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Progress in Chemistry 2009, Vol. 21 Issue (12): 2613-2624 Previous Articles   Next Articles

• Review •

The Application of Platinum and Rhodium N-Heterocyclic Carbene Complexes in Hydrosilylation Reaction

Bai Ying;  Peng Jiajian;  Hu Yingqian;  Li Jiayun;  Lai Guoqiao;  Jiang Jianxiong**   

  1. (Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education and Zhejiang Province, Hangzhou Normal University, Hangzhou 310012, China)
  • Received: Revised: Online: Published:
  • Contact: Jiang Jianxiong E-mail:hsdyjg@163.com
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N-heterocyclic carbene Pt and N-heterocyclic carbene Rh complexes are used as catalysts in hydrosilylation. It is specially noticed that the complexes showed excellent catalytic properties and stabilized physical and chemical nature. This review summarizes the recent progress in the application of platinum and rhodium N-heterocyclic carbene complexes as catalysts in hydrosilylation of ketones, alkynes, alkenes and other unsaturated compounds.

Contents
1 Introduction
2 N-heterocyclic carbene Pt complexes catalyzed hydrosilylation
2.1 Catalytic properties of N-heterocyclic carbene Pt complexes catalyzed hydrosilylation
2.2 Mechanism of catalytic hydrosilylation by N-heterocyclic carbene Pt complexes
3 N-heterocyclic carbene Rh complexes catalyzed hydrosilylation
3.1 N-heterocyclic carbene Rh complexes catalyzed hydrosilylation of ketone
3.2 N-heterocyclic carbene Rh complexes catalyzed hydrosilylation of alkynes
3.3 Mechanism of catalytic hydrosilylation of alkynes by N-heterocyclic carbene Rh complexes
3.4 N-heterocyclic carbene Rh complexes catalyzed hydrosilylation of other compounts
4 Conclusion and expectation

Key words: platinum, rhodium, N-heterocyclic carbene, hydrosilylation

CLC Number: 

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