中文
Earlier issues
Announcement
More
Progress in Chemistry 2009, Vol. 21 Issue (09): 1954-1962 Previous Articles   Next Articles

Special Issue: 金属有机框架材料

• Review •

Metal-Organic Frameworks (MOFs) as Hydrogen Storage Materials

Jia Chao;  |Yuan Xianxia** ; |Ma Zifeng   

  1. （Department of Chemical Engineering, Shanghai Jiao Tong University, Shanghai |200240, China）
  • Received: Revised: Online: Published:
  • Contact: Yuan Xianxia E-mail:yuanxx519@yahoo.com.cn
PDF ( 5960 ) Cited
Export

EndNote

Ris

BibTeX

Hydrogen storage technology is of great importance for hydrogen economy in the 21st century. With the merits of high purity, high crystallization, low cost, large scale productive capability and structure controllable characteristics, metal-organic frameworks (MOFs) have been proved to be very promising in the field of gas storage especially hydrogen storage. In this paper, the research progress of MOFs, including MOF-5, IRMOFs and MMOMs, as hydrogen storage materials in recent years is detailedly reviewed, the structure-modifying technologies for improving hydrogen storage capability of MOFs are systematically introduced, the research progress of theoretical simulation of MOFs as hydrogen storage materials is summarized, and the problems and controversial opinions on hindering the enhancement of hydrogen storage ability of MOFs are pointed out.

Contents
1 Introduction
2 Metal-organic frameworks (MOFs) as hydrogen storage materials
2.1 MOF-5 as hydrogen storage materials
2.2 IRMOFs as hydrogen storage materials
2.3 MMOMs as hydrogen storage materials
2.4 Other modification methods of MOFs as hydrogen storage materials
2.5 Theoretical modeling and prediction of hydrogen storage property of MOFs
3 Conclusion

Key words: metal-organic frameworks (MOFs), hydrogen storage material, central metal ion, organic linker

CLC Number: 

