中文
Earlier issues
Announcement
More
Progress in Chemistry 2009, Vol. 21 Issue (6): 1141-1148 Previous Articles   Next Articles

• Review •

Progress in Supercritical CO2 Microemulsions with Hydrocarbon Surfactants

Wei Junjie; |Su Baogen**; |Xing Huabin; |Zhang Hai |Yang Qiwei |Ren Qilong   

  1. (National Laboratory of Secondary Resources Chemical Engineering, Zhejiang University, Hangzhou 310027, China)
  • Received: Revised: Online: Published:
  • Contact: Su Baogen E-mail:subg@zju.edu.cn
PDF ( 1565 ) Cited
Export

EndNote

Ris

BibTeX

Supercritical CO2 (sc-CO2) is an attractive alternative to conventional solvents. Unfortunately, it is a poor solvent for high molecular weight and hydrophilic substances. One potential way to solve this problem is to solubilize these insoluble substances within microemulsions in sc-CO2. Hydrocarbon surfactants are very favorable to form microemulsions for industrial applications, as they are far less expensive and less toxic than fluorinated surfactants. A great many works have indicated that common hydrocarbon surfactants generally can not form microemulsions in sc-CO2, so the structure design of surfactants becomes necessary. In this work, the methods are introduced to study the formation, determination and evaluation of microemulsions in sc-CO2. The principles of designing hydrocarbon surfactants are reviewed, especially those based on the CO2-philic characteristic and the surface activity of surfactants. The effects of cosurfactants on the formation of microemulsions in sc-CO2 are described and the sc-CO2 microemulsions formed by common hydrocarbon surfactants with cosurfactants are reviewed. Finally, the effects of mixed surfactant, especially the hydrocarbon surfactants, on the formation of microemulsions in sc-CO2 are introduced.

Contents
1 Formation, determination and evaluation of microemulsions
2 Design and choice of hydrocarbon surfactants
2.1 Choice of commercial hydrocarbon surfactants
2.2 Design of hydrocarbon surfactants
3 Effects of cosurfactants
4 Effects of mixed surfactants
5 Conclusion and prospective

Key words: supercritical CO2, micromulsion, hydrocarbon surfactants, cosurfactants

CLC Number: 

