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Progress in Chemistry 2009, Vol. 21 Issue (12): 2515-2524 Previous Articles   Next Articles

• Review •

A Novel Model of Host Molecule in Supramolecular Based on Cyclodextrin-Crownether Coupling System

Sun Tao;  Shen Jian; Sun Hongyuan; Hao Aiyou*   

  1. (School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China)
  • Received: Revised: Online: Published:
  • Contact: Hao Aiyou E-mail:haoay@sdu.edu.cn
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Supramolecule chemistry is an advanced research topic in current chemistry, and the selective synthesis of the host compound is an important aspect. Cyclodextrins and crownethers, which have their own special characters and disadvantages, are both widely used in supramolecular chemistry. The cyclodextrin-crownether coupling system which has two or more recognition sites will expand their applications greatly in the area of molecular recognition , enzyme mimic, chromatography, etc. through synergistic effection with fine results. Here, the recent development of cyclodextrin-crownether coupling system is reviewed. Firstly, the synthesis of different kinds of cyclodextrin-crownether coupling systems is introduced, including the synthesis clues, approaches and methods. Then, the application of the system is emphatically described, including in the field of molecule recognition, mimetic enzyme, isolation of isomers and energy transfer of light. At last, the disadvantages in recent study and prospects are pointed out.

Contents
1 Synthesis of cyclodextrin-crownether coupling system
1.1 Synthesis of simple cyclodextrin-crownether coupling system
1.2 Synthesis of cyclodextrin-crownether coupling system including π-system
1.3 Synthesis of cyclodextrin-crownether coupling system attached to silica gel
1.4 Synthesis of cyclodextrin-crownether-calixarene coupling system
1.5 Synthesis of cyclodextrin-analogue of crownether coupling system
2 Characters and applications of cyclodextrin-crownether coupling system
2.1 Applications of cyclodextrin-crownether coupling system in molecular recognition
2.2 Applications of cyclodextrin-crownether coupling system in enzyme mimics
2.3 Applications of cyclodextrin-crownether coupling system in seperation of isomers
2.4 Applications of cyclodextrin-crownether coupling system in energy transfer of light
3 Prospects

Key words: cyclodextrin, crownether, coupling system, enzyme mimics, molecular recognition, chromatography

CLC Number: 

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