中文
Earlier issues
Announcement
More
Progress in Chemistry 2009, Vol. 21 Issue (11): 2474-2482 Previous Articles   

• Special issues •

Magnetic Catalysts and Magnetically Stabilized Bed Reactor

Xie Wenhua;  Zong Baoning*   

  1. (State Key Laboratory of Catalytic Materials and Reaction Engineering, Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China)
  • Received: Online: Published:
  • Contact: Zong Baoning E-mail:zongbn@ripp-sinopec.com
PDF ( 1882 ) Cited
Export

EndNote

Ris

BibTeX

A new hydrogenation technology for caprolactam purification using amorphous Ni alloy catalyst and magnetically stabilized bed reactor has been developed by Sinopec. It shows significant advantages in industrial applications. Encouraged by this progress, a series of magnetic catalysts with both high catalytic activity and magnetic properties have been investigated, including amorphous metal alloy, metal oxides, bimetallic catalyst with magnetic metal oxide support and polymer magnetic catalytic materials. They have either metal active sites or proton active sites. Following reactions with these magnetic catalysts in magnetically stabilized reactor are evaluated: (1) hydrogenation of carbon monoxide for removing CO from hydrogen, (2) selective hydrogenation of alkynes in the olefins which are produced from hydrocarbon steam cracking for forming ethylene, (3) olefins oligomerization to produce diesel, (4) magnetic cation resin and isobutene ethterification. Above researches are reviewed in this article. The future development on magnetic catalysts and magnetic stabilized bed reactor is also discussed.

Contents
1 Introduction
2 Magnetically stabilized bed reactor
3 Magnetic catalysts
4 Amorphous Ni alloy catalyst and magnetically stabilized bed reactor
4.1 Amorphous alloy
4.2 Amorphous Ni alloy hydrogenation catalysts
4.3 Process intensification of amorphous Ni alloy and magnetically stabilized bed reactor
5 Magnetic catalysts and magnetically stabilized bed reactor
5.1 Selective hydrogenation of acetylene over a magnetic core-shell Pd catalyst in a magnetically stabilized bed
5.2 Olefins oligomerization over magnetic oxide catalysts in a magnetically stabilized bed
5.3 Etherification over magnetic sulfonic acid resin in a magnetically stabilized bed
6 Prospects

Key words: magnetic catalysts, magnetically stabilized bed reactor, process intensification

CLC Number: 

