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Progress in Chemistry 2009, Vol. 21 Issue (09): 1722-1733 Previous Articles   Next Articles

• Review •

Synthesis, Characterization and Catalytic Applications of Hierarchical Pore Zeolite Materials

Wang Yang; |Ma Liyong; |Zhu ning; |Chen Fengqiu**; |Zhan Xiaoli   

  1. (Department of Chemical and Biochemical Engineering, Zhejiang University, Hangzhou 310027, China)
  • Received: Revised: Online: Published:
  • Contact: Chen Fengqiu E-mail:fqchen@zju.edu.cn
  • Supported by:

    National Natural Science Foundation of China

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This article mainly covers the recent development of synthesis, characterization and catalytic applications of hierarchical pore zeolite materials. Based on mechanisms of hierarchical pore formation, synthetic approaches of hierarchical pore zeolite materials including hydrothermal and chemical treatments, acid leaching, base leaching, and templating are systematically reviewed, especially, categorizing the synthetic method of templating. The relevance of characterization techniques for analysis of hierarchical pore zeolite materials, i.e., their structure, texture, hydrothermal stability, and acid properties are subsequently described. Finally, the applications of hierarchical pore zeolite materials as catalysts to acid-catalyzed reactions, environmental catalysis, oxidation reactions and synthesis of fine chemicals are focused, providing guide for the potential of hierarchical pore zeolite materials in catalytic applications.

Contents
1 Introduction
2 Synthesis of hierarchical pore zeolite materials
2.1 Hydrothermal and chemical treatments
2.2 Acid leaching
2.3 Base leaching
2.4 Templating
2.5 Other methods
3 Structure and properties of hierarchical pore zeolite materials
3.1 Structural identification of hierarchical pore zeolite materials
3.2 Textual properties of hierarchical pore zeolite materials
3.3 Hydrothermal stability and acidity of hierarchical pore zeolite materials
4 Catalytic applications of hierarchical pore zeolite materials
4.1 In the field of petrochemical industry
4.2 In the field of environmental protection
4.3 In the field of fine chemical industry
5 Conclusion

Key words: hierarchical pore zeolite materials, templating, solid NMR, acid catalysis

CLC Number: 

