中文
Announcement
More
Progress in Chemistry 2009, Vol. 21 Issue (12): 2651-2659 Previous Articles   Next Articles

• Review •

Syntheses of Branched Polyolefins

Shi Xinbo;  Gao Haiyang;  Wu Qing**   

  1. (Institute of Polymer Science, Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, Sun Yat-Sen University, Guangzhou 510275, China)
  • Received: Revised: Online: Published:
  • Contact: Wu Qing E-mail:ceswuq@mail.sysu.edu.cn
PDF ( 2131 ) Cited
Export

EndNote

Ris

BibTeX

Advances on the catalysts and technologies of preparing branched polyolefins with controllable topology structures are reviewed. Traditionally,branched polyethylenes are obtained by radical polymerization of ethylene, as well as coordination copolymerization of ethylene with α-olefin catalyzed by early transition metal compounds. By combining ethylene oligomerization with in-situ copolymerization of ethylene and the produced α-olefin oligomers, branched polyethylenes with different branch lengh and branching degree are also prepared. In recent years, the newly-developed late transition metal catalysts can be used to synthesize not only the branched, hyperbranched and dendritic polyethylenes by ethylene homopolymerization, but also the end-functional polyolefins with controllable topologies by copolymerization of ethylene with polar monomer.

Contents
1 Introduction
2 Traditional methods of preparing branced polyolefins
3 Syntheses of branced polyolefins by in-situ copolymerization
4 Syntheses of branced polyolefins with controlled topologies by late transition metal catalysts
4.1 Syntheses of branched and hyperbranched polyethylenes by ethylene homopolymerization
4.2 Adjusting polyolefin topology by copolymerization with other monomer or coordination polymerization in tandem with other polymerization methods
5 Conclusion

CLC Number: 

