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Progress in Chemistry 2009, Vol. 21 Issue (12): 2660-2673 Previous Articles   Next Articles

• Review •

Self-Assembly of Conjugated Rod-Coil Block Copolymers

Li Di; Zhang Long;  Fan Quli**; Huang Wei**   

  1. (Jiangsu Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, Nanjing 210046, China)
  • Received: Revised: Online: Published:
  • Contact: Fan Quli;Huang Wei E-mail:iamqlfan@njupt.edu.cn;wei-huang@njupt.edu.cn
  • Supported by:

    National Natural Science Foundation of China

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The self-assembly of conjugated rod-coil block copolymers has recently become one of the hot topics in the research of supramolecular chemistry. This article reviews the program on the self-assembly of conjugated rod-coil block copolymers with different rod blocks, including polyfluorene, polydi(styryl)-anthracene, poly(para-phenylene), poly(para-phenyleneethynylene), poly(para-phenylenevinylene), poly(2,5-benzophenone), polythiophene, poly(phenylquinoline), etc. The syntheses and photophysical properties of conjugated rod-coil block copolymers are introduced. The formation and regulation of well-defined one-, two-, or three-dimensional conjugated domains in nanoscale dimensions by the self-assembly of these copolymers in different solvents, temperature and concentration are reviewed emphatically. The potential applications of the self-assembly of conjugated rod-coil block copolymers in many fields, particularly in optoelectronic device, are summarized. Finally, the prospects for the self-assembly of conjugated rod-coil block copolymers are stated.

Contents
1 Introduction
2 The system of conjugated rod-coil block copolymers
2.1 Fluorene-based conjugated rod-coil block copolymers
2.2 Di(styryl)-anthracene-based conjugated rod-coil block copolymers
2.3 Poly(para-phenylene) or Oligo(para-phenylene) -based conjugated rod-coil block copolymers
2.4 Poly(para-phenyleneethynylene) or Oligo(para-phenyleneethynylene) -based conjugated rod-coil block copolymers
2.5 Poly(para-phenylenevinylene) or Oligo(para-phenylenevinylene) -based conjugated rod-coil block copolymers
2.6 Poly(2,5-benzophenone) -based conjugated rod-coil block copolymers
2.7 Polythiophene-based conjugated rod-coil block copolymers
2.8 Poly(phenylquinoline) -based conjugated rod-coil block copolymers
2.9 Others
3 Conclusion

Key words: rod-coil block copolymers, conjugated polymers, self-assembly

CLC Number: 

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