[ 1 ] 　Corma A. Chem. Rev. , 1995 , 95 (3) : 559 —614
[ 2 ] 　Van Donk S , Janssen A H , Bitter J H , et al . Catal . Rev. , 2003 ,45 (2) : 297 —319
[ 3 ] 　Ruthven D M, Post M F M. in Introduction to Zeolite Science and Practice , 2nd Ed. Amsterdam: Elsevier Science , 2001
[ 4 ] 　Egeblad K, Christensen C H , Kustova M, et al . Chem. Mater. ,2008 , 20 (3) : 946 —960
[ 5 ] 　王德举(Wang D J ) , 刘仲能(Liu Z N) , 李学礼(Li X L) 等. 化学进展(Progress in Chemistry) , 2008 , 20 (5) : 637 —643
[ 6 ] 　ˇCejka J , Mintova S. Catal . Rev. , 2007 , 49 (4) : 457 —509
[ 7 ] 　Corma A , Diaz-Cabanas M J , Martinez-Triguero J , et al . Nature ,2002 , 418 : 514 —517
[ 8 ] 　Sasaki Y, Suzuki T, Takamura Y, et al . J . Catal . , 1998 , 178 (1) :94 —100
[ 9 ] 　Goyvaerts D , Martens J A , Grobet P J , et al . Stud. Surf . Sci .Catal . , 1991 , 63 : 381 —395
[10 ] 　Katada N , Kageyama Y, Takahara K, et al . J . Mol . Catal . A-Chem. , 2004 , 211 (1P2) : 119 —130
[11 ] 　López-Fonseca R , de Rivas B , Gutiérrez-Ortiz J I , et al . Stud.Surf . Sci . Catal . , 2002 , 144 : 717 —722
[12 ] 　Coster D , Blumenfeld A L , Fripiat J J . J . Phys. Chem. , 1994 , 98(24) : 6201 —6211
[13 ] 　Boréave A , Auroux A , Guimon C. Microporous Mater. , 1997 , 11(5-6) : 275 —291
[14 ] 　Yong Y, Gruver V , Fripiat J J . J . Catal . , 1994 , 150 (2) : 421 —429
[15 ] 　Morin S , Ayrault P , Gnep N S , et al . Appl . Catal . A2Gen. , 1998 ,166 (2) : 281 —292
[16 ] 　Tromp M, van Bokhoven J A , Garriga Oostenbrink M T, et al . J .Catal . , 2000 , 190 (2) : 209 —214
[17 ] 　Giudici R , Kouwenhoven H W, Prins R. Appl . Catal . A2Gen. ,2000 , 203 (1) : 101 —110
[18 ] 　Pérez-Ramírez J , Kapteijn F , Groen J C , et al . J . Catal . , 2003 ,214 (1) : 33 —45
[19 ] 　Groen J C , Pérez-Ramírez J , Peffer L A A. Chem. Lett . , 2002 , 31(1) : 94 —95
[20 ] 　Groen J C , Jansen J C , Moulijn J A , et al . J . Phys. Chem. B ,2004 , 108 (35) : 13062 —13065
[21 ] 　Groen J C , Bach T, Ziese U , et al . J . Am. Chem. Soc. , 2005 ,127 (31) : 10792 —10793
[22 ] 　Su L , Liu L , Zhuang J , et al . Catal . Lett . , 2003 , 91 : 155 —167
[23 ] 　Zhao L , Shen B J , Gao J S , et al . J . Catal . , 2008 , 258 (1) :228 —234
[24 ] 　Schmidt I , Madsen C , Jacobsen C J H. Inorg. Chem. , 2000 , 39(11) : 2279 —2283
[25 ] 　Jacobsen C J H , Madsen C , Janssens T V W, et al . Microporous Mesoporous Mater. , 2000 , 39 (1P2) : 393 —401
[26 ] 　Tao Y, Kanoh H , Kaneko K. J . Phys. Chem. B , 2003 , 107 (40) :10974 —10976
[27 ] 　Jacobsen C J H , Madsen C , Houzvicka J , et al . J . Am. Chem.Soc. , 2000 , 122 (29) : 7116 —7117
[28 ] 　Pavlaˇcková Z, Koˇsová G, Zilková N , et al . Stud. Surf . Sci .Catal . , 2006 , 162 : 905 —912
[29 ] 　Egeblad K, Kustova M, Klitgaard S K, et al . Microporous Mesoporous Mater. , 2007 , 101 (1P2) : 214 —223
[30 ] 　Jacobsen C J H , Houzvicka J , Carlsson A , et al . Stud. Surf . Sci .Catal . , 2001 , 135 : 167
[31 ] 　Boisen A , Schmidt I , Carlsson A , et al . Chem. Commun. , 2003 ,(8) : 958 —959
[32 ] 　Janssen A H , Schmidt I , Jacobsen C J H , et al . Microporous Mesoporous Mater. , 2003 , 65 (1) : 59 —75
[33 ] 　Kim S S , Shah J , Pinnavaia T J . Chem. Mater. , 2003 , 15 (8) :1664 —1668