[ 1 ]  Stewart H. ICIS Chemical Business ,2007 , 29 (7) : 29
[ 2 ]  潘祖仁(Pan Z R) . 高分子化学( Polymer Chemistry) , 第3 版. 北京: 化学工业出版社(Beijing : Chemical Industry Press) , 2002
[ 3 ]  焦书科(Jiao S K) . 烯烃配位聚合理论与实践( Theories and Practices of Olefin Coordination Polymerization) . 北京: 化学工业出版社(Beijing : Chemical Industry Press) , 2004
[ 4 ]  Shirayama K, Kita S I , Watabe H. Macromol . Chem. Phys , 1972 , 151 : 97 —120
[ 5 ]  闫冰(Yan B) , 刘晓明(Liu XM) . 塑料(Plastics) , 2008 , 37 (1) : 1 —5
[ 6 ]  Wilfong D L , Knight GW. J . Polym. Sci . Part B : Polym. Phys. , 1990 , 28 : 861 —870
[ 7 ]  Usami T, Gotoh Y, Takayama S. Macromolecules , 1986 , 19 : 2722 —2726
[ 8 ]  Freed K F , Dudowicz J . Macromolecules , 1996 , 29 : 625 —636
[ 9 ]  Zhang M, Lynch D T, Wanke S E. Polymer , 2001 , 42 : 3067 — 3075
[10 ]  Sinn H , Kaminsky W. Adv. Organomet . Chem. , 1980 , 18 : 99 — 149
[11 ]  黄葆同(Huang B T) , 陈伟(Chen W) . 茂金属催化剂及其烯烃聚合物(Metallocene Catalyst and Olefin Polymer) . 北京: 化学工业出版社(Beijing : Chemical Industry Press) , 2002
[12 ]  Kuwabara K, Kaji H , Horii F. Macromolecules , 2000 , 33 : 4453 — 4462
[13 ]  向明(Xiang M) , 张博冲(Zhang B C) , 蔡燎原(Cai L Y) 等. 塑料工业(China Plastics Industry) , 2004 , 31 (4) : 1 —5
[14 ]  刘新星(Liu X X) , 祝方明(Zhu FM) . 塑料(Plastics) , 2000 , 29 (5) : 26 —29
[15 ]  陈红霞(Chen H X) , 吴殿义(Wu D Y) . 化工科技(Science & Technology in Chemical Industry) , 2002 , 1 (10) : 50 —53
[16 ]  黄文娟(Huang WJ ) , 闫卫东(Yan WD) , 胡友良(Hu YL) 等. 应用化学(Chinese Journal of Applied Chemistry) , 2003 , 20 (3) : 817 —822
[17 ]  胡友良(Hu YL) , 马志(Ma Z) , 吕英莹(Lv Y Y) . 石油技术与应用(Petrochemical Technology &Application) , 2003 , 21 (1) : 1 —4
[18 ]  王亚丽(Wang YL) , 张斌( Zhang B) , 王秀绘(Wang X H) 等. 工业催化( Industrial Catalysis) , 2007 , 15 (11) : 15 —19
[19 ]  Beach D L , Kissin Y Y. J . Polym. Sci . A: Polym. Chem. , 1984 , 22 : 3027 —3042
[20 ]  Kissin YV , Beach D L. J . Polym. Sci . A: Polym. Chem. , 1986 , 24 : 1069 —1084
[21 ]  Wang WJ , Yan D J , Zhu S P , et al . Macromolecules , l998 , 31 : 8677 —8683
[22 ]  Schwerdtfeger E D , Irwin L J , Miller S A. Macromolecules , 2008 , 41 : 1080 —1085
[23 ]  Small B L , Brookhart M, Bennett A M A. J . Am. Chem. Soc. , 1998 , 120 : 4049 —4050
[24 ]  Britovsek G J P , Gibson V C , Kimberley B S , et al . Commum. Chem. , 1998 , 7 : 849 —850
[25 ]  Kumar KR , Sivaram S. E. Macromol . Chem. , 2000 , 201 : 1513 — 1520
[26 ]  Kaul F A R ,Mihalios D , Herrmann W A. Organometallics , 2002 , 21 : 74 —82
[27 ]  Semikolenova N V , Babushkin D E , Khysniyarov M M. J . Mol . Catal . A: Chem. , 2002 , 182P183 : 283 —294
[28 ]  Abu2Surrah A S , Repo T, Leskela M, et al . J . Organomet . Chem. , 2002 , 648 : 55 —61
[29 ]  Schmidt R , Welch MB , Palackal SJ , Alt H G. J . Mol . Catal . A: Chem. , 2002 , 179 : 155 —173
[30 ]  Qiu J M, Li Y F , Hu YL. Polym. Int . ,2000 , 49 : 5 —7
[31 ]  Ma Z, Xu D M, Hu YL. Macromol . Rapid. Commun. , 2001 , 22 : 1280 —1283
[32 ]  柳忠阳(Liu Z Y) , 王军(Wang J ) , 徐德民(Xu D M) . 科学通报(Chinese Science Bulletin) , 2001 , 46 (15) : 1264 —1267
[33 ]  Quijada R , Rojas R , Bazen G, et al . Macromolecules , 2001 , 34 : 2411 —2417
[34 ]  Zhang Z Z, Cui N N , Hu Y L , et al . J . Polym. Sci . Part A: Polym. Chem. , 2005 , 43 : 984 —993
[35 ]  黄英娟(Huang YJ ) , 姬荣琴(Ji R Q) , 刘盘阁(Liu P G) 等. 高分子材料科学与工程(Polymer Materials Science & Engineering) , 2005 , 21 (3) : 73 —76
[36 ]  黄英娟(Huang YJ ) , 刘盘阁(Liu P G) , 姬荣琴(Ji R Q) 等. 高分子学报(Acta Polymerica Sininca) , 2004 , (1) : 125 —128
[37 ]  Wang H , Ma Z, Hu YL , et al . Polym. Int . , 2003 , 52 : 1546 — 1552
[38 ]  Furlan L G, Kunrath F A , Mauler R S , et al . J . Mol . Catal . A: Chem. , 2004 , 214 : 207 —211
[39 ]  Zhu N ,Cui Y, Li ZL , et al . Chin. J . Polym. Sci . , 2003 , 21 (4) : 453 —457
[40 ]  艾娇艳(Ai J Y) , 祝方明(Zhu FM) , 林尚安(Lin S A) . 高分子学报(Acta Polymerica Sininca) , 2005 , (1) : 71 —75
[41 ]  Bamhart R W, Bazan G C. J . Am. Chem. Soc. , 1998 , 120 : 1082 —1083
[42 ]  Komon ZJ A , Bu X, Bazan GC. J . Am. Chem. Soc. , 2000 , 122 : 1830 —1831
