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Progress in Chemistry 2009, Vol. 21 Issue (12): 2760-2770 Previous Articles   

• Review •

Hydrogen Storage Using Liquid Organic Hydrides

Zhu Gangli;   Yang Bolun**   

  1. (Department of Chemical Engineering, State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an 710049, China)
  • Received: Revised: Online: Published:
  • Contact: Yang Bolun E-mail:blunyang@mail.xjtu.edu.cn
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The hydrogen storage technology based on liquid organic hydrides, which employs the recyclable aromatic-cycloalkanes pairs as the media for hydrogen storage, is definitely a promising potential candidate for hydrogen storage and supply method with high storage capacity and low cost, especially for the long distance transportation of hydrogen and long term seasonal hydrogen storage. This paper reviews the latest research progress in liquid organic hydrides hydrogen storage technology. The basic principles and advantages of the technology as well as several major cycloalkanes used for hydrogen storage are introduced. Various catalysts for dehydrogenation of cycloalkanes are summarized from the following respects: catalyst composition, addition of second metals, particle dispersion, porous structure and surface properties, catalyst deactivation and stability, resistance to sulphur poisoning. Development of new catalytic-reactor configurations such as nonsteady spray-pulsed system, superheated liquid film system and membrane separation reaction system to overcome heat mass transfer limitations are described. And the proposal for future research is also outlined.

Contents
1 Introduction
2 Hydrogen storage using liquid organic hydrides
2.1 Basic principles and features
2.2 Key problems to solve
2.3 Cycloalkanes for hydrogen storage
2.4 Catalysts for dehydrogenation of cycloalkanes
2.5 Catalytic-reactor configurations for effective dehydrogenation
3 Conclusion

Key words: liquid organic hydride, hydrogen storage, dehydrogenation catalysts, catalytic-reactor configuration

CLC Number: 

