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Progress in Chemistry 2009, Vol. 21 Issue (09): 1782-1791 Previous Articles   Next Articles

• Review •

Green Organic Reactions in Phosphonium Salt Ionic Liquid Media

Huang Qiang1** ;  |Wang Lili2 ;  |Zheng Baozhong1 ;   |Long Quan3   

  1. (1.Departemnt of Materials Science and Engineering, Yunnan University, Kunming 650091, China；2. School of Life Science, Ynnan Normal University, Kunming 650092, China|3.School of Chemical Science and Engineering, Yunnan University, Kunming 650091, China)
  • Received: Revised: Online: Published:
  • Contact: Huang Qiang E-mail:huangqiang@ynu.edu.cn
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Compared with the ammonium-type ionic liquids, phosphonium-based ionic liquids (PILs)have the advantages as less volatility, more stable physical and chemical properties, and combining solvent and catalytic function. Recently, PILs are considered with a growing emphasis as green reactive media. Many types of organic reactions are performed in PILs and some good effects are exhibited. This article focuses mainly on the preparation of PILs and the green organic reactions carried out in PILs, mostly adopting the pioneering work and some selected journal’s examples since the year of 2000. These reactions include Diels-Alder, Heck, Suzuki, Buchwald-Hartwig, Friedel-Crafts, Kornblum substitution, Grignard, carbonylation, transfer hydrogenation, hydroformylation, esterification reactions, etc. PILs media takes on a mumber of express advantages especially for some reactions which involve strong base conditions or electrophilic substitutions.

Contents
1 Introduction
2 Preparation of phosphonium-based ionic liquids
2.1 Quaternary phosphonium salt with haloid anions
2.2 Quaternary phosphonium salt with non-haloid anions
2.3 Chiral phosphonium ionic liquids
2.4 Others
3 Green organic reactions in PILs
3.1 Diels-Alder reaction
3.2 Hydroformylation
3.3 Electrophilic substitution
3.4 Kornblum substitution
3.5 C-C coupling reaction
3.6 Buchwald-Hartwig reaction
3.7 Carbonylation
3.8 Grignard reaction
3.9 Reduction
3.10 Miscellaneous reactions
4 Concluding remarks

Key words: quaternary phosphonium salt, ionic liquids, organic reactions, green chemistry

CLC Number: 

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