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Progress in Chemistry 2009, Vol. 21 Issue (10): 2212-2218 Previous Articles   Next Articles

• Review •

Study of Hydrogen Storage Properties of Lithium Borohydride

Fang Zhanzhao ;   Kang Xiangdong ;   Wang Ping**   

  1. (Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China)
  • Received: Online: Published:
  • Contact: Wang Ping E-mail:pingwang@imr.ac.cn
  • Supported by:

    National Natural Science Foundation of China

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On-board hydrogen storage is generally recognized as the “bottleneck” in promoting the commercialization of hydrogen-powered vehicles. Development of high-performance hydrogen storage materials/technologies for on-board applications is therefore attracting intensive interest of the researchers from both energy and material fields. Recently, lithium borohydride (LiBH4) and other related complex metal hydrides have attracted ever-increasing attention as potential high-capacity hydrogen storage media. The paper reviews the latest progresses made in improving the reversible dehydrogenation of LiBH4 by using various methods, including material composition/reaction pathway tailoring, nanoporous scaffolds incorporation, anion/cation substitution, and catalyst doping, aiming at providing an outline of the key scientific issues and the potential solutions in developing borohydride-based hydrogen storage systems.

Contents
1 Introduction
2 Fundamental physical and chemical properties of LiBH4
3 Improved dehydrogenation/rehydrogenation properties of LiBH4
3.1 reactant destabilization
3.2 nanoporous scaffolds incorporation
3.3 anion/cation substitution
3.4 catalyst modification
4 Conclusion and outlook

Key words: storage hydrogen materials, lithium borohydride, nanostructure, thermodynamics, kinetics

CLC Number: 

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