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Progress in Chemistry 2009, Vol. 21 Issue (12): 2505-2514 Previous Articles   Next Articles

• Review •

Thermodynamic Properties and Applications of Supercritical Carbon Dioxide Microemulsions/Reverse Micelles

Yin Jianzhong1**; Zhou Dan1; Wang Aiqin2   

  1. (1. School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China; 2. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China)
  • Received: Revised: Online: Published:
  • Contact: Yin Jianzhong E-mail:jzyin@dlut.edu.cn
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Supercritical microemulsions (reverse micelle) which improves the solvent properties of supercritical fluid greatly is a hot topic in the research of supercritical fluid technology. The solubilization behavior can be manipulated easily by choosing appropriate surfactants and controlling the operating conditions. As a new green solvent, it has large potential applications in many fields, such as chemical reactions, material preparations and extraction separations. This article provides information of the conceptions of supercritical microemulsions (reverse micelle) system and gives an overview of thermodynamics characteristics, selection of surfactants, phase behavior, calculation of hydrodynamic sizes and interdroplets interactions. The applications in these fields are also reviewed.

Contents
1 Introduction
2 Supercritical microemulsion technology
2.1 Selection of the surfactants for forming scCO2 microemulsion
2.2 Phase equilibrium behavior of scCO2 microemulsion
2.3 Calculation of hydrodynamics properties of the microemulsion
2.4 Interdroplet attractive forces in the cluster of scCO2 microemulsion
3 Applications of scCO2 microemulsion
3.1 Extraction and separation
3.2 Enzyme catalysis
3.3 Preparation of nanomaterials
4 Conclusion and prospects

Key words: supercritical carbon dioxide, microemulsions, reverse micelles, thermodynamic properties

CLC Number: 

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