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Progress in Chemistry 2009, Vol. 21 Issue (09): 1839-1846 Previous Articles   Next Articles

• Review •

Synthesis of Novel Mesoporous Solid Bases

Sun Linbing1** ; |Liu Xiaoqin1;  Liu Dinghua1;  Chun Yuan2; Zhu Jianhua2   

  1. (1. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing 210009, China；2. School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China)
  • Received: Revised: Online: Published:
  • Contact: Sun Linbing E-mail:lbsun@njut.edu.cn
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Mesoporous solid bases can catalyze diverse reactions with a low cost and reduce the production of pollutants. They are promising to take the place of liquid bases and are significant for the development of environmentally benign catalytic processes. The rapid development of mesoporous materials provides an opportunity for the research and preparation of mesoporous solid bases. Up to now, a series of mesoporous solid bases have been successfully synthesized by various methods. In the present paper, the approaches for generating basic sites on different mesoporous hosts, i.e. silica, alumina, zirconia, and carbon, are reviewed. The structures, properties, and catalytic performances of resulting basic materials are described. On the basis of these results, the different synthesis methods are evaluated and the mechanisms of basicity generation are clarified. Finally, the development tendency of mesoporous solid bases is proposed.

Contents
1 Introduction
2 Generating basic sites on mesoporous silica
2.1 Nitrogen doping
2.2 Grafting organic base
2.3 Functionalization with inorganic basic species
2.4 Formation of superbasicity by multicoating
3 Solid bases derived from mesoporous alumina host
3.1 SO42- ions modified mesoporous alumina
3.2 Depositing metal sodium
3.3 One-pot synthesis of potassium-functionalized mesoporous γ-Al2O3
4 Basic species modified mesoporous zirconia and carbon
4.1 Employing mesoporous zirconia as a host
4.2 Employing mesoporous carbon as a host
5 Conclusion and outlook

Key words: mesoporous solid bases, host, basicity generation, mesoporous silica, mesoporous alumina

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Abstract

Synthesis of Novel Mesoporous Solid Bases