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Progress in Chemistry 2009, Vol. 21 Issue (6): 1149-1153 Previous Articles   Next Articles

• Review •

Understanding the Microscopic Structure of the Electrochemically Active Group from Surface Electrochemistry

Guo Yan1; |Ni Wenbin2; |Zhao Jianwei2**   

  1. (1.College of Environmental Science and Engineering, Nanjing University of Information Science &|Technology, Nanjing 210044, China|2.Key laboratory of Analytical Chemistry for Life Science, Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210008, China)
  • Received: Revised: Online: Published:
  • Contact: Zhao Jianwei E-mail:zhaojw@nju.edu.cn
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Understanding structure changes of the electrochemically active species from molecular level can directly promote our knowledge of electrochemistry, molecular/nano electronics, electron transfer in life processes. Surface electrochemistry is a classical experimental method, and from these macroscopic results one can know some information about the molecular structure and the microscopic environment of electrochemically active species. Hence, the transfer coefficient, the apparent number of electron transferred and the reorganization energy are surveyed in this review. The transfer coefficient is directly correlated to the interaction between molecules. The apparent number of electron transferred gives insight into the different connection modes of the subunits in the biomacromolecule. In addition, the reorganization energy can provide information about how the microscopic environment around the electro-active group changes. This paper aims at bringing the value of macroscopic experiment method to molecular electrochmeistry.

Contents
1 Introduction
2 Transfer coefficient and the potential energy surface
3 Correlation between the apparent number of electron transferred and subunits
4 Changes of the microscopic environment reflected by reorganization energy
5 Conclusions

Key words: electrochemistry, electron transfer, transfer coefficient, number of electron transferred, reorganization energy

CLC Number: 

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