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Progress in Chemistry 2009, Vol. 21 Issue (09): 1792-1799 Previous Articles   Next Articles

• Review •

Ionic Liquids for the Electrosyntheses of Conducting Polymers

Dong Bin1,2; |Xu Jingkun1**; |Zheng Liqiang2**   

  1. (1.Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, 330013, Nanchang, China|2.Key Laboratory of Colloid and Interface Chemistry of Education Ministry, Shandong University, Jinan 250100, China)
  • Received: Revised: Online: Published:
  • Contact: Xu Jingkun;Zheng Liqiang E-mail:xujingkun@tsinghua.org.cn;lqzheng@sdu.edu.cn
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Since the discovery of conducting polymers in 1970s, they have attracted much attention due to their novel electronic, electrochemical and optical properties, as well as their promising applications. Typical examples are polypyrrole (PPy), polyaniline (PANI), polythiophene (PTh), poly(3,4-ethylenedioxythiophene) (PEDOT), and poly(p-phenylene) (PPP). Ionic liquids (ILs), a class of organic molten electrolytes at or near ambient temperature, are novel environmentally benign “green solvents” and have remarkable physicochemical properties. This paper reviews the research progress of ionic liquids for the electrosyntheses of conducting polymers, including the use of ionic liquids as growth media or supporting electrolytes to electrosynthesize and test the electrochemical behaviors of conducting polymers, and the use of the aggregations composed of ionic liquids (e.g. ionic liquid microemulsions) as novel electrolytes. The trend for future research is also prospected.

Contents
1 Introduction
2 Ionic liquids as growth media
2.1 Polypyrrole and its derivatives
2.2 Polyaniline and its derivatives
2.3 Polythiophene and its derivatives
2.4 Poly(3,4-ethylenedioxythiophene) and its derivatives
2.5 Poly(p-phenylene)
2.6 Co-polymerization of conducting polymers
3 Ionic liquids as supporting electrolytes
4 Ionic liquids as testing media
5 Aggregations composed of ionic liquids as growth media
6 Conclusion

Key words: ionic liquids, conducting polymers, electrosyntheses

CLC Number: 

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