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Progress in Chemistry 2009, Vol. 21 Issue (09): 1705-1721   Next Articles

• Review •

Carbon Nanomaterials and Their Heterogeneous Catalytic Application

Wang Chunlei ; |Ma Ding ; |Bao Xinhe   

  1. (State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China)
  • Received: Revised: Online: Published:
  • Contact: Bao Xinhe E-mail:xhbao@dicp.ac.cn
  • Supported by:

    National Natural Science Foundation of China

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As a new type of catalyst and/or catalyst supports, carbon nanomaterials (including zero-dimensional, one-dimensional, two-dimensional carbon nanomaterials and nanoporous carbon materials) have potential applications in fields of heterogeneous catalysis, such as oxidative dehydrogenation, selective hydrogenation, ammonia synthesis and decomposition, and electrocatalysis in fuel cell. This paper presents an overview of the development of carbon nanomaterials and their applications in the field of heterogeneous catalysis in recent years. The preparation methods of these carbon nanomaterials are introduced; the relationships of their micro/mesostructures, dopping, electronic properties, surface properties, confinement effects and thus-resulted catalytic performance variations are emphatically reviewed.

Contents
1 Zero-dimensional carbon nanomaterials
1.1 Fullerene discover, structure and application in heterogeneous catalysis
1.2 Onion-like carbon, carbon-encapsulated metal nanoparticles and applications in heterogeneous catalysis
1.3 Nano-diamond and its application in heterogeneous catalysis
2 One-dimensional carbon nanomaterials
2.1 Carbon nanofibers preparation and application in heterogeneous catalysis
2.2 Carbon nanotubes discover, structure and application in heterogeneous catalysis
2.3 Heterogeneous catalyst confined in carbon nanotubes
3 Two-dimensional carbon nanomaterials
3.1 Graphene and its application in heterogeneous catalysis
3.2 Carbon nanowall and its application in heterogeneous catalysis
4 Carbon nanoporous materials
4.1 Mesoporous carbon materials and its application in heterogeneous catalysis
4.2 Functionalized mesoporous carbon and its application in heterogeneous catalysis
4.3 Other carbon nanoporous materials and their applications in heterogeneous catalysis
5 Conclusion and perspective

Key words: carbon nanomaterials, heterogeneous catalysis, catalysts, catalyst supports

CLC Number: 

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