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Progress in Chemistry 2009, Vol. 21 Issue (6): 1187-1198 Previous Articles   Next Articles

• Review •

Fe(II) Spin Crossover Molecule-Based Materials

Zhu Dunru**; |Qi Li; |Cheng Huimin; |Shen Xuan; |Lu Wei   

  1. (State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China)
  • Received: Revised: Online: Published:
  • Contact: Zhu Dunru E-mail:zhudr@njut.edu.cn
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Spin crossover complex has an ideal molecular bistability in which a single molecule or an assembly of molecules can be used as active elements in novel thermal switches, optical switches or information memory devices. The important progress over the past three years on Fe(II) spin crossover molecule-based materials is reviewed in this paper. These materials include the Fe(II) spin crossover complexes showing a spin transition close to room temperature, the Fe(II) spin crossover compounds with the light-induced excited spin state trapping (LIESST) effect and the multifunctional Fe(II) spin crossover materials with liquid crystalline properties, porous properties or electrical conductivity. The applications and perspectives of the Fe(II) spin crossover molecule-based materials are also discussed.

Contents
1 Introduction
2 Fe(II) spin crossover molecule-based materials showing Tc close to room temperature
3 Fe(II) spin crossover molecule-based materials with LIESST effect
4 Multifunctional Fe(II) spin crossover molecule-based materials
4.1 Fe(II) spin crossover materials with liquid crystalline properties
4.2 Porous Fe(II) spin crossover materials
4.3 Fe(II) spin crossover materials with electrical conductivity
5 Conclusions and perspectives

Key words: spin crossover, Fe(II) complexes, LIESST effect, multifunctional materials

CLC Number: 

