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Progress in Chemistry 2009, Vol. 21 Issue (09): 1945-1953 Previous Articles   Next Articles

• Review •

MAlH4(M=Li,Na ) Materials for Hydrogen Storage

Tao Zhanliang**|Chen Jun   

  1. (Institute of New Energy Material Chemistry, Nankai University, Tianjin 300071, China)
  • Received: Revised: Online: Published:
  • Contact: Tao Zhanliang E-mail:taozhl@nankai.edu.cn
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Hydrogen is an environmentally cleaner source of energy, hopeful to replace carbon economy. The availability of feasible methods for hydrogen storage is one of the keys for large scale application. In recent years, solid materials most actively investigated can be regarded for their high hydrogen storage capacity and good reversibility. As a result, many new hydrogen storage materials have been developed. Among them, one of the most promising systems at present is metal complex hydride, which MAlH4(M=Li, Na) as a typical alanate. In this paper, the recent studies on MAlH4(M=Li, Na) as storage hydrogen materials are reviewed. The hydrogenation/dehydrogenation reaction, hydrogen storage properties, reaction mechanisms, theoretical calculations and remaining problems are discussed. And the development trend of MAlH4(M=Li, Na) is also introduced.

Contents
1 Introduction
2 Properties and structures of MAlH4 (M=Li,Na)
3 De-/rehydrogenation of undoped MAlH4 (M=Li,Na)
4 De-/rehydrogenation of doped MAlH4 (M=Li,Na)
4.1 Dopants and doping methods of MAlH4 (M=Li,Na)
4.2 Catalysis mechanism of doped MAlH4 (M=Li,Na)
4.3 Theoretical investigation of MAlH4 (M=Li,Na)
4.4 Kinetic properties of doped NaAlH4
5 Summary and outlook

Key words: storage hydrogen materials, metal complex hydrides, alanates, catalysis, reaction mechanisms

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