[ 1 ] 　牟天成(Mu T C) , 韩布兴(Han B X) . 化学进展(Progress in Chemistry) , 2006 , 18 (1) : 19 —23
[ 2 ] 　Eastoe J , Gold S. Phys. Chem. Chem. Phys. , 2005 , 7 : 1352 —1362
[ 3 ] 　Eastoe J , Dupont A , Steytler D C. Curr. Opin. Colloid Interface Sci . , 2003 , 8 : 267 —273
[ 4 ] 　张国栋(Zhang GD) , 韩富(Han F) , 张高勇(Zhang G Y) . 化学通报(Chemistry) , 2006 , (2) : 84 —90
[ 5 ] 　李双(Li S) , 王家喜(Wang J X) . 化学世界(Chemical World) ,2007 , (8) : 496 —499
[ 6 ] 　苏宝根(Su B G) . 浙江大学博士论文(Doctoral Dissertation of Zhejiang University) , 2007
[ 7 ] 　Su B G, Xing HB , Ren QL. J . Chem. Eng. Data , 2008 , 53 (8) :1705 —1707
[ 8 ] 　Su B G, Xing HB , Yang YW, et al . J . Chem. Eng. Data , 2008 ,53 (7) : 1672 —1674
[ 9 ] 　Harrison K, Goveas J , Johnston K P , et al . Langmuir , 1994 , 10 :3536 —3541
[10 ] 　Fulton J L , Pfund D M, McClain J B , et al . Langmuir , 1995 , 11 :4241 —4249
[11 ] 　Eastoe J , Bayazit Z, Martel S , et al . Langmuir , 1996 , 12 : 1423 —1424
[12 ] 　Eastoe J , Cazelles B M H , Steytler D C , et al . Langmuir , 1997 ,13 : 6980 —6984
[13 ] 　Eastoe J , Gold S , Steytler D C. Langmuir , 2006 , 22 : 9832 —9842
[14 ] 　Johnston K P , Harrison K L , Clarke M J , et al . Science , 1996 ,271 : 624 —626
[15 ] 　Loeker F , Marr P C , Howdle S M. Colloid Surf . A-Physicochem.Eng. Asp. , 2003 , 214 : 143 —150
[16 ] 　Sagisaka M, Yoda S , Takebayashi Y, et al . Langmuir , 2003 , 19 :220 —225
[17 ] 　Eastoe J , Downer A , Paul A , et al . Phys. Chem. Chem. Phys. ,2000 , 2 : 5235 —5242
[18 ] 　Hoefling T, Stofesky D , Reid M, et al . J . Supercrit . Fluids , 1992 ,5 (4) : 237 —241
[19 ] 　Consani KA , Smith R D. J . Supercrit . Fluids , 1990 , 3 (2) : 51 —65
[20 ] 　Liu J C , Han B X, Li G Z, et al . Langmuir , 2001 , 17 : 8040 —8043
[21 ] 　Liu J C , Zhang J L , Mu T C , et al . J . Supercrit . Fluids , 2003 ,26 : 275 —280
[22 ] 　Liu J C , Han B X, Wang ZW, et al . Langmuir , 2002 , 18 : 3086 —3089
[23 ] 　Liu J C , Han B X, Zhang GL , et al . Chem. Eur. J . , 2002 , 8(6) : 1356 —1360
[24 ] 　Ryoo W, Webber S E , Johnston K P. Ind. Eng. Chem. Res. ,2003 , 42 : 6348 —6358
[25 ] 　Hoefling T A , Enick R M, Beckman E J . J . Phys. Chem. , 1991 ,95 : 7127 —7129
[26 ] 　Kazarian S G, Vincent M F , Bright F V , et al . J . Am. Chem.Soc. , 1996 , 118 : 1729 —1736
[27 ] 　Nelson M R , Borkman R F. J . Phys. Chem. A , 1998 , 102 :7860 —7863
[28 ] 　Raveendran P , Wallen S L. J . Am. Chem. Soc. , 2002 , 124 :12590 —12599
[29 ] 　Raveendran P , Wallen S L. J . Am. Chem. Soc. , 2002 , 124 :7274 —7275
[30 ] 　Sarbu T, Styranec T, Beckman EJ . Nature , 2000 , 405 : 165 —168
[31 ] 　Shen Z, Mchugh M A , Xu J , et al . Polymer , 2003 , 44 : 1491 —1498
[32 ] 　Fan X, Potluri V K, McLeod M C , et al . J . Am. Chem. Soc. ,2005 , 127 : 11754 —11762
[33 ] 　Stone M T, da Rocha S R P , Johnston K P , et al . J . Phys. Chem.B , 2003 , 107 : 10185 —10192
[34 ] 　Stone M T, Smith P G, da Rocha S R P , et al . J . Phys. Chem. B ,2004 , 108 : 1962 —1966
[35 ] 　Pitt A R , Morley S D , Burbidge N J , et al . Colloid Surf . A-Physicochem. Eng. Asp. , 1996 , 114 : 321 —335
