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Progress in Chemistry 2009, Vol. 21 Issue (12): 2744-2752 Previous Articles   Next Articles

• Review •

A Promising New Energy Material——Spinel Lithium Titanate

Huang Yan1;   Zhang Junying1**;  Zhang Zhongtai2;  Tang Zilong2   

  1. （1. Center of Materials Physics and Chemistry, School of Science, Beihang University, Beijing 100191, China；2. State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China)
  • Received: Revised: Online: Published:
  • Contact: Zhang Junying E-mail:zjy@buaa.edu.cn
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As important new energy materials, many kinds of Li-ion battery electrode materials have aroused unprecedented wide concern. The negative electrode material—spinel Li4Ti5O12 has been paid more and more attentions by researchers due to its many excellent properties such as “zero-strain”. In the meantime, some of these properties also meet the requirements of electrode materials used in electric automobile’s energy storage cell, and hence they are also used in the research of Asymmetric Hybrid Super Capacitors. This paper reviews the structure and properties of Li4Ti5O12, explores researches at home and broad from the aspects of preparation method(sol-gel, solid-state reaction. etc), modification by doping and composing with other materials and so on. The application research progress of this material in all kinds of storage cells is also introduced.

Contents
1 The structure and Li+ insertion mechanism of LTO
2 Preparation methods of LTO
2.1 Sol-gel method
2.2 Process optimization of solid-state synthesis for LTO
2.3 The other preparation methods 3 Various LTO with different morphologies
3.1 LTO with typical morphology
3.2 LTO with porous structure
3.3 LTO nanotube/nanowire and flower-like spinel LTO
4 The reseaches on improving the electronic conductivity of LTO
4.1 Composing with some other materials
4.2 Modification by dopping
5 Application of LTO in various kinds of storage cells
5.1 Li-ion battery with LTO anode
5.2 Application of LTO in asymmetric hybrid energy cell
6 Prospects

Key words: LTO, zero-strain, lithium-ion battery, solid-phase reaction, electronic conductivity, high-rate, asymmetric

CLC Number: 

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