ 6 ] 　Srinivasan S , Annaraj J , Athappan P. J . Inorg. Biochem. , 2005 ,99 : 876 —882
[ 7 ] 　Kuriakose M, Kurup M R P , Suresh E. Polyhedron , 2007 , 26 :2713 —2718
[ 8 ] 　Charistos D , Voulgaropoulos B , Voutsas G. Structural Chemistry ,2001 , 12 : 67 —72
[ 9 ] 　Sutradhar M, Mukherjee G, Drew M G B , et al . Inorg. Chem. ,2006 , 45 : 5150 —5161
[10 ] 　Maurya M R , Khurana S , Zhang W, et al . J . Chem. Soc. Dalton Trans. , 2002 , 3015 —3023
[11 ] 　Maia P I D S , Deflon V M, Souza E J D , et al . Transition Metal Chemistry , 2005 , 30 : 404 —410
[12 ] 　Bastos AMB , Silva J GD , Maia P I D S , et al . Polyhedron , 2008 ,27 : 1787 —1794
[13 ] 　Maurya M R , Khurana J . Chem. Sci . , 2006 , 118 : 503 —511
[14 ] 　于青(Yu Q) , 李春英(Li C Y) , 边贺东(Bian H D) 等. 结构化学(Chin. J . Struct . Chem. ) , 2007 , 26 (1) : 37 —40
[15 ] 　Plass W, Pohlmann A , Yozgatli H P , et al . J . Inorg. Biochem. ,2000 , 80 : 181 —183
[16 ] 　Maia P I D S , Deflon V M, Sousa G F D , et al . Z. Anorg. Allg.Chem. , 2007 , 633 : 783 —789
[17 ] 　NoblVa P , VieitesM, Parajón-Costa B S , et al . J . Inorg. Biochem. ,2005 , 99 : 443 —451
[18 ] 　NoblVa P , Baran EJ , Otero L , et al . Eur. J . Inorg. Chem. , 2004 ,322 —328
[19 ] 　陈瑞金(Chen R J ) , 周荫庄(Zhou Y Z) , 胡代娣(Hu D D) 等.结构化学(Chin. J . Struct . Chem. ) , 2006 , 25 (2) : 219 —223
[20 ] 　Rath S P , Mondal S , Chakravorty A. Inorg. Chim. Acta , 1997 ,267 : 247 —253
[21 ] 　Diamantis A A , Frederiksen J M, Salam M A , et al . Aust . J .Chem. , 1986 , 39 : 1081 —1088
[22 ] 　Tsiamis C , Voulgaropoulos B , Charistos D , et al . Polyhedron ,2000 , 19 : 2003 —2010
[23 ] 　Wang W, Zeng F L , Wang X, et al . Polyhedron , 1996 , 15 :1699 —1703
[24 ] 　Palacios M S , RocVo MJ , DomVnguez S , et al . Polyhedron , 1997 ,16 : 1143 —1147
[25 ] 　Huo L H , Gao S , Liu J W, et al . Acta Crystallographica Section E:Structure Reports Online , 2004 , E60 : m758 —m760
[26 ] 　刘九辉(Liu J H) , 吴小园(Wu X Y) , 张全争(Zhang Q Z) 等.无机化学学报(Chinese Journal of Inorganic Chemistry) , 2006 , 22(6) : 1028 —1032
[27 ] 　Maurya M R , Khurana S , Schulzke C , et al . Eur. J . Inorg.Chem. , 2001 , 779 —788
[28 ] 　吴琼洁(Wu QJ ) , 刘世雄(Liu S X) . 结构化学(Chin. J . Struct .Chem. ) , 2004 , 23 (10) : 1177 —1182
[29 ] 　Maurya M R , Agarwal S , Bader C , et al . J . Chem. Soc. Dalton Trans. , 2005 , 537 —544
[30 ] 　Huo L H , Gao S , Liu J W, et al . Acta Crystallographica Section E:Structure Reports Online , 2004 , E60 : m606 —m608
[31 ] 　Rath S P , Rajak K K, Mondal S , et al . J . Chem. Soc. Dalton Trans. , 1998 , 2097 —2101
[32 ] 　Rath S P , Rajak K K, Chakravorty A. Inorg. Chem. , 1999 , 38 :4376 —4377
[33 ] 　Gao S , Weng Z Q , Liu S X. Polyhedron , 1998 , 17 : 3595 —3606
