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Progress in Chemistry 2009, Vol. 21 Issue (09): 1763-1771 Previous Articles   Next Articles

• Review •

Self-Assembled Fabrication, Photochemical and Electrochemical Properties of Macrocyclic Metallosupramolecules Based on Conjugated Terpyridine and Transition Metal Ions

Pan Yuexiu1;Tong Bin1; |Zhi Junge2|Zhao Wei1|Shen Jinbo1|Dong Yuping1**   

  1. (1. College of Materials Science &|Engineering| Beijing Institute of Technology| Beijing 100081| China；2. College of Science| Beijing Institute of Technology| Beijing 100081| China)
  • Received: Revised: Online: Published:
  • Contact: Dong Yuping E-mail:chdongyp@bit.edu.cn
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The polygonal cyclic metallosupramolecules based on 2,2':6',2"-terpyridine and transition metal ions are a new class of rigid oligomers which possess unique structural, electronic, and physical characteristics. Construction of highly ordered, regularly repeating molecular architectures through self-assembly techniques is of interest from a variety of supramolecular perspectives, which leads to utilitarian applications in molecular electronics, catalysis, luminescence, advanced drugs, nanoscale structures and devices, and crystal engineering. This review focuses on the synthesis, photochemical and electrochemical properties of the special class of the full-conjugated polygonal macrocyclic metallosupramolecules. The problems existed in this research field and possible prospects are also discussed.

Contents
1 Introduction
2 Conjugated Coordinate self-assembly supramolecular metallomacrocycles of terpyridine and transition metal ions
2.1 Triangle
2.2 Quadrangle
2.3 Pentagon
2.4 Hexagon
3 Perspects

Key words: conjugated terpyridine, polygonal macrocyclic metallosupramolecules, coordinate self-assembly, photochemical properties, electrochemical properties