[34 ] 　Kustova M, Egeblad K, Zhu K, et al . Chem. Mater. , 2007 , 19(12) : 2915 —2917
[35 ] 　Katsuki H , Furuta S , Watari T, et al . Microporous Mesoporous Mater. , 2005 , 86 (1P3) : 145 —151
[36 ] 　Ryoo R , Joo S H , Jun S. J . Phys. Chem. B , 1999 , 103 (37) :7743 —7746
[37 ] 　Cho S I , Choi S D , KimJ H , et al . Adv. Funct . Mater. , 2004 , 14(1) : 49 —54
[38 ] 　Yang Z, Xia Y, Mokya R. Adv. Mater. , 2004 , 16 (8) : 727 —732
[39 ] 　Fang Y M, Hu H Q. J . Am. Chem. Soc. , 2006 , 128 ( 33) :10636 —10637
[40 ] 　Tao Y S , Kanoh H , Kaneko K. J . Am. Chem. Soc. , 2003 , 125(22) : 6044 —6045
[41 ] 　Tao Y, Kanoh H , Hanzawa Y, et al . Colloids Surf . A , 2004 , 241(1/3) : 75 —80
[42 ] 　Tao Y, Kanoh H , Kaneko K. Langmuir , 2005 , 21 (2) : 504 —507
[43 ] 　Xiao F S , Wang L , Yin C , et al . Angew. Chem. Int . Ed. , 2006 ,45 (19) : 3090 —3093
[44 ] 　Wang H , Pinnavaia TJ . Angew. Chem. Int . Ed. , 2006 , 45 (45) :7603 —7606
[45 ] 　Holland B T, Abrams L , Stein A. J . Am. Chem. Soc. , 1999 , 121(17) : 4308 —4309
[46 ] 　Tosheva L , Valtchev V , Sterte J . Microporous Mesoporous Mater. ,2000 , 35P36 : 621 —629
[47 ] 　Davis S A , Burkett SL , Mann S , et al . Nature , 1997 , 385 : 420 —423
[48 ] 　Dong A , Wang Y, Tang Y, et al . Adv. Mater. , 2002 , 14 (12) :926 —929
[49 ] 　Valtchev V , Smaihi M, Faust A C , et al . Angew. Chem. Int . Ed. ,2003 , 42 (24) : 2782 —2785
[50 ] 　Zhang B , Davis S A , Mann S. Chem. Mater. , 2002 , 14 ( 3) :1369 —1375
[51 ] 　Karlsson A , Stêcker M, Schmidt R. Microporous Mesoporous Mater. , 1999 , 27 (2P3) : 181 —192
[52 ] 　Hedin N , Graf R , Chmelka B F , et al . J . Am. Chem. Soc. , 2004 ,126 (30) : 9425 —9432
[53 ] 　Choi M, Cho H S , Ryoo R , et al . Nat . Mater. , 2006 , 5 : 718 —723
[54 ] 　Srivastava R , Choi M, Ryoo R. Chem. Commun. , 2006 , (43) :4489 —4491
[55 ] 　Choi M, Srivastava R , Ryoo R. Chem. Commun. , 2006 , (42) :4380 —4382
[56 ] 　Corma A. Chem. Rev. , 1997 , 97 (6) : 2373 —2420
[57 ] 　Liu Y, Zhang W, Pinnavaia TJ . J . Am. Chem. Soc. , 2000 , 122(36) : 8791 —8792
[58 ] 　Liu Y, Pinnavaia T J . J . Mater. Chem. , 2002 , 12 (11) : 3179 —3190
[59 ] 　Liu Y, Zhang W, Pinnavaia T J . Angew. Chem. Int . Ed. , 2001 ,40 (7) : 1255 —1258
[60 ] 　Sakthivel A , Huang S , Chen W, et al . Adv. Funct . Mater. , 2005 ,15 (2) : 253 —258
[61 ] 　Tan Q F , Bao X J , Song T C , et al . J . Catal . , 2007 , 251 (1) :69 —79
[62 ] 　Kloetstra KR , Zandbergen HW, van Bekkum H , et al . Microporous Mater. , 1996 , 6 (5P6) : 287 —293
[63 ] 　Ooi Y S , Zakaria R , Mohamed A R , et al . Appl . Catal . A-Gen. ,2004 , 274 (1P2) : 15 —23
[64 ] 　Corma A , Diaz U , Domine M E , et al . Angew. Chem. Int . Ed. ,2000 , 39 (8) : 1499 —1501
[65 ] 　Climent MJ , Corma A , Iborra S. J . Catal . , 2005 , 233 (2) : 308 —316
[66 ] 　Climent MJ , Corma A , Velty A. Appl . Catal . A-Gen. , 2004 , 263(2) : 155 —161
[67 ] 　Schacht S , Huo Q , Voigt-Martin I G, et al . Science , 1996 , 273(5276) : 768 —771
[68 ] 　Lin J C , Yates M Z. Langmuir , 2005 , 21 (6) : 2117 —2120
[69 ] 　Kloetstra K R , van Bekkum H , Jansen J C. Chem. Commun. ,1997 , (23) : 2281 —2282
[70 ] 　Huang L , Guo W, Deng P , et al . J . Phys. Chem. B , 2000 , 104(13) : 2817 —2823