[43 ]  李贺新(Li H X) , 石金永(Shi J Y) , 闫卫东( Yan W D) 等. 高分子学报(Acta Polymerica Sininca) , 2004 , (6) : 935 —938
[44 ]  艾娇艳(Ai J Y) , 祝方明(Zhu FM) , 林尚安(Lin S A) . 高分子学报(Acta Polymerica Sininca) , 2004 , (2) : 225 —228
[45 ]  Komon ZJ A , Diamond G M, Bazan G C , et al . J . Am. Chem. Soc. , 2002 , 124 : 12580 —12585
[46 ]  Wang J X, Li H B , Marks TJ , et al . Organometallics , 2004 , 23 : 5112 —5114
[47 ]  Johnson L K, Killian C M, Brookhart M. J . Am. Chem. Soc. , 1995 , 117 : 6414 —6415
[48 ]  Daniel J T, Johnson L K, Brookhart M, et al . J . Am. Chem. Soc. , 2000 , 122 : 6686 —6700
[49 ]  Leigh H S , Brookhart M. J . Am. Chem. Soc. , 2001 , 123 : 11539 —11555
[50 ]  Leatherman M D , Svejda S A , Brookhart M, et al . J . Am. Chem. Soc. , 2003 , 125 : 3068 —3081
[51 ]  Ittel S D , Johnson L K, Brookhart M. Chem. Rev. , 2000 , 100 : 1169 —1203
[52 ]  Gibson V C , Spitzmesser S K. Chem. Rev. , 2003 , 103 : 283 —315
[53 ]  Gates D P , Svejda S A , Brookhart M, et al . Macromolecules , 2000 , 33 : 2320 —2334
[54 ]  Meinhard D , Rieger B. Chem. Asian J . , 2007 , 2 : 386 —392
[55 ]  Meinhard D , Wegner M, Rieger B , et al . J . Am. Chem. Soc. , 2007 , 129 : 9182 —9191
[56 ]  AlObaidi F , Ye Z B , Zhu S P. Polymer , 2004 , 45 : 6823 —6829
[57 ]  Camacho D H , Guan Z B. Angew. Chem. Int . Ed. , 2004 , 43 : 1821 —1825
[58 ]  Popeney C S , Camacho D H , Guan Z B. J . Am. Chem. Soc. , 2007 , 129 : 10062 —10063
[59 ]  Camacho D H , Guan ZB. Macromolecules , 2005 , 38 : 2544 —2546
[60 ]  Drexel H C , Salo E V , Guan Z B , et al . Organometallics , 2005 , 24 : 4933 —4939
[61 ]  Popeney C , Guan Z B. Organometallics , 2005 , 24 : 1145 —1155
[62 ]  Guan Z B , Cotts P M. Science , 1999 , 283 : 2059
[63 ]  Guan Z B. Chem. Eur. J . , 2002 , 14 : 3086 —3092
[64 ]  Guan Z B. J . Polym. Sci . Part A: Polym. Chem. , 2003 , 41 : 3680 —3692
[65 ]  Cotts P M, Guan Z B , McCord M, et al . Macromolecules , 2000 , 33 : 6945 —6952
[66 ]  Kunrath F A , Mota F F , de Souza R F , et al . Macromol . Chem. Phys. , 2002 , 203 : 2407 —2411
[67 ]  Ye Z B , AlObaidi F , Zhu S P. Macromol . Chem. Phys. , 2004 , 205 : 897 —906
[68 ]  Wang J L , Ye Z B , Zhu S P. Ind. Eng. Chem. Res. , 2007 , 46 : 1174 —1178
[69 ]  Wang C M, Grubbs R H. Organometallics , 1998 , 17 : 3149 —3151
[70 ]  Younkin T R , Connor E F , Grubbs R H. Science , 2000 , 287 : 460 —462
[71 ]  Hicks F A , Brookhart M. Organometallics , 2001 , 20 : 3217 —3219
[72 ]  Jenkins J C , Brookhart M. Organometallics , 2003 , 22 : 250 —256
[73 ]  Hicks F A , Brookhart M. Organometallics , 2003 , 22 : 3533 —3545
[74 ]  Keim W, Schulz R P. J . Mol . Catal . , 1994 , 92 : 21 —33
[75 ]  Laine T V , Piironen U , Lappalainen K. J . Organomet . Chem. , 2000 , 606 : 112 —124
[76 ]  Laine T V , Lappalainen K, Liimatta J . Macromol . Rapid. Commun. , 1999 , 20 : 487 —491
[77 ]  Huang Z F , Gao H Y, Wu Q , et al . J . Polym. Sci . Part A: Polym. Chem. , 2008 , 46 : 1618 —1628
[78 ]  Guan Z B , Marshall WJ . Organometallics , 2002 , 21 : 3580 —3586
[79 ]  Daugulis O , Brookhart M. Organometallics , 2002 , 21 : 5935 —5943
[80 ]  Zhang D , Jin G X. Organometallics , 2003 , 22 :2851 —2854
[81 ]  Mecking S , Brookhart M. J . Am. Chem. Soc. , 1998 , 120 : 888 — 899
[82 ]  Chen G H , Ma X S. J . Am. Chem. Soc. , 2003 , 125 : 6697 —6704
[83 ]  Chen G H , Guan Z B. J . Am. Chem. Soc. , 2004 , 126 : 2662 — 2663
[84 ]  Wang J L , Ye Z B , Joly H. Macromolecules , 2007 , 40 : 6150 — 6163
[85 ]  Ye J D , Ye Z B , Zhu S P. Polymer , 2008 , 49 : 3382 —3392
[86 ]  Wang J L , Zhang KJ , Ye ZB. Macromolecules , 2008 , 41 : 2290 — 2293
[87 ]  Park S , Takeuchi D , Osakada K. J . Am. Chem. Soc. , 2006 , 128 : 888 —899
[88 ]  Hong S C , Matyjaszewski K, Brookhart M, et al . J . Polym. Sci . Part A: Polym. Chem. , 2002 , 40 : 2736 —2749
[89 ]  Zhang KJ , Ye Z B , Subramanian R. Macromolecules , 2008 , 41 : 640 —649
[90 ]  Chen G H , Huynh D , Guan Z B , et al . J . Am. Chem. Soc. , 2006 , 128 : 4298 —4302
[91 ]  Zhang K J , Wang J L , Ye Z B , et al . Macromol . Rapid. Commun. , 2007 , 28 : 2185 —2191

