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Progress in Chemistry 2009, Vol. 21 Issue (12): 2589-2594 Previous Articles   Next Articles

• Review •

Ferroceneacetylene: a Versatile Building Block in Optoelectronic Molecules

Guo Jian; Zhuang Shun; Wu Kaiqiang; Yuan Yaofeng**   

  1. (Department of Chemistry, Fuzhou University, Fuzhou 350108, China)
  • Received: Revised: Online: Published:
  • Contact: Yuan Yaofeng E-mail:yaofeng_yuan@fzu.edu.cn
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Ferrocene has many attractive features, such as excellent reversible redox properties, high solubility in organic media, and high modifiability with organic chemical methods, and it remains a promising molecular fragment for molecular devices. Alkynyl has rigidity and linearity. The combination of the two make ferroceneacetylene has delocalized π-bond as a versatile building block. So it has been widely used in the design and synthesis of optoelectronic functional molecule. The review focuses on the structures and applications of molecules containing ferroceneacetylene in molecular wire, molecular switch, molecular rotor, chemosensing, nonlinnear optics, catalyst, photochromism and so on in recent years.

Contents
1 Introduction
2 Applications of ferroceneacetylene in optoelectronic functional molecules
2.1 Molecular wire
2.2 Molecular switch
2.3 Molecular sensor
2.4 Molecular rotor
2.5 Nonlinnear optics materials
2.6 Magnetic materials
2.7 Catalyst
2.8 Precursor of nano-materials
2.9 Photochromism
3 Expectation

Key words: ferroceneacetylene, π-conjugated structures, optoelectronic functional molecules, building block

CLC Number: 

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