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Progress in Chemistry 2009, Vol. 21 Issue (6): 1164-1170 Previous Articles   Next Articles

• Review •

Environmentally Stimuli-Responsive Surfactants

Xie Zhanfeng1,2|Feng Yujun1**   

  1. (1. Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China|2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China)
  • Received: Revised: Online: Published:
  • Contact: Feng Yujun E-mail:yjfeng@cioc.ac.cn
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Surfactants can be self-assembled into organized structures such as micelles, vesicles, liquid-crystals in the solution. These organized structures have found broad applications ranging from catalysis, preparation of novel materials to biopharmaceutics. Controlling and changing the surfactant aggregation plays an important role for their applications. Recently, tuning the physicochemical properties of surfactants through regulating environmental condition represents a new direction in surfactant science. The recent progress of six types of environmentally stimuli-responsive surfactants, i.e., pH-, electrolyte-, organic molecule-, temperature-, photo-, and redox-stimuli responsive surfactants are reviewed, and the relationship between their responsive properties and molecular structures is discussed. The future trends of these surfactants are outlooked in this review.

Contents
1 The classification of stimuli-responsive surfactants
1.1 pH stimuli-responsive surfactants
1.2 Electrolyte stimuli-responsive surfactants
1.3 Organic molecule stimuli-responsive surfactants
1.4 Temperature stimuli-responsive surfactants
1.5 Photo stimuli responsive surfactants
1.6 Redox stimuli responsive surfactants
2 The application perspective of stimuli-responsive surfactants
2.1 Application in modifying solution rheology
2.2 Application in enhanced oil recovery
2.3 Application in chemical separation
2.4 Application in gene transfer
2.5 Application in cosolubilization
3 Conclusions

Key words: smart surfactants, micelles, vesicles, environmentally stimuli-responsive

CLC Number: 

