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Progress in Chemistry 2009, Vol. 21 Issue (10): 2044-2052 Previous Articles   Next Articles

• Review •

Highly Dispersed Supported Co Catalysts for Fischer-Tropsch Synthesis

Shi Yumei;  Yao Nan;  Lu Chunshan;  Fan Yangbo;  Liu Huazhang;  Li Xiaonian**   

  1. (Institute of Industrial Catalysis, College of Chemical Engineering and Materials Science, State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology,  Zhejiang University of Technology, Hangzhou 310032, China)
  • Received: Revised: Online: Published:
  • Contact: Li Xiaonian E-mail:xnli@zjut.edu.cn
  • Supported by:

    National Natural Science Foundation of China

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The supported cobalt is one of important Fischer-Tropsch synthesis (FTS) catalysts, its catalytic activity and selectivity（i.e. CH4%, C5+%）are strongly depended on the metallic Co site dispersion and density. Therefore, increasing metallic Co dispersion and catalyst reducibility provide the effective way to improve Co utilization efficiency and decrease catalyst cost. This paper summarizes the recent progress in highly dispersed supported Co FTS catalyst. We focus on the influences of preparation method, support type and the noble metal promoter on catalyst reducibility and metal dispersion. We also discuss the structural requirements for reaction stability and FTS performance on highly dispersed supported Co catalyst as well as propose some suggestion for supported Co catalyst development.

Contents
1 Introduction
2 The influences of preparation method
3 The influences of support type
3.1 Conventional oxidic supports
3.2 Mesoporous molecular sieve as supports
3.3 Other supports
4 Effects of noble metal promoted effects
5 The influences of metallic Co dispersion on FTS activity, stability and selectivity
6 The conclusion

Key words: Fischer-Tropsch synthesis, supported Co catalyst, metallic Co dispersion, active site property, turnover frequency (TOF)

CLC Number: 

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