[71 ] 　On D T, Kaliaguine S. Angew. Chem. Int . Ed. , 2001 , 40 (17) :3248 —3251
[72 ] 　Hidrobo A , Retuert J , Araya P , et al . J . Porous Mater. , 2003 , 10(4) : 231 —234
[73 ] 　On D T, Kaliaguine S. Angew. Chem. Int . Ed. , 2002 , 41 (6) :1036 —1040
[74 ] 　On D T, Kaliaguine S. J . Am. Chem. Soc. , 2003 , 125 (3) : 618 —619
[75 ] 　Mavrodinova V , Popova M, Valchev V , et al . J . Colloid Interface Sci . , 2005 , 286 (1) : 268 —273
[76 ] 　Anderson M W, Holmes S M, Hanif N , et al . Angew. Chem. Int .Ed. , 2000 , 39 (15) : 2707 —2710
[77 ] 　Wang Y, Tang Y, Dong A , et al . J . Mater. Chem. , 2002 , 12 (6) :1812 —1818
[78 ] 　Aguado J , Serrano D P , Rodríguez J M. Microporous Mesoporous Mater. , 2008 , 115 (3) : 504 —513
[79 ] 　Sun Y Y, Prins R. Appl . Catal . A-Gen. , 2008 , 336 (1P2) : 11 —16
[80 ] 　Haskouri J E , Morales J M, de Zárate D O , et al . Inorg. Chem. ,2008 , 47 (18) : 8267 —8277
[81 ] 　McCusker L B , Baerlocher C. Stud. Surf . Sci . Catal . , 2005 , 157 :41 —64
[82 ] 　Zhao D Y, Huo Q S , Feng J L , et al . J . Am. Chem. Soc. , 1998 ,120 (24) : 6024 —6036
[83 ] 　ProkeˇsováP , Mintova S , Cějka J , et al . Microporous Mesoporous Mater. , 2003 , 64 (1P3) : 165 —174
[84 ] 　Xia Y, Mokaya R. J . Mater. Chem. , 2004 , 14 (23) : 3427 —3435
[85 ] 　Prokeˇsová-Fojtíková P , Petkov N , Cějka J , et al . Collect . Czech.Chem. Commun. , 2005 , 70 (11) : 1829 —1847
[86 ] 　WichterlováB , Tvaru.ˇzková Z, Sobalík Z, et al . Microporous Mesoporous Mater. , 1998 , 24 (4P6) : 223 —233
[87 ] 　Triantafyllidis K S , Lappas A A , Vasalos I A , et al . Catal . Today ,2006 , 112 (1P4) : 33 —36
[88 ] 　Triantafyllidis K S , Iliopoulou E F , Antonakou E V , et al .Microporous Mesoporous Mater. , 2007 , 99 (1P2) : 132 —139
[89 ] 　Waller P , Shan Z, Jansen J C , et al . Chem. Eur. J . , 2004 , 10(20) : 4970 —4976
[90 ] 　Bordoloi A , Devassy B M, Niphadkar P S , et al . J . Mol . Catal . A-Chem. , 2006 , 253 (1P2) : 239 —244
[91 ] 　Sakthivel A , Chen W H , Liu S H , et al . Catal . Lett . , 2006 , 108(3/4) : 173 —178
[92 ] 　Zhang Z, Han Y, Zhu L , et al . Angew. Chem. Int . Ed. , 2001 , 40(7) : 1258 —1262
[93 ] 　Christensen C I , Johannsen K, Schmidt I , et al . J . Am. Chem.Soc. , 2003 , 125 (44) : 13370 —13371
[94 ] 　Agundez J , Diaz I , Marquez-Alvarez C , et al . Chem. Commun. ,2003 , (1) : 150 —151
[95 ] 　Rovik A K, Hagen A , Schmidt I , et al . Catal . Lett . , 2006 , 109 (3/4) : 153 —156
[96 ] 　Kustova M Y, Hasselriis P , Christensen C H. Catal . Lett . , 2004 ,96 (3/4) : 205 —211
[97 ] 　Solberg S M, Kumar D , Landry C C. J . Phys. Chem. B , 2005 ,109 (51) : 24331 —24337
[98 ] 　Kustova M Y, Rasmussen S B , Kustov L A , et al . Appl . Catal . B-Environ. , 2006 , 67 (1P2) : 60 —67
[99 ] 　Chen X, Kawi S. Chem. Commun. , 2001 , (15) : 1354 —1355
[100 ] Tabata T, Ohtsuka H. Catal . Lett . , 1997 , 48 (3/4) : 203 —211
[101 ] Zeng S Q , Blanchard J , Breysse M, et al . Appl . Catal . A2Gen. ,2006 , 298 : 88 —93
[102 ] Zhu Y Z, Nie Y T, Jaenicke S , et al . J . Catal . , 2005 , 229 (2) :404 —413
[103 ] Bagshaw S A , Baxter N I , Brew D R M, et al . J . Mater. Chem. ,2006 , 16 (23) : 2235 —2244
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