[36 ] 　Eastoe J , Paul A , Nave S , et al . J . Am. Chem. Soc. , 2001 , 123 :988 —989
[37 ] 　Gold S , Eastoe J , Grilli R , et al . Colloid Polym. Sci . , 2006 , 284 :1333 —1337
[38 ] 　Eastoe J , Gold S , Steytler D C. Aust . J . Chem. , 2007 , 60 : 630 —632
[39 ] 　Eastoe J , Gold S , Rogers S , et al . Angew. Chem. Int . Ed. , 2006 ,45 : 3675 —3677
[40 ] 　Shervani Z, Ikushima Y, Yukiya H , et al . Colloid Surf . A-Physicochem. Eng. Asp. , 2006 , 289 : 229 —232
[41 ] 　Curri M L , Agostiano A , Manna L , et al . J . Phys. Chem. B ,2000 , 104 : 8391 —8397
[42 ] 　Bansal V K, Shah D O , O'connell J P. J . Colloid Interface Sci . ,1980 , 75 (2) : 462 —475
[43 ] 　Hou MJ , Shah D O. Langmuir , 1987 , 3 : 1086 —1096
[44 ] 　Graciaa A , Lachaise J , Cucuphat C , et al . Langmuir , 1993 , 9 :3371 —3374
[45 ] 　Perez M M, Graciaa A , Lachaise J , et al . Colloid Surf . A-Physicochem. Eng. Asp. , 1995 , 100 : 217 —224
[46 ] 　Liu J C , Shervani Z, Raveendran P , et al . J . Supercrit . Fluids ,2005 , 33 : 121 —130
[47 ] 　McFann GJ , Johnston K P. AIChE J . , 1994 , 40 (3) : 543 —555
[48 ] 　Liu J , Han B X, Li G Z, et al . Fluid Phase Equilib. , 2001 , 187/188 : 247 —254
[49 ] 　Liu J , Han B X, Zhang J L , et al . Fluid Phase Equilib. , 2003 ,211 : 265 —271
[50 ] 　Sawada K, Takagi T, Ueda M. Dyes Pigment . , 2004 , 60 : 129 —135
[51 ] 　Hutton B H , Perera J M, Grieser F , et al . Colloid Surf . A-Physicochem. Eng. Asp. , 1999 , 146 : 227 —241
[52 ] 　周永晟(Zhou YS) . 兰州大学博士论文(Doctoral Dissertation of Lanzhou University) , 2006
[53 ] 　周永晟(Zhou YS) , 安学勤(An XQ) , 沈伟国(Shen W G) 等.科学通报(Chinese Science Bulletin) , 2006 , 51 (7) : 862 —864
[54 ] 　Wang J S F , Wai C M. J . Supercrit . Fluid , 2007 , 40 : 176 —182
[55 ] 　Chennamsetty N , Bock H , Scanu L F , et al . J . Chem. Phys. ,2005 , 122 : art . no. 094710
[56 ] 　Ohde H , Hunt F , Wai C M. Chem. Mater. , 2001 , 13 : 4130 —4135
[57 ] 　Ji M, Chen X Y, Wai C M, et al . J . Am. Chem. Soc. , 1999 ,121 : 2631 —2632
[58 ] 　Sagisaka M, Koike D , Mashimo K, et al . Langmuir , 2008 , 24 :10116 —10122
[59 ] 　Eastoe J , Dupont A , Steytler D C , et al . J . Colloid Interface Sci . ,2003 , 258 : 367 —373
[60 ] 　Sagisaka M, Fujii T, Koike D , et al . Langmuir , 2007 , 23 : 2369 —2375
[1] Deying Mu, Zhu Liu, Shan Jin, Yuanlong Liu, Shuang Tian, Changsong Dai. The Recovery and Recycling of Cathode Materials and Electrolyte from Spent Lithium Ion Batteries in Full Process [J]. Progress in Chemistry, 2020, 32(7): 950-965.
[2] Shi Jingya Wu Peiyi. Application of FTIR Spectroscopy in Polymereric Systems under Supercritical CO2 Processing [J]. Progress in Chemistry, 2009, 21(05): 1023-1033.
[3] Wang Weibin|Yin Jianzhong*. CO2/Ionic Liquids Phase Behaviors and Its Applications for Reaction and Separation [J]. Progress in Chemistry, 2008, 20(04): 441-449.
[4] He Yongjun1** Qi Suitao2 Zhao Shiyong1. Nanoparticle-Stabilized Emulsions and Their Applications in Preparation of Nanostructures [J]. Progress in Chemistry, 2007, 19(9): 1443-1448.