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[ 1 ] 　Mihailovic A , Vladescu L , McCauley M, et al . Langmuir , 2006 , 22(10) : 4699 —4709
[ 2 ] 　Besker N , Coletti C , Marrone A , et al . J . Phys. Chem. B , 2007 ,111 (33) : 9955 —9964
[ 3 ] 　Baranoff E , Collins J P , Flamigni L , et al . Chem. Soc. Rev. ,2004 , 33 (3) : 147 —155
[ 4 ] 　Chan W K. Coordin. Chem. Rev. , 2007 , 251 : 2104 —2118
[ 5 ] 　Hofmeier H , Schubert U S. Chem. Soc. Rev. , 2004 , 33 ( 6) :373 —399
[ 6 ] 　Biani F F , Grigiotti E , Laschi F , et al . Inorg. Chem. , 2008 , 47(12) : 5425 —5440
[ 7 ] 　Man K Y K, Wong H L , Chan W K, et al . Chem. Mater. , 2004 ,16 (3) : 365 —367
[ 8 ] 　巢晖(Chao H) , 高峰( Gao F) , 计亮年(Ji L N) . 化学进展(Progress in Chemistry) , 2007 , 19 (12) : 1844 —1851
[ 9 ] 　Eryazici I , Moorefield C N , Newkome G R. Chem. Rev. , 2008 ,108 (6) : 1834 —1895
[10 ] 　Morgan G T, Burstall F H. J . Chem. Soc. , 1932 , 20 —30
[11 ] 　Kelch S , Rehahn M. Macromolecules , 1999 , 32 (18) : 5818 —5828
[12 ] 　Constable E C , Cargill T, Tocher D A. J . Chem. Soc. Dalton.Trans. , 1992 , 3467 —3475
[13 ] 　Constable E C , Cargill T, Tocher D A. Macromol . Symp. , 1994 ,77 : 219 —228
[14 ] 　Grosshenny V , Romero F M, Ziessel R. J . Org. Chem. , 1997 , 62(5) : 1491 —1500
[15 ] 　Schütte M, Kurth D G, Linford M R. Angew. Chem. Int . Ed. ,1998 , 37 (20) : 2891 —2893
[16 ] 　Tomohiko H , Yoshimasa I , Kikujiro U , et al . Polyhedron , 2008 , 27(8) : 2031 —2034
[17 ] 　Kristi O , McLaughlin RL , Williams M E. Inorg. Chem. , 2007 , 46(3) : 965 —974
[18 ] 　Poddutoori P K, Poddutoori P , Maiya B G, et al . Inorg. Chem. ,2008 , 47 (17) : 7512 —7522
[19 ] 　Beves J E , Constable E C , Housecroft C E , et al . Polyhedron ,2008 , 27 (11) : 2395 —2401
[20 ] 　Veauthier J M, Schelter E J , John K D , et al . Inorg. Chem. ,2008 , 47 (13) : 5841 —5849
[21 ] 　Harriman A , Ziessel R. Chem. Commun. , 1996 , 1707 —1716
[22 ] 　Shunmugam R , Tew GN. Chem. Eur. J . , 2008 , 14 (13) : 5409 —5412
[23 ] 　Shunmugam R , Tew G N. Polym. Adv. Technol . , 2008 , 19 (6) :596 —601
[24 ] 　Berthet J C , Thuery P , Dognon J P , et al . Inorg. Chem. , 2008 , 47(15) : 6850 —6862
[25 ] 　Gou L , Wu Q R , Hu H M, et al . Inorg. Chim. Acta , 2008 , 361(7) : 1922 —1928
[26 ] 　Kadjane P , Charbonnière L , Ziessel R. J . Fluoresc. , 2008 , 18(1) : 119 —129
[27 ] 　Padhi S K, Saha D , Manivannan V , et al . Polyhedron , 2008 , 27(6) : 1714 —1720
[28 ] 　Ikoma T, Oshio H , Yamamoto M, et al . J . Phys. Chem. A , 2008 ,112 (37) : 8641 —8648
[29 ] 　Lin X F , Phillips D L. J . Org. Chem. , 2008 , 73 (10) : 3680 —3688
[30 ] 　Du P W, Schneider J , Castellano F N , et al . J . Am. Chem. Soc. ,2008 , 130 (15) : 5056 —5058
[31 ] 　Huang W, Qian H F. J . Mol . Struct . , 2008 , 874 : 64 —76
[32 ] 　Constable E C , Housecroft C E , Neuburger M, et al . Polyhedron ,2008 , 27 (1) : 65 —70
[33 ] 　Ievins A D , Moughton A O , O’Reilly R K. Macromolecules , 2008 ,4 (10) : 3571 —3578
[34 ] 　Kurth D G, Osterhout R. Langmuir , 1999 , 15 (14) : 4842 —4846
[35 ] 　Kurth D G, Schutte M, Wen J . Colloid Surface A: Physico. Chem.Eng. Aspects , 2002 , 198 : 633 —643
[36 ] 　Caruso F , Schuler C , Kurth D G. Chem. Mater. , 1999 , 11 (11) :3394 —3399
[37 ] 　Kurth D G, Nikolai S , Rabe J P. Angew. Chem. Int . Ed. , 2002 ,41 (19) : 3681 —3683
[38 ] 　Kurth D G, Meister A , Thunemann A F , Forster G. Langmuir ,2003 , 19 (10) : 4055 —4057
[39 ] 　Lehmann P , Kurth D G, Brezesinski G, Symietz C. Chem. Eur.J . , 2001 , 7 (8) : 1646 —1651
[40 ] 　Liu B , Huang H X, Zhang C F , et al . Thin Solid Films , 2008 , 516(8) : 2144 —2150
[41 ] 　Bodenthin Y, Pietsch U , Kurth D G, et al . J . Am. Chem. Soc. ,2005 , 127 : 3110 —3115
[42 ] 　Bodenthin Y, Pietsch U , Kurth D G, et al . J . Phys. Chem. B ,2005 , 109 (26) : 12795 —12799
[43 ] 　Yamanoi Y, Nishihara H. Chem. Commun. , 2007 , 3983 —3989
[44 ] 　Kanaizuka K, Murata M, Nishihara H , et al . Chem. Lett . , 2005 ,34 (4) : 534 —535
[45 ] 　Nishimori Y, Kanaizuka K, Nishihara H , et al . Chem. Asian J . ,2007 , 2 (3) : 367 —376
[46 ] 　Kosbar L , Srinivasan C. Langmuir , 2006 , 22 (18) : 7631 —7638
[47 ] 　Battocchio C , Polzonetti G, Gambino L , et al . Nucl . Instr. Meth.Phys. Res. B , 2006 , 246 (1) : 145 —150