[ 1 ] 　游效曾(You X Z) . 配位化合物的结构和性质( The Structures and Properties of Coordination Compounds) . 北京: 科学出版社(Beijing : Science Press) , 1992. 645 —662
[ 2 ] 　Hauser A. Adv. Polym. Sci . , 2004 , 233 : 49 —58
[ 3 ] 　Gütlich P , Goodwin H A. Top. Curr. Chem. , 2004 , 233 : 1 —47
[ 4 ] 　Kahn O , Martinez C J . Science , 1998 , 279 : 44 —48
[ 5 ] 　Kênig E , Madeja K. Chem. Commun. , 1966 , 61 —62
[ 6 ] 　Kênig E , Ritter G, Kulshreshtha S K. Chem. Rev. , 1985 , 85 :219 —234
[ 7 ] 　Goodwin H A. Coord. Chem. Rev. , 1976 , 18 : 293 —325
[ 8 ] 　Gütlich P. Structure &Bonding , 1981 , 44 : 83 —195
[ 9 ] 　Gütlich P , Hauser A , Spiering H. Angew. Chem. Int . Ed. , 1994 ,33 : 2024 —2054
[10 ] 　Toftlund H , McGarvey J J . Top. Curr. Chem. , 2004 , 233 : 151 —166
[11 ] 　Goodwin H A. Top. Curr. Chem. , 2004 , 233 : 59 —90
[12 ] 　Van Koningsbruggen PJ . Top. Curr. Chem. , 2004 , 233 : 123 —149
[13 ] 　Kusz J , Gütlich P , Spiering H. Top. Curr. Chem. , 2004 , 234 :129 —153
[14 ] 　Real J A , Gaspar A B , Muìoz M C , et al . Top. Curr. Chem. ,2004 , 233 : 167 —193
[15 ] 　Garcia Y, Niel V , Muìoz M C , et al . Top. Curr. Chem. , 2004 ,233 : 229 —257
[16 ] 　Krêber J , Codjovi E , Kahn O , et al . J . Am. Chem. Soc. , 1993 ,115 : 9810 —9811
[17 ] 　Krêber J , Audière J P , Kahn O , et al . Chem. Mater. , 1994 , 6 :1404 —1412
[18 ] 　Kahn O , Codjovi E , Garcia Y, et al . Molecule-Based Magnetic Materials (Eds. Turnbull MM, Sugimoto T, Thompson L K) . ACS Symposium Series , vol . 644. Washington DC: American Chemical Society , 1996. 298 —310
[19 ] 　Coronado E , Galán-Mascarós J R , Monrabal-Capilla M, et al . Adv.Mater. , 2007 , 19 : 1359 —1361
[20 ] 　Galet A , Gaspar A B , Real J A , et al . Adv. Mater. , 2005 , 17 :2949 —2953
[21 ] 　Rajadurai C , Schramm F , Ruben M, et al . Inorg. Chem. , 2006 ,45 : 10019 —10021
[22 ] 　Cobo S , Molnár G, Real J A , et al . Angew. Chem. Int . Ed. ,2006 , 45 : 5786 —5789
[23 ] 　Tayagaki T, Galet A , Molnár G, et al . J . Phys. Chem. B , 2005 ,109 : 14859 —14867
[24 ] 　Quesada M, de la Peìa-O’Shea V A , Gamez P , et al . Adv.Mater. , 2007 , 19 : 1397 —1402
[25 ] 　Min K S , DiPasquale A , Miller J S , et al . Inorg. Chem. , 2007 ,46 : 1048 —1050
[26 ] 　Bréfuel N , Shova S , Tuchagues J P , et al . Chem. Mater. , 2006 ,18 : 5467 —5479
[27 ] 　McGarvey J J , Lawthers I. J . Chem. Soc. Chem. Commun. , 1982 ,906 —907
[28 ] 　Decurtins S , Gütlich P , Kêhler C P , et al . Chem. Phys. Lett . ,1984 , 105 : 1 —4
[29 ] 　Decurtins S , Gütlich P , Hasselbach K M, et al . Inorg. Chem. ,1985 , 24 : 2174 —2178
[30 ] 　Real J A , Gaspar A B , Muìoz M C. Dalton Trans. , 2005 , 2062 —2079
[31 ] 　Létard J F , Guionneau P , Nguyen O , et al . Chem. Eur. J . , 2005 ,11 : 4582 —4589
[32 ] 　Bousseksou A , Molnár G, Real J A , et al . Coord. Chem. Rev. ,2007 , 251 : 1822 —1833
[33 ] 　Hayami S , Juhász G, Sato O , et al . Inorg. Chem. , 2005 , 44 :7289 —7291
[34 ] 　Niel V , Thompson A L , Real J A , et al . Chem. Eur. J . , 2005 ,11 : 2047 —2060
[35 ] 　Papanikolaou D , Margadonna S , Prassides K, et al . J . Am. Chem.Soc. , 2006 , 128 : 8358 —8363
[36 ] 　Money V A , Carbonera C , Howard J A K, et al . Chem. Eur. J . ,2007 , 13 : 5503 —5514
[37 ] 　Lazar H Z, Forestier T, Létard J F , et al . Dalton Trans. , 2007 ,4276 —4285
[38 ] 　Absmeier A , Bartel M, Linert W, et al . Eur. J . Inorg. Chem. ,2007 , 3047 —3054
[39 ] 　Guionneau P , Gac F L , Kaiba A , et al . Chem. Commun. , 2007 ,3723 —3725
[40 ] 　Gaspar A B , Ksenofontov V , Seredyuk M, et al . Coord. Chem.Rev. , 2005 , 249 : 2661 —2676
[41 ] 　Schadt M, Helfrich W. Appl . Phys. Lett . , 1971 , 18 : 127 —128
[42 ] 　Ksenofontov V , Levchenko G, Spiering H , et al . Chem. Phys.Lett . , 1998 , 294 : 545 —553
[43 ] 　Hayami S , Motokawa N , Shuto A , et al . Inorg. Chem. , 2007 , 46 :1789 —1794
[44 ] 　Hayami S , Motokawa N , Shuto A , et al . Polyhedron , 2007 , 26 :2375 —2380
[45 ] 　Seredyuk M, Gaspar A B , Ksenofontov V , et al . Chem. Mater. ,2006 , 18 : 2513 —2519
[46 ] 　朱敦如(Zhu D R) , 周俊(Zhou J ) , 杨捷(Yang J ) 等. 南京工业大学学报(Journal of Nanjing University of Technology) , 2007 , 29(3) : 103 —110
[47 ] 　Neville S M, Moubaraki B , Kepert C J , et al . Angew. Chem. ,2007 , 119 : 2105 —2108
[48 ] 　Molnár G, Cobo S , Real J A , et al . Adv. Mater. , 2007 , 19 :2163 —2167
[49 ] 　Coronado E , Galán-Mascarós J R. J . Mater. Chem. , 2005 , 15 :66 —74
[50 ] 　Bonhommeau S , Guillon T, Bousseksou A , et al . Angew. Chem. ,2006 , 118 : 1655 —1659
[51 ] 　Faulmann C , Jacob K, Dorbes S , et al . Inorg. Chem. , 2007 , 46 :8548 —8549
[52 ] 　Faulmann C , Dorbes S , Bonneval B G, et al . Eur. J . Inorg.Chem. , 2005 , 3261 —3270
[53 ] 　Dorbes S , Valade L , Real J A , et al . Chem. Commun. , 2005 ,69 —71
[54 ] 　Takahashi K, Cui H B , Okano Y, et al . Inorg. Chem. , 2006 , 45 :5739 —5741
[55 ] 　Zhu D R , Xu Y, You X Z, et al . Chem. Mater. , 2002 , 14 : 838 —843
[56 ] 　朱敦如(Zhu D R) . 南京大学博士学位论文( Doctorial Dissertation of Nanjing University) , 2000 , 1 —61
[57 ] 　Boldog I , Gaspar A B , Martinez V , et al . Angew. Chem. Int . Ed. ,2008 , 47 : 6433 —6437
[58 ] 　Cobo S , Ostrovskii D , Bousseksou A , et al . J . Am. Chem. Soc. ,2008 , 130 : 9019 —9024
[59 ] 　Seredyuk M, Gaspar A B , Ksenofontov V , et al . Adv. Funct .Mater. , 2008 , 18 : 2089 —2101
[60 ] 　Seredyuk M, Gaspar A B , Ksenofontov V , et al . J . Am. Chem.Soc. , 2008 , 130 : 1431 —1439
[61 ] 　Neville S M, Halder GJ , Kepert CJ , et al . J . Am. Chem. Soc. ,2008 , 130 : 2869 —2876
[62 ] 　Genre C , Jeanneau E , Matouzenko G S , et al . Chem. Eur. J . ,2008 , 14 : 697 —705
[63 ] 　Arai M, Kosaka W, Ohkoshi S , et al . Angew. Chem. Int . Ed. ,2008 , 47 : 6685 —6687
[64 ] 　Matsukizono H , Kuroiwa K, Kimizuka N. J . Am. Chem. Soc. ,2008 , 130 : 5622 —5623
[65 ] 　Khusniyarov MM, Weuhermueller T, Wieghardt K, et al . Angew.Chem. Int . Ed. , 2008 , 47 : 1228 —1231
[1] Tang Guotao Wang Qinglun Liao Daizheng Yang Guangming. Spin Crossover and Its Research Progress [J]. Progress in Chemistry, 2010, 22(0203): 257-264.