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Progress in Chemistry 2009, Vol. 21 Issue (09): 1800-1806 Previous Articles   Next Articles

• Review •

Dissolution of Cellulose in Novel Green Solvent Ionic Liquids and Its Application

Liu Chuanfu** ;  |Zhang Aiping ; |Li Weiying  |Sun Runcang   

  1. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China)
  • Received: Revised: Online: Published:
  • Contact: Liu Chuanfu E-mail:chfliu@scut.edu.cn
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Ionic liquids as a class of promising solvents have attracted much attention in recent years. Cellulose is the most abundant bio-renewable resource in the world and would be the most promising feedstock for industry in the future. Dissolution of cellulose in ionic liquids combines two major green chemistry principles, using environmentally preferable solvents and bio-renewable feedstocks, and has opened a novel platform for the green utilization of cellulose materials. The progress in dissolution of cellulose with ionic liquids and its application for the preparation of regenerated cellulose composites, cellulose derivatives, and bio-ethanol are reviewed. More scrutinized studies on the fundamentals, such as the mechanism of dissolution and degradation of cellulose macromolecules, transformation of cellulose crystalline structure, and the homogeneous chemical modification of cellulose with solid reagents, have to be further investigated to develop new bio-polymers and prosper the industry.

Contents
1 Introduction
2 Dissolution of cellulose in ionic liquids
3 Preparation of regenerated cellulose composites in ionic liquids
4 Preparation of cellulose derivatives in ionic liquids
5 Application of ionic liquids in the preparation of bio-ethanol from cellulosic resources
6 Prospects

Key words: cellulose, ionic liquids, dissolution, regenerated cellulose composites, cellulose derivatives, bioethanol

CLC Number: 

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