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Progress in Chemistry 2009, Vol. 21 Issue (10): 2153-2163 Previous Articles   Next Articles

• Review •

Silole Derivatives-Based Electroluminescent Materials

Mao Linyan; Wan Junhua; Li Zhifang; Tao Lan; Qiu Huayu   

  1. (Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 310012, China)
  • Received: Revised: Online: Published:
  • Contact: Qiu Huayu E-mail:huayuqiu@163.com
  • Supported by:

    National Natural Science Foundation of China

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Silole-based π-conjugated compounds and their derivatives have been actively studied as promising electroluminescent materials because of their unique electronic structure (low-lying LUMO level), formed by σ*-π* conjugation. This article summarizes recent progress in the synthesis of silole derivatives and the applications as both emitter and electron-transport materials, respectively by 1,1,2,3,4,5-substituted siloles, silicon-bridged stilbene, dithienosilole, spiro-silole derivatives. This article explains how the silicon to tune up the electronic structure of the heterocyclic systems. The influence of molecular structures achieved by changeing the substitutes on the electronic properties of silole derivatives is discussed in detail. The future research direction of silole derivatives is also mentioned.

Contents
1 Introduction
2 Silole derivatives-based electroluminescent materials
2.1 2,3,4,5-substituted silole derivatives-based electroluminescent materials
2.2 Silicon-bridged stilbene based electroluminescent materials
2.3 Dithienosilole derivatives-based electroluminescent materials
2.4 Spiro-silole derivatives-based electroluminescent materials
3 Conclusion

Key words: silole, σ*-π* conjugation, electroluminescent

CLC Number: 

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