[48 ] 　Haensch C , Ott C , Hoeppener S , Schubert U S. Langmuir , 2008 ,24 (18) : 10222 —10227
[49 ] 　Hwang S H , Moorefield C N , Dai L M, Newkome G R. Chem.Mater. , 2006 , 18 (17) : 4019 —4024
[50 ] 　Rotas G, Sandanayaka A S D , Tagmatarchis N , et al . J . Am.Chem. Soc. , 2008 , 130 (14) : 4725 —4731
[51 ] 　Du C , Li Y, Wang S , et al . Synth. Met . , 2001 , 124 (2/3) : 287 —289
[52 ] 　Chen H Y, Tagore R , Crabtree R H , et al . Inorg. Chem. , 2007 ,46 (1) : 34 —43
[53 ] 　Jain A , Slebodnick C , Winkel B S J , et al . J . Inorg. Biochem. ,2008 , 102 (10) : 1854 —1861
[54 ] 　Mukkala V M, Helenius M, Takalo H , et al . Helv. Chim. Acta ,1993 , 76 (3) : 1361 —1363
[55 ] 　Fallahpour R A. Eur. J . Inorg. Chem. , 1998 , 1205 —1207
[56 ] 　Eryazici I , Moorefield C N , Newkome G R. J . Org. Chem. , 2006 ,71 (3) : 1009 —1014
[57 ] 　Winter A , Egbe D A M, Schubert U S. Org. Lett . , 2007 , 9 (12) :2345 —2348
[58 ] 　Schmittel M, Kalsani V S , Mal P J , et al . Inorg. Chem. , 2006 , 45(16) : 6370 —6377
[59 ] 　Alexander M W, Cargell T. Coord. Chem. Rev. , 1997 , 160 : 1 —52
[60 ] 　Diaz D J , Bernhand S , Abruna H D. J . Phys. Chem. B , 2001 ,105 : 8746 —8754
[61 ] 　Romero F M, Ziessel R , Dupont-Gervais A , et al . Chem.Commun. , 1996 , 551 —553
[62 ] 　Ziessel R. Synthesis , 1999 , 1839 —1865
[63 ] 　Hwang S H , Moorefieid C N , Newkome G R , et al . Chem.Commun. , 2005 , 713 —715
[64 ] 　Würthner F , You C C , Saha-Mê ller C R. Chem. Soc. Rev. , 2004 ,33 (3) : 133 —146
[65 ] 　Constable E C. Coord. Chem. Rev. , 2008 , 252 : 842 —855
[66 ] 　Chow H S , Constable E C , Housecroft C E , et al . Polyhedron ,2006 , 25 (8) : 1831 —1843
[67 ] 　Philp D , Stoddart J F. Angew. Chem. , 1996 , 35 (11) : 1155 —1196
[68 ] 　Constable E C , Schofield E. Chem. Commun. , 1998 , 403 —404
[69 ] 　Kurth D G, Lopez J P , Dong W F. Chem. Commun. , 2005 ,2119 —2121
[70 ] 　Constable E C , Dunphy E L , Housecroft C E , et al . Chem. Eur.J . , 2006 , 12 (17) : 4600 —4610
[71 ] 　Eryazici I , Newkome G R. Dalton Trans. , 2007 , 626 —628
[72 ] 　Goshe A J , Bosnich B. Synlett , 2001 , 941 —944
[73 ] 　Sommer R D , Rheingold A L , Goshe A J , Bosnich B. J . Am.Chem. Soc. , 2001 , 123 (17) : 3940 —3952
[74 ] 　Fujita M, Yazaki J , Ogura K. J . Am. Chem. Soc. , 1990 , 112(14) : 5645 —5647
[75 ] 　Fujita M, Yazaki J , Ogura K. Chem. Lett . , 1991 , 6 : 1031 —1032
[76 ] 　Drain C M, Lehn J M. J . Chem. Soc. Chem. Commun. , 1994 ,2313 —2315
[77 ] 　Chi X, Guerin A J , Haycock R A , et al . J . Chem. Soc. Chem.Commun. , 1995 , 2567 —2569
[78 ] 　Fan J , Whiteford J A , Fleischer E B , et al . J . Am. Chem. Soc. ,1999 , 121 (12) : 2741 —2752
[79 ] 　Constable E C , Cargill T A M W. J . Chem. Soc. Dalton. Trans. ,1994 , 1409 —1418
[80 ] 　Sun S S , Silva A S , Lees AJ , et al . Inorg. Chem. , 2000 , 39 (7) :1344 —1345
[81 ] 　Sun S S , Lees A J . Inorg. Chem. , 2001 , 40 (13) : 3154 —3160
[82 ] 　Ipaktschi J , Hosseinzadeh R , Schlaf P. Angew. Chem. Int . Ed. ,1999 , 38 (11) : 1658 —1660
[83 ] 　Zhang F , Vill V , Heck J . Organometallics , 2004 , 23 (16) : 3853 —3864
[84 ] 　Hwang S H , Moorefield C N , Newkome G R , et al . Chem.Commun. , 2005 , 4672 —4674
[85 ] 　Newkome G R , Cho T J , Moorefield C N , et al . Angew. Chem.Int . Ed. , 1999 , 38 (24) : 3717 —3721
[86 ] 　Newkome G R , Cho TJ , Moorefield C N. Chem. Eur. J . , 2002 , 8(13) : 2946 —2954
[87 ] 　Wang P , Newkome G R , Wesdemiotis C. Int . J . Mass Spectrom. ,2006 , 255 : 86 —92
[88 ] 　Newkome G R , Cho T J , Moorefield C N. Chem. Eur. J . , 2004 ,10 (6) : 1493 —1500
[89 ] 　Hwang S H , Moorefield C N , Newkome G R , et al . Dalton Trans. ,2006 , 3518 —3522
[90 ] 　Hwang S H , Newkome G R. Macromol . Rapid Commun. , 2006 , 27(21) : 1809 —1813
[91 ] 　Hwang S H , Moorefield C N , Newkome G R. Inorg. Chim. Acta ,2007 , 360 (5) : 1780 —1784
[92 ] 　Bhattacharyya S , Kymakis E , Amaratunga G A. J . Chem. Mater. ,2004 , 16 : 4819 —4823
[93 ] 　Balasubramanian K, Burghard M. Small , 2005 , 1 (2) : 180 —192
[94 ] 　Newkome G R , Wang P S , Moorefield C N , et al . Science , 2006 ,312 (5781) : 1782 —1785
[95 ] 　Li S N , Moorefield C N , Newkome G R , et al . Eur. J . Org.Chem. , 2008 , 19 : 3328 —3334
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