[ 1 ] 　丁福臣(Ding F C) , 易玉峰(Yi Y F) . 制氢储氢技术. 北京:化学工业出版社(Beijing : Chemical Industry Press ) , 2006 ,1243 —2471
[ 2 ] 　Saito Y. Catalyst and Catalysis , 2001 , 43 (4) : 259 —263
[ 3 ] 　Srivastava S , Srivastava O N. Alloy Compd. , 1999 , 290 (1/2) :250 —256
[ 4 ] 　Noh J S , Agarwal R K, Schwarz J A. Int . J . Hydrogen Energ. ,1987 , 12 (10) : 693 —700
[ 5 ] 　Dillon A C , Jones K M, Bekkedahl T A , et al . Nature , 1997 , 386 :377 —379
[ 6 ] 　Tibbetts G G, Meisner G P , Olk C H. Carbon , 2001 , 39 : 2291 —2301
[ 7 ] 　孙艳(Sun Y) , 周理( Zhou L) , 苏伟(Su W) 等. 科学通报(Chinese Science Bulletin) ,2007 , 52 (3) : 361 —365
[ 8 ] 　Rosi N L , Eckert J , Yaghi O M, et al . Science , 2003 , 300(5622) : 1127 —1129
[ 9 ] 　Wong-Foy A G, Matzger A J , Yaghi O M, et al . J . Am. Chem.Soc. , 2006 , 128 (11) : 3494 —3495
[10 ] 　Pan L , Sander MB , Li J , et al . J . Am. Chem. Soc. , 2004 , 126(5) , 1308 —1309
[11 ] 　潘相敏(Pan XM) , 马建新(Ma J X) . 天然气化工(Natural Gas Chemical Industry) , 2003 , 28 (5) : 51 —55
[12 ] 　Wee J H. J . Power Sources , 2006 , 155 (2) : 329 —339
[13 ] 　Parmaliana A , Crisafulli C , Maggiore R , et al . React . Kinet .Catal . L. , 1981 , 18 (3P4) :295 —299
[14 ] 　Lázaro M P , García-BordejéE , Sebastián D , et al . Catal . Today ,2008 , 138 (3/4) : 203 —209
[15 ] 　González-Marcos M P , Iìarra B , Guil J M,et al . Appl . Catal . A-gen. , 2004 , 273 (1P2) : 259 —268
[16 ] 　Hodoshima S , Takaiwa S , Shono A , et al . Appl . Catal . A-gen. ,2005 , 283 : 235 —242
[17 ] 　Swesi Y, Ronze D , Pitault I , et al . Int . J . Hydrogen Energ. ,2007 , 32 : 5059 —5066
[18 ] 　Scherer G W H , Newson E. Int . J . Hydrogen Energ. , 1998 , 23(1) : 19 —25
[19 ] 　Scherer GW H , Newson E , Wokaun A. Int . J . Hydrogen Energ. ,1999 , 24 (12) : 1157 —1169
[20 ] 　Newson E , Haueter T H , Hottinger P , et al . Int . J . Hydrogen Energ. , 1998 , 23 (10) : 905 —909
[21 ] 　Weissermel K, Arpe H J , Hammett L P. Industrial Organic Chemistry. 4th ed. Weinheim: Wiley-VCH , 2003. 313 —337
[22 ] 　Biniwale R B , Rayalu S , Devotta S , et al . Int . J . Hydrogen Energ. , 2008 , 33 (1) : 360 —365
[23 ] 　Kariya N , Fukuoka A , Ichikawa M. Appl . Catal . A-Gen. , 2002 ,233 (1) : 91 —102
[24 ] 　Hodoshima S , Nagata H , Saito Y, et al . Appl . Catal . A-Gen. ,2005 , 292 (18) : 90 —96
[25 ] 　Kaiya N , Fukuoka A , Ichikawa M. Appl . Catal . A-Gen. , 2003 ,247 : 247 —259
[26 ] 　Hodoshima S , Arai H , Saito Y. Int . J . Hydrogen Energ. , 2003 , 28(2) : 107 —204
[27 ] 　Hodoshima S , Hiroshi A , Shigeki T, et al . Int . J . Hydrogen Energ. , 2003 , 28 : 1255 —1262
[28 ] 　Pham D T, Tetsuya S , Masahiro M, et al . Fuel Process Technol . ,2008 , 89 (4) : 415 —418
[29 ] 　Vázquez-Zavala A , Ostoa-Montes A , Acosta D. Appl . Surf . Sci . ,1998 , 136 : 62 —72
[30 ] 　Vê ltera J ,Kürschnera U. Appl . Catal . , 1983 , 8 (2) : 167 —176
[31 ] 　Chaouki J , Klvana D. Chem. Eng. Sci . , 1994 , 49 (24) : 4639 —4646
[32 ] 　Fujikawa T, Ribeiro F H , Somorjai G A. J . Catal . , 1998 , 178 :58 —65
[33 ] 　González-Marcos M P , Iìarra B , Guil J M, et al . Catal . Today ,2005 , 107/108 : 685 —692
[34 ] 　Dautzenberg F M, Helle J N , Biloen P. J . Catal . , 1980 , 63 :119 —128
[35 ] 　Biloen P , Helle J N , Verbeek H. J . Catal . , 1980 , 63 : 112 —118
[36 ] 　Burch R , Garla L C. J . Catal . , 1981 , 71 : 360 —372
