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Progress in Chemistry 2009, Vol. 21 Issue (6): 1094-1100 Previous Articles   Next Articles

• Review •

Recent Advances in Mechanisms and Kinetics of Low-Temperature Selective Catalytic Reduction of NOX with NH3

Li Yuntao; Zhong Qin**   

  1. (School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China)
  • Received: Revised: Online: Published:
  • Contact: Zhong Qin E-mail:zq304@mail.njust.edu.cn; zq304@tom.com
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The mechanisms and kinetics of low-temperature selective catalytic reduction (SCR) have attracted many researchers’ attention. The mechanisms of low-temperature SCR is reviewed by the reaction pathways and reaction models, focusing on the role of oxygen in the low-temperature SCR, the adsorption of NO over the catalyst, the nature of the active NH3 species and the governing reaction models (Langmuir-Hinshelwood or Eley-Rideal). Moreover, combining with the mechanisms of low-temperature SCR, the kinetics of low-temperature SCR are critically discussed. Points of convergence and disagreement are underlined. The perspectives in low-temperature SCR are promoted.

Contents
1 Introduction
2 Mechanisms of low-temperature selective catalytic reduction of NOX with NH3
2.1 Reaction pathways of low-temperature NH3- SCR
2.2 Reaction mechanisms of low-temperature NH3- SCR
3 Kinetics of low-temperature NH3- SCR
4 Conclusion and perspectives

Key words: low-temperature selective catalytic reduction, removal of NOX, mechanisms of SCR, kinetics of SCR

CLC Number: 

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