[ 1 ] 　Zhang L F , Eisenberg A. Science , 1995 , 268 : 1728 —1731
[ 2 ] 　Alexandridis P , Holzwarth J F , Hatton TA. Macromolecules , 1994 ,27 : 2414 —2425
[ 3 ] 　Riess G. Prog. Polym. Sci . , 2003 , 28 : 1107 —1170
[ 4 ] 　Lazzari M, Liu G, Lecommandoux S ( Eds. ) . Block Copolymers in Nanoscience. Wiley2VCH , 2008. 91 —116
[ 5 ] 　York A W, Kirkland S E , McCormick C L. Adv. Drug Deliv.Rev. , 2008 , 60 : 1018 —1036
[ 6 ] 　Johnsson M, Engberts J B F N. J . Phys. Org. Chem. , 2004 , 17 :934 —944
[ 7 ] 　Alireza T B , Holmberg K. Curr. Opin. Colloid Interface Sci . ,2007 , 12 : 81 —91
[ 8 ] 　Alami E O , Holmberg K. Adv. Colloid Interface Sci . , 2003 , 100/102 : 13 —46
[ 9 ] 　McCormick C L. Stimuli2responsive Water Soluble and Amphiphilic Polymers. Washington DC: ACS , 2001
[10 ] 　马俊涛(Ma J T) . 化学世界(Chemical World) . 2001 , ( 11) :608 —614
[11 ] 　詹劲(Zhan J ) , 周蕊(Zhou R) , 刘铮(Liu Z) . 精细化工( Fine Chemicals) , 2001 , 18 (9) : 534 —537
[12 ] 　Suich D J , Soane D S. CA 2470524 , 2003
[13 ] 　Vakarelski I U , Brown S C , Rabinovich Y I , et al . Langmuir ,2004 , 20 : 1724 —1731
[14 ] 　Fukuda H , Goto A , Yoshioka H , et al . Langmuir , 2001 , 17 :4223 —4231
[15 ] 　Klijn J E , Stuart M C A , Scarzello M, et al . J . Phys. Chem. B ,2006 , 110 : 21694 —21700
[16 ] 　Johnsson M, Wagenaar A , Stuart M C A , et al . Langmuir , 2003 ,19 : 4609 —4618
[17 ] 　Johnsson M, Wagenaar AJ , Engberts B F N. J . Am. Chem. Soc. ,2003 , 125 : 757 —760
[18 ] 　Scarzello M, Klijn J E , Wagenaar A , et al . Langmuir , 2006 , 22 :2558 —2568
[19 ] 　Bergsma M, Fielden ML , Engberts1 J B F N. J . Colloid Interface Sci . , 2001 , 243 : 491 —495
[20 ] 　Asokan A , Cho MJ . Bioconjugate Chem. , 2004 , 15 : 1166 —1173
[21 ] 　Liang E , Hughes J . Biophys. Acta , 1998 , 1369 : 39 —50
[22 ] 　Gonzalez Y I , Nakanishi H , Stjerndahl M, et al . J . Phys. Chem.B , 2005 , 109 : 11675 —11682
[23 ] 　Shen Y, Hao J , Hoffmann H. Soft Matter , 2007 , 3 : 1407 —1412
[24 ] 　Menger F M, Balachander N. J . Am. Chem. Soc. , 1992 , 114 :5862 —5863
[25 ] 　Mohanty A , Patra T, Dey J . J . Phys. Chem. B , 2007 , 111 :7155 —7159
[26 ] 　Ryhanen S J , Saily V MJ , Parry MJ , et al . J . Am. Chem. Soc. ,2006 , 128 : 8659 —8663
[27 ] 　Bordes R , Vedrenne M, Coppel Y, et al . ChemPhysChem , 2007 ,8 : 2013 —2018
[28 ] 　Owen T, Pynn R , Hammouda B , et al . Langmuir , 2007 , 23 :9393 —9400
[29 ] 　Sommerdijk N A J M, Hoeks T H L , Synak M, et al . J . Am.Chem. Soc. , 1997 , 119 : 4338 —4344
[30 ] 　Huang X, Cao M W, Wang YL , et al . J . Phys. Chem. B , 2006 ,110 : 19479 —19486
[31 ] 　Desai A , Varade D , Mataa J , et al . Colloids Surf . A: Physicochem.Eng. Aspects , 2005 , 259 : 111 —115
[32 ] 　Davies T S , Ketner A M, Raghavan S R. J . Am. Chem. Soc. ,2006 , 128 : 6669 —6675
[33 ] 　Gonzalez Y I , Stjerndahl M, Danino D , et al . Langmuir , 2004 , 20 :7053 —7063
[34 ] 　Acharya D P , Kunieda H , Shiba Y, et al . J . Phys. Chem. B ,2004 , 108 : 1790 —1797
[35 ] 　尹海清(Yi H Q) , 黄建滨( Hang J B) . 物理化学学报(Acta Phys. Chim. Sin. ) , 2005 , 21 : 1324 —1330
[36 ] 　Chen H , Ye Z, Han L , et al . Surf . Sci . , 2007 , 601 : 2147 —2151
[37 ] 　Aathimanikandan S V , Savariar E N , Thayumanavan S. J . Am.Chem. Soc. , 2005 , 127 : 14922 —14929
[38 ] 　Hoffmann H , Horbaschek K, Witte F. J . Colloid Interface Sci . ,2001 , 235 : 33 —45
[39 ] 　Raghavan S R , Edlund H , Kaler E W. Langmuir , 2002 , 18 :1056 —1064
[40 ] 　Hassan P A , Valaulikar B S , Manohar C , et al . Langmuir , 1996 ,12 : 4350 —4357
[41 ] 　Kang H C , Lee B , Yoon J , et al . J . Colloid Interface Sci . , 2000 ,231 : 255 —264
[42 ] 　Eastoe J , Wyatt P , Beeby A , et al . Langmuir , 2002 , 18 : 7837 —7844
[43 ] 　Dunkin I R , Gittinger A , Sherrington D C , et al . J . Chem. Soc.Chem. Commun. , 1994 , (19) : 2245 —2246
[44 ] 　Dunkin I R , Gittinger A , Sherrington D C , et al . J . Chem. Soc.Perkin Trans. 2 , 1996 , (9) : 1837 —1842
[45 ] 　Tsuchiya K, Orihara Y, Sakai H , et al . J . Am. Chem. Soc. 2004 ,126 : 12282 —12283
[46 ] 　Ghosh S , Irvin K, Thayumanavan S. Langmuir , 2007 , 23 : 7916 —7919
[47 ] 　Bell P C , Bergsma M, Dolbnya I P , et al . J . Am. Chem. Soc. ,2003 , 125 : 1551 —1558
[48 ] 　Quagliotto P , Viscardi G, Barolo C , et al . J . Org. Chem. , 2003 ,68 : 7651 —7660
[49 ] 　McGregor C , Perrin C , Monck M, et al . J . Am. Chem. Soc. ,2001 , 123 : 6215 —6220
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