[ 1 ] 　Liu YA , Hamby R K, Colberg R D. Powder Technology , 1991 , 64(1/2) :3 —41
[ 2 ] 　Tuthill E J , US 3440731 , 1969
[ 3 ] 　Rosensweig R E. US 4115927 , 1978
[ 4 ] 　Rosensweig R E , Ciprios G. US 4668379 , 1987
[ 5 ] 　Rosensweig R E. US 4541924 , 1985
[ 6 ] 　Rosensweig R E. US 4296080 , 1981
[ 7 ] 　Rosensweig R E. Science , 1979 , 204 : 57 —61
[ 8 ] 　Rosensweig R E. FerrohydroDynamics , New York : Cambridge University Press , 1985
[ 9 ] 　Kwauk M S , Ma X H , Ouyang F , Wu Y X, Weng D C , Cheng L N. Chem. Eng. Sci . , 1992 , 47 : 3467 —3474
[10 ] 　胡宗定( Hu Z D) , 吴建勇(Wu J Y) . 化工学报( CIESC Journal) , 1988 , 39 : 121 —126
[11 ] 　朱庆山( Zhu Q S) , 李洪钟(Li H Z) . 化工学报( CIESC Journal) , 1996 , 47 : 53 —58
[12 ] 　朱庆山( Zhu Q S) , 李洪钟(Li H Z) . 化工学报( CIESC Journal) , 1996 , 47 : 59 —64
[13 ] 　郑传根(Zheng C G) . 化学反应工程与工艺(Chemical Reaction Engineering and Technology) , 1990 , 6 : 1 —8
[14 ] 　Hu T T, Wu J Y. Chem. Eng. Res. Des. , 1987 , 65 : 238 —242
[15 ] 　宗保宁(Zong B N) , 慕旭宏(Mu X H) , 孟祥　(Meng X K)等. 化工进展( Chemical Industry and Engineering Progress ) ,2002 , 21 (8) : 536 —539
[16 ] 　孟祥　(Meng X K) , 宗保宁(Zong B N) , 慕旭宏(Mu X H)等. 化学反应过程与工艺(Chemical Reaction Engineering and Technology) , 2002 , 18 (1) : 26 —30
[17 ] 　慕旭宏(Mu X H) , 宗保宁(Zong B N) , 闵恩泽(Min E Z) . 石油学报(Acta Petrolei Sinica) , 1998 , 14 (1) : 41 —45
[18 ] 　孟祥　(Meng X K) . 北京: 石油化工科学研究院博士后研究工作报告(Beijing: Post Doctor Research Report of Research Institute of Petroleum Processing) , 2000
[19 ] 　Berger P , Adelman N B , Beckman K J , Campbell D J , Ellis A B ,Lisenaky G C. J . Chem. Edu. , 1999 , 76 : 943 —948
[20 ] 　Klingerberg D J . AIChE J . , 2001 , 47 : 246 —249
[21 ] 　Gill C S , Price B A , Jones C W. J . Catal , 2007 , 251 : 145 —152
[22 ] 　Mykhaylyk O , Cherchenko A , Ilkin A , Dudchenko N , Ruditsa V.J . Magn. Magn. Mater. , 2001 , 225 : 241 —247
[23 ] 　Lübbe A , Bergemann S C , Brock J , McClure D G. J . Magn. Magn.Mater. , 1999 , 194 : 149 —155
[24 ] 　Weinmann HJ , Ebert W, Misselitz B , Schimtt-Willich H. Eur. J .Radiol . , 2003 , 46 : 33 —44
[25 ] 　Sun S , Murray C B , Weller D , Folks L , Moser A. Science , 2000 ,287 : 1989 —1992
[26 ] 　Takafuji M, Ide S , Ihara H , Xu Z. Chem. Mater. , 2004 , 16 :1977 —1983
[27 ] 　Latham A H , William M E. Acc. Chem. Res. , 2008 , 41 : 411 —420
[28 ] 　Lu A H , Salabas E L , Schüth F. Angew. Chem. Int . Ed. , 2007 ,46 : 1222 —1226
[29 ] 　Wang G H , Harrison A. J . Colloid Interface Sci . , 1999 , 217 :203 —207
[30 ] 　Tartaj P , Morales M P , Gonzalez-Carreno T, Veintemillas-Verdaguer S , Serna C J . J . Magn. Magn. Mater. , 2005 , 290P291 : 28 —34
[31 ] 　Cui L L , Xu H , He P , Sumitomo K, Yamaguchi Y, Gu H C. J .Polym. Sci . A , 2007 , 45 : 5285 —5295
[32 ] 　Abu-Reziq R , Wang D S , Post M, Alper H. Chem. Mater. , 2008 ,20 : 2544 —2550
[33 ] 　Yi D K, Lee S S , Ying J Y. Chem. Mater. , 2006 , 18 : 2459 —2461
[34 ] 　Lu A H , Schmidt W, Matoussevitch N , Bênnermann H , Spliethoff B , Tesche B , Bill E , Kiefer W, Schuth F. Angew. Chem. Int .Ed. , 2004 , 43 : 4303 —4306
[35 ] 　Smith G V , Brower W E. Proc. Int . Congr. Catal . 7th , Tokyo ,1980. 355
[36 ] 　宗保宁(Zong B N) , 闵恩泽(Min E Z) , 董树忠(Dong S Z) ,邓景发(Deng J F) . 化学学报(Acta Chimica Sinica) , 1989 , 47 :1052 —1056
[37 ] 　Duwez P , Willens R H , Klement W. J . Appl . Phys. , 1960 ,31 :1136 —1137
[38 ] 　Molnar A , Smith GV , Bartok M. Advances in Catalysis , 1989 , 36 :329 —367
[39 ] 　梁娟(Liang J ) , 王善均(Wang S J ) . 催化剂新材料(New Catalysis Materials) . 北京: 化学工业出版社(Beijing: Chemical Industry Press) , 1990. 135
[40 ] 　Zhang D C , Zong B N , Jin Z M, Tian M, Min E Z. J . Thermal Anal . , 1993 , 39 (10) : 1331 —1338
[41 ] 　宗保宁(Zong B N) , 闵恩泽(Min E Z) , 朱永山(Zhu Y S) . CN 91111807. 1 , 1991
[42 ] 　Yang Y Y, Song F R , Dai W. Petrochemical Technology , 2001 , 30(supplement) : 26 —30
[43 ] 　Dong M H , Pan Z Y, Meng X K, Mu X H , Zong B N. AIChEJ . ,2008 , 54 (5) : 1358 —1364
[44 ] 　王松汉(Wang S H) , 何细藕( He X O) . 乙烯工艺与技术(Ethylene Technology and Processing) . 北京: 中国石化出版社(Beijing: China Petrochemical Press) , 2000
[45 ] 　邹仁　(Zou R J ) . 石油化工裂解原理与技术(The Principle and Technology of Petroleum and Chemical Pyrolysis) . 北京: 化学工业出版社(Beijing: Chemical Industry Press) , 1982
[46 ] 　Boitiaux J P , Cosyns J . US4490481 , 1984
[47 ] 　Johnson MM, Walker D W, Nowack G P. US4404124 , 1983
[48 ] 　Blankenship S A , Voight R W, Perkins J A , et al . US6509292 ,2003
[49 ] 　Sud2Chemie A G. Chem. Eng. , 2000 , 107 (10) : 19
[50 ] 　彭颖( Peng Y) , 孟祥　(Meng X K) , 宗保宁( Zong B N) .CN200710099559 , 2007
[51 ] 　彭颖( Peng Y) , 孟祥　(Meng X K) , 宗保宁( Zong B N) .CN200810105361. 7 , 2008
[52 ] 　谢文华(Xie W H) , 程萌(Cheng M) , 宗保宁(Zong B N) , 刘强(Liu Q) . CN200710177896. 0 , 2007
[53 ] 　谢文华(Xie W H) , 程萌(Cheng M) , 宗保宁(Zong B N) , 刘强(Liu Q) . CN20081022557015 , 2008
[54 ] 　Pan Z Y, Dong M H , Meng X K, Zhang X X, Mu X H , Zong B N.Chem. Eng. Sci . , 2007 , 62 : 2712 —2717
No related articles found!