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Progress in Chemistry 2009, Vol. 21 Issue (10): 2017-2027 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

Additives of Interphase Film Formation for Lithium Ion Batteries

Xu Mengqing1,2,3;  Xing Lidan1;   Li Weishan1,2,3   

  1. (1. School of Chemistry and Environment, South China Normal University, Guangzhou, 510006, China; 2. Key Lab of Electrochemical Technology on Energy Storage and Power Generation in Guangdong Universities, Guangzhou 510006, China; 3. College of Materials Science and Engineering, South China University of Technology, Guangzhou, 510641, China)
  • Received: Revised: Online: Published:
  • Contact: Li Weishan E-mail:liwsh@scnu.edu.cn
  • Supported by:

    National Natural Science Foundation of China

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The progress on additives of interphase films formed on anode/electrolyte and cathode/electrolyte interphases for lithium ion batteries is reviewed in this paper. On the basis of summarization of the mechanism of SEI film formation on anode surface, the performance of additives is reviewed and evaluated from two different SEI formation mechanisms, modification film mechanism and formation film mechanism, respectively. The drawback and challenge of SEI film formation additives are also illustrated. In addition, the mechanism and the progress of additives on cathode/electrolyte interphase are basically introduced. At the end of the paper, the application of theoretical calculation methods on interphase film is basically reviewed, and the application of theoretical calculation methods on the designation and optimization of new additives is also prospected.

Contents
1 Introduction
2 Progress of formation process and characterization of interphase films
2.1 SEI of anode/electrolyte
2.2 Additives of interphase film formation on cathode/electrolyte
3 The application of theoretical calculation method on interphase film
3.1 The application of theoretical calculation method on the mechanism of interphase film formation
3.2 The application of theoretical calculation method on the mechanism and designation of additives of interphase film formation
4 Conclusion and prospect

Key words: lithium-ion battery, electrode, solid electrolyte interphase(SEI), additives, theoretical calculation

CLC Number: 

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