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Progress in Chemistry 2009, Vol. 21 Issue (09): 1939-1944 Previous Articles   Next Articles

• Review •

Enzymatic Approach for 1, 3-Diacylglycerol Preparation

Duan Zhangqun|Du Wei*|Liu Dehua*   

  1. (Institute of Applied Chemistry, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China)
  • Received: Revised: Online: Published:
  • Contact: Du Wei; Liu Dehua E-mail:duwei@tsinghua.edu.cn; dhliu@tsinghua.edu.cn
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It has been shown recently that consumption of 1,3-Diacylglycerol(1,3-DAG) oil has beneficial effects on the suppressing the accumulation of body fat and preventing the increase of body weight. However, because of the minor content of 1,3-DAG in natural form, the synthesis of 1,3-DAG has become more significant. Chemical methods and enzymatic approach can be used for 1,3-DAG preparation. By comparison, there are many advantages associated with enzymatic approach: the reaction can be carried out under mild conditions, the process is environmentally friendly and high quality product can be achieved. Therefore, more and more attention have been paid to the enzymatic method for 1,3-DAG production in recent years. This review covers the aspects of enzyme-mediated catalysis for 1,3-DAG, and also suggests that reducing the cost and prolonging the lifetime of the enzyme can promote enzyme-mediated production of 1,3-DAG on industrial scale.

Contents
1 Introduction
2 Lipases for 1,3-DAG preparation
3 Methods for 1,3-DAG preparation
3.1 Esterification
3.2 Partial hydrolysis
3.3 Partial alcoholysis
3.4 Glycerolysis
3.5 Hydrolysis or alcoholysis followed by esterification
3.6 Other methods
4 Enzyme reactors for 1,3-DAG production
5 Conclusion and prospects

Key words: 1,3-DAG, lipases, esterfication, transesterification

CLC Number: 

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