中文
Earlier issues
Announcement
More
Progress in Chemistry 2009, Vol. 21 Issue (05): 964-970 Previous Articles   Next Articles

• Review •

NOx Storage-Reduction Catalysts Used for Lean-Burn NOx Removal

Guo Lihong; Liu Yong; Meng Ming**   

  1. (Tianjin Key Laboratory of Applied Catalysis Science and Engineering, Department of Catalysis Science and Technology, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China)
  • Received: Revised: Online: Published:
  • Contact: Meng Ming E-mail:mengm@tju.edu.cn
PDF ( 1643 ) Cited
Export

EndNote

Ris

BibTeX

The NOx storage and reduction (NSR) technology will be the most promising way to reduce the NOx emission from lean-burn engines. Since the concept of NOx storage and reduction was firstly proposed by Toyota Co. in 1996, the NSR catalysts have attracted much attention in environmental catalysis area. The main advances in different formulated NSR catalysts (PBA-type、hydrotalcite-type、perovskite-type) in the last decade are systematically reviewed in this paper. The emphases are put on the commonly recognized NOx storage and reduction pathway and the NSR catalysts deactivation mechanism, including the negative effect of H2O and CO2, the thermal aging and SO2 poisoning. At last, the developing tendency for NSR technology is proposed.

Contents
1 PBA –type NSR catalysts
1.1 Precious metals
1.2 Storage components
1.3 Supports
2 Other materials and structures for NSR catalysts
3 Mechanisms of NOx storage-reduction reaction
4 Deactivation of NSR catalysts
5 Problems and Outlook

Key words: lean-burn, nitrogen oxides, storage-reduction

CLC Number: 