[ 1 ] 　毛宗强(Mao Z Q) , 刘志华(Liu Z H) . 电池(Battery) , 2002 ,32 (3) : 150 —152
[ 2 ] 　Rowsell J L C , Yaghi O M. Microporous Mesoporous Material ,2004 , 73 : 3 —14
[ 3 ] 　Fang S S , Dong YD. Nature , 2001 , 23 (5) : 259 —262
[ 4 ] 　Chae H K, Siberio-PUrez D Y, Yaghi O M, et al . Nature , 2004 ,427 : 523 —527
[ 5 ] 　许炜(Xu W) , 陶占良(Tao Z L) , 陈军(Chen J ) . 化学进展(Progress in Chemistry) , 2006 , 18 : 200 —210
[ 6 ] 　Tomic E A. Journal of Applied Polymer Science , 1965 , 9 : 3745 —3752
[ 7 ] 　Kitagawa S , Kitaura R , Noro S. Angewandte Chemie International Edition , 2004 , 43 : 2334 —2375
[ 8 ] 　Mueller U , Puetter H , Hesse M, et al . WO 20050498922A1 , 2005
[ 9 ] 　王素娜(Wang S N) , 江国庆(Jiang G Q) , 白俊峰(Bai J F)等. 无机化学学报( Chinese Journal of Inorganic Chemistry) ,2005 , 21 (1) : 1 —11
[10 ] 　洪茂椿(Hong M C) , 吴新涛(Wu X T) , 苏伟平(Su W P) 等.化学进展(Progress in Chemistry) , 2003 , 15 (4) : 249 —255
[11 ] 　Bai J F , Virovets A V , Scheer M. Angewandte Chemie International Edition , 2002 , 41 (10) : 1737 —1740
[12 ] 　Bai J F , Leiner E , Scheer M. Angewandte Chemie International Edition , 2002 , 41 (5) : 783 —786
[13 ] 　Yaghi O M, Li H L , Davic C , et al . Accounts of Chemistry Research , 1998 , 31 : 474 —484
[14 ] 　Li HL , Eddaoudi M, Yaghi O M, et al . Nature , 1999 ,402 : 276 —279
[15 ] 　Rosi N L , Eckert J , Eddaoudi M, et al . Science , 2003 , 300 :1127 —1129
[16 ] 　Eddaoudi M, KimJ , Rosi N L , et al . Science , 2002 , 295 : 469 —472
[17 ] 　Pan L , Sander M B , Huang X Y, et al . Journal of American Chemistry Society , 2004 , 126 : 1308 —1309
[18 ] 　Rowsell J L C , Millward A R , Yaghi O M, et al . Journal of American Chemistry Society , 2004 , 126 : 5666 —5667
[19 ] 　Rowsell J L C , Yaghi O M. Journal of American Chemistry Society ,2006 , 128 : 1304 —1315
[20 ] 　Kaye S S , Dailly A , Yaghi O M, et al . Journal of the American Chemistry Society , 2007 , 129 : 14176 —14177
[21 ] 　Furukawa H , Michael M A , Yaghi O M. Journal of Material Chemistry , 2007 , 17 : 3197 —3204
[22 ] 　Rosi N L , Kim J , Yaghi O M. Journal of American Chemistry Society , 2005 , 127 : 1504 —1518
[23 ] 　Panella B , Hirscher M, Müller U , et al . Advanced Functional Materials , 2006 , 16 : 520 —524
[24 ] 　Vishnyakov A , Ravikovitch P I , Neimark A V , et al . Nano Letter ,2003 , 3 : 713 —718
[25 ] 　Wang Q , Johnson J K. Journal of Chemical Physics , 1999 , 110 :577 —586
[26 ] 　Yaghi O M, Keeffe M O , Ockwig N W, et al . Nature , 2003 , 423 :705 —714
[27 ] 　Chen B L , Ockwig N W, Yaghi O M, et al . Angewandte Chemie International Edition , 2005 , 44 : 4745 —4749
[28 ] 　Lee J Y, Pan L , Kelly S P , et al . Advanced Materials , 2005 , 17 :2703 —2706
[29 ] 　Forster P M, Eckert J , Chang J S , et al . Journal of American Chemistry Society , 2003 , 125 : 1309 —1312
[30 ] 　Férey G, Latroche M, Serre C , et al . Chemistry Communication ,2003 , 2976 —2977
[31 ] 　Latroche M, Surble S , Serre C , et al . Angewandte Chemie International Edition , 2006 , 45 : 8227 —8231
[32 ] 　Zhou W, Wu H , Yildirim T. Journal of American Chemistry Society ,2008 , 130 : 15268 —15269
[33 ] 　Wang X S , Ma S Q , Zhou H C. Chemistry of Materials , 2008 , 20 :3145 —3152
[34 ] 　Fang Q R , Zhu GS , Jin Z, et al . Angewandte Chemie International Edition , 2007 , 46 : 6638 —6642
[35 ] 　Xue M, Zhu G S , Li Y Y, et al . Crystal Growth &Design , 2008 ,8 : 2478 —2483
[36 ] 　Li Y Q , Xie L , Li X G, et al . Inorganic Chemistry , 2008 , 47 :10372 —10377
[37 ] 　Wang Y, Cheng P , Yan S P. Inorganic Chemistry , 2007 , 46 :4530 —4534
[38 ] 　Dinca M, Dailly A , Liu Y, et al . Journal of the American Chemistry Society , 2006 , 128 : 16876 —16883
[39 ] 　Dinca M, Long J R. Journal of the American Chemistry Society ,2007 , 129 : 11172 —11176
[40 ] 　Dinca M, Yu A F , Long J R. Journal of the American Chemistry Society ,2006 ,128 : 8904 —8913
[41 ] 　Choi HJ , Dinca M, Long J R. Journal of the American Chemistry Society , 2008 , 130 : 7848 —7850