[34 ] 　马东升(Ma D S) , 高山(Gao S) , 霍丽华(Huo L H) 等. 高等学校化学研究(Chemical Research in Chinese Universities) , 2004 , 20(3) : 341 —344
[35 ] 　Gao S , Huo L H , Zhang X F , et al . Acta Crystallographica Section E: Structure Reports Online , 2005 , E61 : m738 —m739
[36 ] 　Gao S , Liu J W, Huo L H , et al . Acta Crystallographica Section E:Structure Reports Online , 2004 , E60 : m1722 —m1724
[37 ] 　Chakravarty J , Dutta S , Dey A , et al . J . Chem. Soc. Dalton Trans. , 1994 , 557 —561
[38 ] 　Ghosh T, Bhattacharya S , Das A , et al . Inorg. Chim. Acta , 2005 ,358 : 989 —996
[39 ] 　Nica S , Rudolph M, Gêrls H , et al . Inorg. Chim. Acta , 2007 ,360 : 1743 —1752
[40 ] 　Ghosh T, Mondal B , Ghosh T, et al . Inorg. Chim. Acta , 2007 ,360 : 1753 —1761
[41 ] 　邓兆鹏(Deng Z P) , 高山(Gao S) , 赵辉(Zhao H) 等. 无机化学学报( Chinese Journal of Inorganic Chemistry) , 2007 , 23 ( 1) :173 —176
[42 ] 　Sreeja P B , Kurup M R P. Spectrochim. Acta Part A , 2005 , 61 :331 —336
[43 ] 　周荫庄(Zhou Y Z) , 陈瑞金(Chen R J ) , 屠淑洁(Tu S J ) 等. 中国化学(Chinese Journal of Chemistry) , 2006 , 24 : 153 —156
[44 ] 　Nica S , Pohlmann A , Plass W. Eur. J . Inorg. Chem. , 2005 ,2032 —2036
[45 ] 　Zhou Y Z, Chen R J , Hu D D , et al . Z. Kristallogr. NCS , 2005 ,220 : 509 —510
[46 ] 　Zhou YZ, Zhang XM, Feng J N. Z. Kristallogr. NCS , 2006 , 221 :449 —450
[47 ] 　Zhou Y Z, Hu D D , Chen R J , et al . Z. Kristallogr. NCS , 2005 ,220 : 623 —624
[48 ] 　Hu D D , Zhou Y Z. 25th CCS Congress. China : Chinese Chemical Society , 2006. 11 —P2165
[49 ] 　Plass W, Yozgatli H P. Z. Anorg. Allg. Chem. , 2003 , 629 : 65 —70
[50 ] 　Pohlmann A , Nica S , Luong T K K, et al . Inorg. Chem.Commun. , 2005 , 8 : 289 —292
[51 ] 　Maurya M R , Agarwal S , Bader C , et al . Eur. J . Inorg. Chem. ,2005 , 147 —157
[52 ] 　Becher J , Seidel I , Plass W, et al . Tetrahedron , 2006 , 62 : 5675 —5681
[53 ] 　Lippold I , Gêrls H , Plass W, et al . Eur. J . Inorg. Chem. , 2007 ,1487 —1491
[54 ] 　周荫庄(Zhou Y Z) , 陈瑞金(Chen R J ) , 萧岭梅(Xiao L M) 等.结构化学(Chin. J . Struct . Chem. ) , 2008 , 27 (3) : 369 —373
[55 ] 　高山(Gao S) , 刘世雄(Liu S X) . 应用化学(Chinese Journal of Applied Chemistry) , 2001 , 18 (2) : 161 —162
[56 ] 　Maurya M R , Agarwal S , Abid M, et al . J . Chem. Soc. Dalton Trans. , 2006 , 937 —947
[57 ] 　Deng Z P , Gao S , Huo L H , et al . Acta Crystallographica Section E: Structure Reports Online , 2005 , E61 : m2214 —m2216
[58 ] 　Mondal B , Ghosh T, Sutradhar M, et al . Polyhedron , 2008 , 27 :2193 —2201
[59 ] 　胡代娣(Hu D D) . 首都师范大学硕士论文(Master Dissertation of Capital Normal University) , 2007
[60 ] 　张小梅(Zhang X M) . 首都师范大学硕士论文(Master Dissertation of Capital Normal University) , 2007
[61 ] 　陈瑞金(Chen R J ) . 首都师范大学硕士论文(Master Dissertation of Capital Normal University) , 2006
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