[ 1 ] 　Matsumoto S. CATTECH , 2000 , 4 : 102 —109
[ 2 ] 　Akama H , Matsushita K. Catal . Surv. Jpn. , 1999 , 3 : 139 —146
[ 3 ] 　Hamada H , Kintaichi Y, Sasaki M, Ito T. Chem. Lett . , 1990 , 19 :1069 —1070
[ 4 ] 　Iwamoto M, Hamada H. Catal . Today , 1991 , 10 : 57 —71
[ 5 ] 　Zhang G, Yamaguchi Y, Kawakami H , Suzuki T. Appl . Catal . B ,1992 , 1 : L15 —L20
[ 6 ] 　Obuchi A , Nakamura N , Ogata A , Mizuno K, Obuchi H. Appl .Catal . B , 1993 , 2 : 71 —80
[ 7 ] 　Miyoshi N , Matsumoto S , Katoh K, Tanaka T, Harada J , Takahashi N , Yokota K, Sugiura M, Kasahara K. SAE Paper , 1995 , 950809
[ 8 ] 　Takahashi N , Shinjoh H , Lijima T, Suzuki T, Yamazaki K, Yokota K, Suzuki H , Miyoshi N , Tateishi S , Kasahara K. Catal . Today ,1996 , 27 : 63 —69
[ 9 ] 　Matsumoto S. Catal . Today , 1996 , 29 : 43 —45
[10 ] 　Bêgner W, Kr?mer M, Krutzsch B , Pischinger S , Voigtl? nder D ,Wenninger G, Wirbeleit F , Brogan MS , Brisley RJ , Webster D E.Appl . Catal . B , 1995 , 7 : 153 —171
[11 ] 　Salasc S , Skoglundh M, Fridell E. Appl . Catal . B , 2002 , 36 :145 —160
[12 ] 　Su Y, Kabin K, Harold M, Amiridis M. Appl . Catal . B , 2007 ,71 : 207 —215
[13 ] 　Huang H , Long R ,Yang R. Energ. Fuel . , 2001 , 15 : 205 —213
[14 ] 　Huang H , Long R , Yang R. Appl . Catal . B , 2001 , 33 : 127 —136
[15 ] 　Amberntsson A , Fridell E , Skoglundh M. Appl . Catal . B , 2003 ,46 : 429 —439
[16 ] 　Amberntsson A , Skoglundh M, Ljungstrom S , Fridell E. J . Catal . ,2003 , 217 : 253 —263
[17 ] 　Abdulhamid H , Fridell E , Skoglundh M. Appl . Catal . B , 2006 ,62 : 319 —328
[18 ] 　Abdulhamid H , Dawody J , Fridell E , Skoglundh M. J . Catal . ,2006 , 244 : 169 —182
[19 ] 　Vijay R , Hendershot RJ , Rivera-JimUnez SM, Rogers WB , Feist B J , Snively C M, Lauterbach J . Catal . Commun. , 2005 , 6 : 167 —171
[20 ] 　Vijay R , Snively CM, Lauterbach J . J . Catal . , 2006 , 243 : 368 —375
[21 ] 　Vijay R , Dellamorte J C , Snively CM, Lauterbach J . Chim. Oggi . ,2007 , 25 : 14 —16
[22 ] 　李新刚(Li X G) , 孟明(MengM) , 林培琰(Lin P Y) 等. 催化学报(Chinese Journal of Catalysis) , 2002 , 23 : 417 —420
[23 ] 　Yamazaki K, Suzuki T, Takahashi N , Yokota K, Sugiura M. Appl .Catal . B , 2001 , 30 : 459 —468
[24 ] 　Yamazaki K, Takahashi N , Shinjoh H , Sugiura M. Appl . Catal . B ,2004 , 53 : 1 —12
[25 ] 　Luo J Y, Meng M, Zha YQ , Xie YN , Hu T D , Zhang J , Liu T.Appl . Catal . B , 2008 , 78 : 38 —52
[26 ] 　Lietti L , Forzatti P , Nova I , Tronconi E. J . Catal . , 2001 , 204 :175 —191
[27 ] 　Szailer T, Kwak J H , Kim D H , Szanyi J , Wang C M, Peden C H F. Catal . Today , 2006 , 114 : 86 —93
[28 ] 　Szanyi J , Kwak J H , Hanson J , Wang C M, Szailer T, Peden C H F. J . Phys. Chem. B , 2005 , 109 : 7339 —7344
[29 ] 　Szanyi J , Kwak J H , Kim D H , Burton S D , Peden C H F. J . Phys.Chem. B , 2005 , 109 : 27 —29
[30 ] 　Kwak J H , Kim D H , Szailer T, Peden C H F , Szanyi J . Catal .Lett . , 2006 , 111 : 119 —126
[31 ] 　Piacentini M, Maciejewski M, Baiker A. Appl . Catal . B , 2005 ,60 : 265 —275
[32 ] 　Piacentini M, Maciejewski M, Baiker A. Appl . Catal . B , 2005 ,59 : 187 —195
[33 ] 　Piacentini M, Maciejewski M, Baiker A. Appl . Catal . B , 2006 ,66 : 126 —136
[34 ] 　Piacentini M, Maciejewski M, Baiker A. Top. Catal . , 2007 , 42/43 : 55 —59
[35 ] 　Luo J Y, Meng M, Li X G, Zha YQ. Micropor. Mesopor. Mater. ,2008 , 113 (1/3) : 277 —285
[36 ] 　Hodjati S , Bernhardt P , Petit C , Pitchon V , Kiennemann A. Appl .Catal . B , 1998 , 19 : 209 —219
[37 ] 　Hodjati S , Bernhardt P , Petit C , Pitchon V , Kiennemann A. Appl .Catal . B , 1998 , 19 : 221 —232
[38 ] 　Takeuchi M, Matsumoto S. Top. Catal . , 2004 , 28 : 151 —156