[42 ] 　Dybtsev D N , Kim D , Kim K, et al . Journal of American Chemistry Society , 2004 , 126 : 32 —33
[43 ] 　Li Y W, Yang R T. AIChE Journal , 2008 , 54 : 269 —279
[44 ] 　Li Y W, Yang R T. Journal of American Chemistry Society , 2006 ,128 : 726 —727
[45 ] 　Li Y W, Yang R T. Journal of American Chemistry Society , 2006 ,128 : 8136 —8137
[46 ] 　Liu Y Y, Zeng J L , Sun L X, et al . International Journal of Hydrogen Energy , 2007 , 32 : 4005 —4010
[47 ] 　Mulfort K L , Hupp J T. Inorganic Chemistry , 2008 , 47 : 7936 —7938
[48 ] 　Han S S , Deng W Q , Goddard W A. Angewandte Chemie International Edition , 2007 , 46 : 6289 —6292
[49 ] 　Han S S , Goddard W A. Journal of Physical Chemistry C , 2008 ,112 : 13431 —13436
[50 ] 　Yang Q Y, Zhong CL. Journal of Physical Chemistry B , 2005 , 109 :11862 —11864
[51 ] 　Chen B L , Ockwig N W, Millward A R , et al . Angewandte Chemie International Edition , 2005 , 44 : 4745 —44749
[52 ] 　Yang Q Y, Zhong CL. Journal of Physical Chemistry B , 2006 , 110 :655 —658
[53 ] 　Zhang L , Wang Q , Liu Y C. Journal of Physical Chemistry B , 2007 ,111 : 4291 —4295
[54 ] 　Li Y W, Yang F H , Yang R T. Journal of Physical Chemistry C ,2007 , 111 : 3405 —3411
[55 ] 　Klontzas E , Mavrandonakis A , Klopper W, et al . Journal of Physical Chemistry C , 2007 , 111 : 13635 —13640
[56 ] 　Buda C , Dunietz B D. Journal of Physical Chemistry B , 2006 , 110 :10479 —10484
[57 ] 　Dalach P , Frost H , Ellis D E , et al . Journal of Physical Chemistry C , 2008 , 112 : 9278 —9284
[1] Zhao Ding, Weijie Yang, Kaifu Huo, Leon Shaw. Thermodynamics and Kinetics Tuning of LiBH4 for Hydrogen Storage [J]. Progress in Chemistry, 2021, 33(9): 1586-1597.
[2] Tingting Gu, Jian Gu, Yu Zhang, Hua Ren. Metal Borohydride-Based System for Solid-State Hydrogen Storage [J]. Progress in Chemistry, 2020, 32(5): 665-686.
[3] Qilu Yao, Hongxia Du, Zhang-Hui Lu. Catalytic Hydrolysis of Ammonia Borane for Hydrogen Production [J]. Progress in Chemistry, 2020, 32(12): 1930-1951.
[4] Jinghao Liu, Xueqian Wu, Yufeng Wu, Jiamei Yu. Computational Study on Adsorption and Separation of C2 and C3 Hydrocarbons by Metal-Organic Frameworks [J]. Progress in Chemistry, 2020, 32(1): 133-144.
[5] Xi Liang, Cheng Wang, Yijie Lei, Yadi Liu, Bo Zhao, Feng Liu. Potential Applications of Metal Organic Framework-Based Materials for Proton Exchange Membrane Fuel Cells [J]. Progress in Chemistry, 2018, 30(11): 1770-1783.
[6] Shiliang Zhang, Qilu Yao, Zhanghui Lu*. Synthesis and Dehydrogenation of Hydrazine Borane [J]. Progress in Chemistry, 2017, 29(4): 426-434.
[7] Guo Ruimei, Bai Jinquan, Zhang Heng, Xie Yabo, Li Jianrong. Metal-Organic Frameworks for Catalytic Oxidation [J]. Progress in Chemistry, 2016, 28(2/3): 232-243.
[8] Li Chao, Fan Meiqiang, Chen Haichao, Chen Da, Tian Guanglei, Shu Kangying. Thermodynamics and Kinetics Modifications on the Li-Mg-N-H Hydrogen Storage System [J]. Progress in Chemistry, 2016, 28(12): 1788-1797.
[9] Zhang Hui, Zhou Yajing, Song Xiaokai. Advanced Functional Materials Derived from Metal-Organic Frameworks [J]. Progress in Chemistry, 2015, 27(2/3): 174-191.
[10] Song Xiaokai, Zhou Yajing, Li Liang. Synthesis of Core-Shell Metal-Organic Frameworks [J]. Progress in Chemistry, 2014, 26(0203): 424-435.
[11] Li Xue, Zhang Yifang, Qi Weihong, Cao Xiaowu, Wang Yuan, Li Haohua. Hydrogen Storage Nanoalloys [J]. Progress in Chemistry, 2013, 25(07): 1122-1130.
[12] Fu Yanyan, Yan Xiuping*. Metal-Organic Framework Composites [J]. Progress in Chemistry, 2013, 25(0203): 221-232.
[13] Liu Bing, Jie Suyun*, Li Bogeng*. Metal-Organic Frameworks for Heterogeneous Catalysis [J]. Progress in Chemistry, 2013, 25(01): 36-45.
[14] Li Linqing, Lv Ying, Li Jun, Dong Xiaoli, Gao Shuang. Application of Metal-Organic Frameworks in Olefin Oxidation [J]. Progress in Chemistry, 2012, 24(05): 747-756.
[15] Xu Shujun, Liang Liyun, Li Buyi, Luo Yali, Liu Chengmei, Tan Bien. Research Progress on Microporous Organic Polymers [J]. Progress in Chemistry, 2011, 23(10): 2085-2094.