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Progress in Chemistry 2009, Vol. 21 Issue (10): 2132-2152 Previous Articles   Next Articles

• Review •

Assembly and Metal Complex Properties of Terpyridine Ligands

Yuan Sichun1,2**;  Chen Haibo2;  Wang Huichuan1**   

  1. (1. Department of Fundamental Science, Beijing University of Agriculture, Beijing  102206, China; 2. Key Laboratory of Bioorganic and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing  100871, China)
  • Received: Revised: Online: Published:
  • Contact: Yuan Sichun;Wang Huichuan E-mail:ysc2007@sina.com;whch56221@sohu.com
  • Supported by:

    National Natural Science Foundation of China

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Metal-ligand coordination is one of the most important interactions used in supramolecular chemistry. Oligopyridine ligands can coordinate with many transition metal ions and form stable complexes with unique magnetic, photophysical and electrochemical properties, so transition metal complexes based on terpyridine ligands have been attracting considerable attention. This review systematically summarizes the assembly methodologies for terpyridine ligand and its derivatives and the photophysical and photochemical properties of terpyridine transition metal complexes, including monotopic, ditopic and multitopic terpyridine ligands and mononuclear, multinuclear complexes with various topologic structures, such as linear metal oligomers, metallopolymers, metallomacrocyclic compounds and organic-metal dendrimers. Meanwhile, the perspectives in their applications and studies are also emphasized.

Contents
1 Introduction
2 Mononuclear metal complexes
2.1 Assembly strategies and physical properties of mononuclear metal complexes
2.2 Assembly of mononuclear Ru(Ⅱ) complexes
2.3 Photophysical properties of mononuclear Ru(Ⅱ) complexes
2.4 Photophysical properties of other mononuclear metal complexes
3 Multinuclear metal complexes
3.1 Multinuclear linear metallo-oligomers
3.2 Metallopolymers
3.3 Metallopolygons
3.4 3-Dimensional metallomacromolecules
4 Research situations in China
5 Conclusion

Key words: terpyridine ligands, assembly, transition metal complexes, photophysical and photochemical properties

CLC Number: 

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