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Progress in Chemistry 2009, Vol. 21 Issue (09): 1757-1762 Previous Articles   Next Articles

• Review •

Mechanisms of Methanol-to-Olefin Reaction

Yu Xianbo ; |Liu Ye ; |Yang Yongrong ; |Wang Jingdai*   

  1. (State Key Laboratory of Chemical Engineering, Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China)
  • Received: Revised: Online: Published:
  • Contact: Wang Jingdai E-mail:wangjd@cmsce.zju.edu.cn
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Researches in mechanism for methanol-to-olefin (MTO) reaction are reviewed in this paper. Five reaction steps, the equilibrium between methanol and dimethyl ether, induction period, post-induction period, secondary reaction and deactivation, are introduced as well as the reaction types in each step. The main mechanism models and their experimental proofs are concluded. The mechanism models, especially the direct mechanism and the hydrocarbon pool theory, are discussed in detail in each reaction step. The hydrocarbon pool theory is thought as the one that can better explain the MTO reaction based on the experimental proof. Meanwhile the research methods, both theoretic and experimental are also reviewed in this paper.

Contents
1 Introduction
2 Mechanisms of methanol to olefin reaction
2.1 Equilibrium between methanol and dimethyl ether
2.2 Induction period
2.3 Post-induction period
2.4 Secondary reaction
2.5 Deactivation
3 Conclusion

Key words: methanol-to-olefins(MTO), mechanisms, hydrocabon pool

CLC Number: 