[37 ] 　Palazov A , Bonev C H , Lietz G, et al . J . Catal . , 1987 , 103 :249 —260
[38 ] 　Yolcular S , Olgun O. Catal . Today , 2008 , 138 : 198 —202
[39 ] 　Nabarawy T. Adsorpt . Sci . Technol . , 1997 , 15 (1) : 25 —37
[40 ] 　Zaki T. Petrol . Sci . Technol . , 2005 , 23 (9P10) : 1163 —1181
[41 ] 　Al2Zehour H. Catal . Commun. , 2008 , 9 : 1398 —1403
[42 ] 　Onda A , Komatsu K, Yashima T. J . Catal . , 2001 , 201 : 13 —21
[43 ] 　袁华军(Yuan H J ) . 浙江大学硕士论文(Master Dissertation of Zhejiang University) , 2004
[44 ] 　沈绍辉(Shen S H) . 浙江大学硕士论文(Master Dissertation of Zhejiang University) , 2006
[45 ] 　高林辉(Gao L H) . 浙江大学博士论文(Doctoral Dissertation of Zhejiang University) , 2006
[46 ] 　高林辉(Gao L H) , 陈长聘(Chen C P) , 张继文(Zhang J W)等. 化工学报(Journal of Chemical Industry and Engineering) ,2004 , 55 : 163 —167
[47 ] 　Biniwale R B , Nobuko K, Ichikawa M. Catal . Lett . , 2005 , 105 (1/2) : 83 —87
[48 ] 　Patrici R , Fresia O , Gina P. J . Chem. Technol . Biot . , 1994 , 59 :233 —236
[49 ] 　Serp P , Corrias M, Kalck P. Appl . Catal . A-Gen. , 2003 , 253(2) : 337 —358
[50 ] 　Wang Y G, Shah N , Huffman G P. Energy Fuels , 2004 , 18 (5) :1429 —1433
[51 ] 　Wang Y G, Shah N , Huggins F E , et al . Energy Fuels , 2006 , 20(6) : 2612 —2615
[52 ] 　Yoshimi O , Eiji S , Watanabe E , et al . Int . J . Hydrogen Energ. ,2006 , 31 : 1348 —1356
[53 ] 　Chen A B , Zhang WP , Li X Y, et al . Catal . Lett . , 2007 , 119 (1/2) : 159 —164
[54 ] 　陈进富(Chen J F) , 陆绍信(Lu S X) , 朱亚杰(Zhu Y J ) . 燃料化学学报(Journal of Fuel Chemistry and Technology) , 1998 , 26(6) : 543 —547
[55 ] 　陈进富(Chen J F) , 俞英(Yu Y) , 蔡卫权(Cai W Q) . 太阳能学报(Acta Energiae Solaris Sinica) , 2002 , 23 (6) : 782 —785
[56 ] 　苏君雅(Su J Y) , 丁梅(Ding M) , 杨青(Yang Q) . 石油化工(Petrochemical Technology) , 1996 , 25 (6) : 391 —395
[57 ] 　杨继涛(Yang J T) , 郝雪松(Hao X S) , 苏君雅(Su J Y) 等.石油化工(Petrochemical Technology) , 2002 , 31 (12) : 955 —957
[58 ] 　杨继涛(Yang J T) , 黄亚茹(Huang Y R) , 苏君雅(Su J Y) 等.石油大学学报(自然科学版) (Journal of China University of Petroleum (Edition of Natural Science) ) , 2003 , 27 (2) : 98 —104
[59 ] 　Amano H , Sato S , Takahashi R , et al . Phys. Chem. Chem. Phys. ,2001 , 3 (5) : 873 —879
[60 ] 　Reyes P , Pecchi G, Oportus M, et al . Bol . Soc. Chil . Quim. ,1996 , 41 : 173 —179
[61 ] 　Reyes P , Fernandez J , Pecchi G, et al . J . Chem. Technol . Biot . ,1998 , 73 : 1 —6
[62 ] 　Gates B C , Katzer J R , Schuit G C A. Chemistry of Catalytic Processes. New York : McGraw-Hill , 1979. 184 —324
[63 ] 　Saito Y, Aramaki K, Hodoshima S , et al . Chem. Eng. Sci . , 2008 ,63 (20) : 4935 —4941
[64 ] 　Zhang L Y,Xu G H ,An L ,et al . Int . J . Hydrogen Energ. , 2006 ,31 : 2250 —2255
[65 ] 　Biniwale R B , Yamashiro H , Masaru I. Catal . Lett . , 2005 , 102(1/2) : 23 —31
[66 ] 　Biniwale R B , Masaru I. Chem. Eng. Sci . , 2007 , 62 : 7370 —7377
[67 ] 　Itoh N , Tamura E , Hara S , et . al . Catal . Today , 2003 , 82 (1/4) :119 —125
[68 ] 　Frisch H L , Shahin M, Haoran D N. J . Membrane Sci . , 1999 , 154(1) : 33 —40
[69 ] 　Jeong B H , Sotowa K I , Kusakabe K. J . Membrane Sci . , 2003 ,224 (1/2) : 151 —158
[70 ] 　Zhao L L , Wang R S. Appl . Surf . Sci . , 2004 , 236 : 217 —222
[71 ] 　Tereschenko G F , Ermilova M M, Mordovin V P , et al . Int . J .Hydrogen Energ. , 2007 , 32 (16) : 4016 —4022
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