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Progress in Chemistry 2009, Vol. 21 Issue (6): 1134-1140 Previous Articles   Next Articles

• Review •

Study of Emulsions Stabilized by Hydrophobically Associating Polymers

Wei Yunping1;  |Sun Wenbin2;  |Sun Dejun1**   

  1. (1.Key Laboratory for Colloid Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, China|2.Shanghai Research Institute of Petrochemical Technology,Shanghai 201208,China)
  • Received: Revised: Online: Published:
  • Contact: Sun Dejun E-mail:djsun@sdu.edu.cn
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The progress of emulsions stabilized by hydrophobically associating polymers is summarized. We discuss solution properties of hydrophobically associating polymers, whose solution shows much better thickening ability than those of low-molecular-weight surfactants due to their large molecular structures and associations of hydrophobic groups on backbone. Researches about emulsions stabilized solely by hydrophobically associating polymers are summarized, the emulsification mechanisms differ from those of the low-molecular-weight surfactants. Meanwhile, we discuss the interactions between hydrophobially associating polymers and surfactants, this kind of polymer has strong interaction with small surfactants by forming complex to stabilize emulsions. The paper summarizes their application in stabilizing emulsions. Then, the stabilization mechanism of emulsions prepared by hydrophobically associating polymer is given.

Contents
1 Introduction
2 Emulsions stabilized solely by hydrophobically associating polymers
3 Interactions between hydrophobically associating polymers and surfactants and emulsions stabilized by them
3.1 Interactions between hydrophobically associating polymers and surfactants
3.2 Emulsions stabilized by hydrophobically associating polymers and surfactants
4 Stabilization mechanism of HAP-stabilized emulsion
5 Summary

Key words: hydrophobically associating polymers, emulsions, surfactants

CLC Number: 

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