[1] Jiaye Li, Peng Zhang, Yuan Pan. Single-Atom Catalysts for Electrocatalytic Carbon Dioxide Reduction at High Current Densities [J]. Progress in Chemistry, 2023, 35(4): 643-654.
[2] Yuewen Shao, Qingyang Li, Xinyi Dong, Mengjiao Fan, Lijun Zhang, Xun Hu. Heterogeneous Bifunctional Catalysts for Catalyzing Conversion of Levulinic Acid to γ-Valerolactone [J]. Progress in Chemistry, 2023, 35(4): 593-605.
[3] Chunyi Ye, Yang Yang, Xuexian Wu, Ping Ding, Jingli Luo, Xianzhu Fu. Preparation and Application of Palladium-Copper Nano Electrocatalysts [J]. Progress in Chemistry, 2022, 34(9): 1896-1910.
[4] Mingjue Zhang, Changpo Fan, Long Wang, Xuejing Wu, Yu Zhou, Jun Wang. Catalytic Reaction Mechanism for Hydroxylation of Benzene to Phenol with H2O2/O2 as Oxidants [J]. Progress in Chemistry, 2022, 34(5): 1026-1041.
[5] Shujin Shen, Cheng Han, Bing Wang, Yingde Wang. Transition Metal Single-Atom Electrocatalysts for CO2 Reduction to CO [J]. Progress in Chemistry, 2022, 34(3): 533-546.
[6] Yang Linyan, Guo Yupeng, Li Zhengjia, Cen Jie, Yao Nan, Li Xiaonian. Modulation of Surface and Interface Properties of Cobalt-Based Fischer-Tropsch Synthesis Catalyst [J]. Progress in Chemistry, 2022, 34(10): 2254-2266.
[7] Wu Qiaomei, Yang Qiyue, Zeng Xianhai, Deng Jiahui, Zhang Liangqing, Qiu Jiarong. Catalytic Conversion of Cellulose-Based Biomass to Diols [J]. Progress in Chemistry, 2022, 34(10): 2173-2189.
[8] Yuan Su, Keming Ji, Jiayao Xun, Liang Zhao, Kan Zhang, Ping Liu. Catalysts for Catalytic Oxidation of Formaldehyde and Reaction Mechanism [J]. Progress in Chemistry, 2021, 33(9): 1560-1570.
[9] Xiangchun Tang, Jiaxiang Chen, Lina Liu, Shijun Liao. Pt-Based Electrocatalysts with Special Three-Dimensional Morphology or Nanostructure [J]. Progress in Chemistry, 2021, 33(7): 1238-1248.
[10] Jingchen Tian, Gongde Wu, Yanjun Liu, Jie Wan, Xiaoli Wang, Lin Deng. Application of Supported Non-Noble Metal Catalysts for Formaldehyde Oxidation at Low Temperature [J]. Progress in Chemistry, 2021, 33(11): 2069-2084.
[11] Yiqiang Liu, Yimei Qiu, Xing Tang, Yong Sun, Xianhai Zeng, Lu Lin. Glucose Isomerization into Fructose by Chemocatalytic Route [J]. Progress in Chemistry, 2021, 33(11): 2128-2137.
[12] Andong Hu, Shungui Zhou, Jie Ye. The Mechanism, Progress and Prospect of Biohybrid Mediated Semi-Artificial Photosynthesis [J]. Progress in Chemistry, 2021, 33(11): 2103-2115.
[13] Mengting Xu, Yanqing Wang, Ya Mao, Jingjuan Li, Zhidong Jiang, Xianxia Yuan. Cathode Catalysts for Non-Aqueous Lithium-Air Batteries [J]. Progress in Chemistry, 2021, 33(10): 1679-1692.
[14] Huina Zou, Shoufei Zhu. Progresses of 1,10-Phenanthroline Type Ligands in Fe/Co/Ni Catalysis [J]. Progress in Chemistry, 2020, 32(11): 1766-1803.
[15] Wenhao Wu, Wen Lei, Liqiong Wang, Sen Wang, Haijun Zhang. Preparation of Single Atom Catalysts [J]. Progress in Chemistry, 2020, 32(1): 23-32.
Viewed
Full text


Abstract

Syntheses of Branched Polyolefins