[ 1 ] 　Meisel S L , McCullough J P , Lechthaler C H , et a1. Chemtech. ,1976 , 6 : 86 —89
[ 2 ] 　Chang C D , Silvestri A J . J . Catal . , 1977 , 47 : 249 —259
[ 3 ] 　Chang C D. Catal . Today , 1992 , 13 : 103 —111
[ 4 ] 　Cosyns J , Chodorge J , Commereuc D. Hydrocarbon Processing ,1998 , 1 : 28 —29
[ 5 ] 　HawJ F , Song W G, Marcus D M, et al . Acc. Chem. Res. ,2003 , 36 : 317 —326
[ 6 ] 　Stêcker M. Microporous Mesoporous Mater. , 1999 , 29 : 3 —48
[ 7 ] 　Chang C D. Catal . Rev. , 1983 , 25 : 1 —118
[ 8 ] 　Keil F J . Microporous Mesoporous Mater. , 1999 , 29 : 49 —66
[ 9 ] 　Wilson S , Barger P. Microporous Mesoporous Mater. , 1999 , 29 :117 —126
[10 ] 　Olsbye U , Bjorgen M, Svelle S. Catalysis Today , 2005 , 106 (1/4) :108 —111
[11 ] 　Lesthaeghe D , Speybroeck V V , Marin G B. Ind. Eng. Chem.Res. , 2007 , 46 : 8832 —8838
[12 ] 　胡浩(Hu H) , 叶丽萍(Ye L P) , 应卫勇(Ying W Y) 等. 工业催化( Industrial Catalysis) , 2008 , 16 (3) : 18 —23
[13 ] 　Chang C D , Howe R F , Yurchak S. Methane Conversion.Amsterdam: Elsevier , 1988. 127
[14 ] 　Salvador P , Kladnig W. J . Chem. Soc. Faraday Tyans. 1 , 1977 ,73 : 1153 —1168
[15 ] 　NovákováJ , KubelkováL , Dolejˇsek Z. J . Catal . , 1987 , 108 :208 —213
[16 ] 　Forester T R , Howe R F. J . Am. Chem. Soc. , 1987 , 109 : 5076 —5082
[17 ] 　Kupelková L , Nováková J , Nedomová K. J . Catal . , 1990 , 124 :441 —450
[18 ] 　Murray D K, Chang J W, Haw J F. J . Am. Chem. Soc. , 1993 ,115 : 4732 —4741
[19 ] 　Salehirad F , Anderson M W. J . Catal . , 1998 , 177 : 189 —207
[20 ] 　Wang W, Seiler M, Hunger M. J . Phys. Chem. B , 2001 , 105(50) : 12553 —12558
[21 ] 　Wang W, Buchholz A , Hunger M, et a1. J . Am. Chem. Soc. ,2003 , 125 : 15260 —15267
[22 ] 　Wang W, Jiang Y, Hunger M. Catal . Today , 2006 , 113 : 102 —114
[23 ] 　Jiang Y, Hunger M, Wang W. J . Am. Chem. Soc. , 2006 , 128(35) : 11679 —11692
[24 ] 　Wang W, Hunger M. Acc. Chem. Res. , 2008 , 41 (8) : 895 —904
[25 ] 　徐柏庆(Xu P Q) , 梁娟(Liang J ) , 陈国权(Chen G Q) 等. 催化学报(Chinese Journal of Catalysis) , 1991 , 12 (4) : 273 —280
[26 ] 　Dessau R M. J . Catal . , 1986 , 99 : 111 —116
[27 ] 　Cui Z M, Liu Q , Song W G, et al . J . Phys. Chem. C , 2008 , 112 :2685 —2688
[28 ] 　Langner B E. Appl . Catal . , 1982 , 2 : 289 —302
[29 ] 　Song W G, Marcus D M, Haw J F , et al . J . Am. Chem. Soc. ,2002 , 124 : 3844 —3845
[30 ] 　Van den Berg J P , Wolthuizen J P , van Hooff J H C. Proceedings 5th International Zeolite Conference ( Ed. Rees L V) , London , 1980.649
[31 ] 　Munson E J , Haw J F. J . Am. Chem. Soc. , 1991 , 113 : 6303 —6305
[32 ] 　Ono Y, Mori T. J . Chem. Soc. Faraday Trans. 1 , 1981 , 77 :2209 —2221
[33 ] 　Chang C D , Hellring S D , Pearson J A. J . Catal . , 1989 , 115 :282 —285
[34 ] 　Cui Z M, Liu Q , Song W G. Angew. Chem. Int . Ed. , 2006 , 45 :6512 —6515
[35 ] 　Marcus D M, McLachlan KA , HawJ F , et al . Angew. Chem. Int .Ed. , 2006 , 45 : 3133 —3136
[36 ] 　Lesthaeghe D , van Speybroeck V , Marin GB. Angew. Chem. Int .Ed. , 2006 , 45 : 1714 —1719
[37 ] 　Mole T, Bett G, Seddon D. J . Catal . , 1983 , 84 : 435 —445
[38 ] 　Kolboe S. Acta Chem. Scand. , 1986 , A40 : 711 —713
[39 ] 　Dahl I M, Kolboe S. Catal . Lett . , 1993 , 20 : 329 —336
[40 ] 　Dahl I M, Kolboe S. J . Catal . , 1994 , 149 : 458 —464
[41 ] 　Dahl I M, Kolboe S. J . Catal . , 1996 , 161 : 304 —309
[42 ] 　Goguen P W, Xu T, Barich D H , Haw J F , et al . J . Am. Chem.Soc. , 1998 , 120 : 2650 —2651
[43 ] 　Xu T, Barich D H , Haw J F , et al . J . Am. Chem. Soc. , 1998 ,120 : 4025 —4026
[44 ] 　Mikkelsen a, Kolboe S. Microporous and Mesoporous Materials ,1999 , 29 (1P2) : 173 —184
[45 ] 　Song W G, Haw J F , Nicholas J B. J . Am. Chem. Soc. , 2000 ,122 : 10726 —10727
[46 ] 　Song W G, Nicholas J B , HawJ F. J . Phys. Chem. B , 2001 , 105 :4317 —4323
[47 ] 　Arstad B , Kolboe S. J . Am. Chem. Soc. , 2001 , 123 : 8137 —8138
[48 ] 　Song W G, Nicholas J B , Sassi A. Catal . Lett . , 2002 , 81 : 49 —53
[49 ] 　Bjorgen M, Bonino F. Kolboe S. J . Am. Chem. Soc. , 2003 , 125(51) : 15863 —15868
[50 ] 　Bjorgen M, Olsbye U , Kolbue S , et al . J . Catal . , 2004 , 221 (1) :1 —10
[51 ] 　Chua Y T, Stair P C , Nicholas J B. J . Am. Chem. Soc. , 2003 ,125 (4) : 866 —867
[52 ] 　Bjørgen M, Svelle S , Joensen F , et al . J . Catal . , 2007 , 249 :195 —207
[53 ] 　Song W, Fu H , HawJ F. J . Phys. Chem. B , 2001 , 105 : 12839 —12843
[54 ] 　Fu H , Song W G, Marcus D M. J . Phys. Chem. B , 106 (22) :5648 —5652
[55 ] 　Marcus D M, Song W G, Abubakar SM. Langmuir , 2004 , 20 (14) :5946 —5951
[56 ] 　Svelle S , Olsbye U , Lillerud K P. J . Am. Chem. Soc. , 2006 , 128(17) : 5618 —5619
[57 ] 　HawJ F , Nicholas J B , Song W G. J . Am. Chem. Soc. , 2000 ,122 : 4763 —4775
[58 ] 　Song W, Nicholas J B , HawJ F. J . Am. Chem. Soc. , 2001 , 123 :121 —129
[59 ] 　Sullivan R F , Egan CJ , Langlois G E. J . Am. Chem. Soc. , 1961 ,83 : 1156 —1160
[60 ] 　Arstad B , Kolboe S , Swang O. J . Phys. Chem. B , 2002 , 106(49) : 12722 —12726
[61 ] 　Arstad B , Kolboe S , Swang O. J . Phys. Chem. B , 2005 , 109(39) : 8914 —8922
[62 ] 　Sassi A , Song W G, Wildman M A. J . Phys. Chem. B , 2002 ,106 : 2294 —2303
[63 ] 　Song W G, Fu H , Haw J F. J . Am. Chem. Soc. , 2001 , 123 :4749 —4754
[64 ] 　Arstad B , Nicholas J B , Haw J F. J . Am. Chem. Soc. , 2004 ,126 : 2991 —3001
[65 ] 　Sassi A , Wildman M A , Haw J F. J . Phys. Chem. B , 2002 , 106(34) : 8768 —8773
[66 ] 　Cui ZM, Liu Q , Bain S W. J . Catal . , 2008 , 258 : 83 —86
[67 ] 　Svelle S , Rønning P O , Kolboe S. J . Catal . , 2004 , 224 ( 1) :115 —123
[68 ] 　Svelle S , Rønning P O , Kolboe S. J . Catal . , 2005 , 234 ( 2) :385 —400
[69 ] 　Svelle S , Arstad B , Kolboe S. J . Phys. Chem. B , 2003 , 107 (35) :9281 —9289
[70 ] 　Svelle S , Kolboe S , Swang O. J . Phys. Chem. B , 2004 , 108 (9) :2953 —2962
[71 ] 　Svelle S , Joensen F , Nerlov J . J . Am. Chem. Soc. , 2006 , 128(46) : 14770 —14771
[72 ] 　Bjørgen M, Olsbye U , Kolboe S. J . Catal . , 2003 , 215 : 30 —44
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Abstract

Mechanisms of Methanol-to-Olefin Reaction