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Progress in Chemistry 2009, Vol. 21 Issue (09): 1880-1887 Previous Articles   Next Articles

• Review •

Preparation of Magnetic Hybrid Nanoparticles via Surface-Initiated Polymerization from Magnetite

Zhou Lilin; |Kuang Jinming; |Yuan Jinying**   

  1. (Key Laboratory of Organic Optoelectronics and Molecular Engineering of the Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China)
  • Received: Revised: Online: Published:
  • Contact: Yuan Jinying E-mail:yuanjy@mail.tsinghua.edu.cn
  • Supported by:

    National Natural Science Foundation of China

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Magnetic hybrid nanoparticles have superparamagnetism from magnetite and lots of special properties from polymer parts, such as biocompatibility, stimuli-responsivity, fluorescence, and the dispersion of hybrid nanoparticles, are obviously improved compared to that of magnetite. The research of magnetic hybrid nanoparticles have been intensively pursued because of their potential application in biomedicine, catalysis, separation and other fields. In this paper, the research progress of the preparation of magnetic hybrid nanoparticles via surface-initiated polymerization is reviewed from polymerization mechanism, including traditional radical polymerization, atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide-mediated radical polymerization (NMRP), and ring-opening polymerization (ROP).

Contents
1 Introduction
2 Preparation of magnetic hybrid nanoparticles via surface-initiated polymerization from magnetite
2.1 Traditional radical polymerization
2.2 Living polymerization
3 Conclusion and prospects

Key words: magnetite, surface-initiated polymerization, superparamagnetism, hybrid materials

CLC Number: 

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