[39 ] 　Basile F , Fomasari G. Appl . Catal . B , 2006 , 69 : 58 —64
[40 ] 　Basile F , Fomasari G. Catal . Today , 2007 , 119 : 59 —63
[41 ] 　Dou D , Balland J . SAE Paper , 2002 , 200220120734
[42 ] 　Iwachido K, Tanada H , Watanabe T. SAE Paper , 2001 , 2001-01-1298
[43 ] 　Piacentini M, Maciejewski , Baiker A. Appl . Catal . B , 2007 , 72 :105 —117
[44 ] 　Ito K, Kakino S , Ikeue K. Appl . Catal . B , 2007 , 74 : 137 —143
[45 ] 　Takahashi N , Suda A , Hachisuka I , Sugiura M, Sobukawa H ,Shinjoh H. Appl . Catal . B , 2007 , 72 : 187 —195
[46 ] 　Imagawa H , Tanaka T, Takahashi N , Matsunaga S , Suda A , Shinjoh H. J . Catal . , 2007 , 51 : 315 —320
[47 ] 　刘咏(Liu Y) , 孟明(Meng M) , 郭丽红( Guo L H) , 查宇清(Zha YQ) . 催化学报(Chinese Journal of Catalysis) , 2007 , 28 :850 —856
[48 ] 　Liu Y, Meng M, Li X G, Guo L H , Zha Y Q. Chem. Eng. Res.Des. , 2008 , 86 : 932 —940
[49 ] 　Hodjati S , Vaezzadeh K, Petit C , Pitchon V , Kiennemann A. Appl .Catal . B , 2000 , 26 : 5 —16
[50 ] 　Hodjati S , Petit C , Pitchon V , Kiennemann A. Appl . Catal . B ,2000 , 27 : 117 —126
[51 ] 　陈加福(Chen J F) , 孟明(Meng M) , 林培琰(Lin P Y) , 李新刚(Li X G) , 伏义路(Fu YL) , 俞寿明(Yu S M) . 催化学报(Chinese Journal of Catalysis) , 2003 , 24 : 419 —422
[52 ] 　Li X G, Chen J F , Lin P Y, Meng M, Fu Y L , Tu J , Li Q X.Catal . Commun. , 2004 , 5 : 25 —28
[53 ] 　Milt V G, Querini C A , Miro E E , Ulla M A. J . Catal . , 2003 ,220 : 424 —432
[54 ] 　Casapu M, Grunwaldt J D. Catal . Lett . , 2008 , 120 : 1 —7
[55 ] 　Centi G, Arena G E , Perathoner S. J . Catal . , 2003 , 216 : 443 —454
[56 ] 　Centi G, Fornasari G, Gobbi C , Livi M, Trifiro F , Vaccari A.Catal . Today , 2002 , 73 : 287 —296
[57 ] 　Yu J J , Jiang Z, Zhu L , Hao Z P , Xu Z P. J . Phys. Chem. B ,2006 , 110 : 4291 —4300
[58 ] 　Yu J J , Tao Y X, Liu C C , Hao Z P , Xu Z P. Enviro. Sci .Technol . , 2007 , 41 : 1399 —1404
[59 ] 　Crocoll M, Kureti S , Weisweiler W. J . Catal . , 2005 , 229 : 480 —489
[60 ] 　Epling W S , Parks J E , Campbell G C. Catal . Today , 2004 , 96 :21 —30
[61 ] 　Mahzoul H , Brilhac J F , Gilot P. Appl . Catal . B , 1999 , 20 : 47 —55
[62 ] 　Nova I , Castoldi L , Lietti L , Tronconi E , Forzatti P , Prinetto F ,Giovanna G. J . Catal . , 2004 , 222 : 377 —388
[63 ] 　James D , Fourre E , Ishii M, Bowker M. Appl . Catal . B , 2003 ,45 : 147 —159
[64 ] 　Abdulhamid H , Fridell E , Skoglundh M. Top. Catal . , 2004 , 30/31 : 161 —168
[65 ] 　Lesage T, Verrier C , Bazin P , Saussey J , Daturi M. Phys. Chem.Chem. Phys. , 2003 , 5 : 4435 —4440
[66 ] 　Castoldi L , Nova I , Lietti L , Tronconi E , Forzatti P. Top. Catal . ,2007 , 42/43 : 189 —193
[67 ] 　Nova I , Castoldi L , Lietti L. Catal . Today , 2002 , 75 : 431 —437
[68 ] 　Epling W S , Campbell G C , Parks J E. Catal . Lett . , 2003 , 90 :45 —56
[69 ] 　Graham GW, Jen H W, Chun W, Sun H P , Pan X Q , McCabe R W. Catal . Lett . , 2004 , 93 : 3 —6
[70 ] 　Uy D , O’Neill A E , Li J , Watkins WL H. Catal . Lett . , 2004 ,95 : 191 —201
[71 ] 　Graham GW, Jen H W, Chun W, Sun H P , Pan X Q , McCabe RW. Catal . Lett . , 2004 , 93 : 129 —134
[72 ] 　Uy D , O’Neill A E , Li J , Watkins WL H. Catal . Lett . , 2004 ,95 : 191 —201
[73 ] 　Casapu M, Grunwaldt J D , Maciejewski M, Baiker A , Eckhoff S ,Gobel U , Wittrock M. J . Catal . , 2007 , 251 : 28 —38
[74 ] 　Casapu M, Grunwaldt J D , Maciejewski M, Baiker A , Wittrock M,Gobel U , Eckhoff S. Top. Catal . , 2007 , 42P43 : 3 —7
[75 ] 　Matsumoto S , Ikeda Y, Suzuki H , Ogai M, Miyoshi N. Appl .Catal . B , 2000 , 25 : 115 —124
[76 ] 　Hachisuka I , Hirata H , Ikeda Y, Matsumoto S. SAE Paper , 2000 ,2000-01-1196
[77 ] 　Sedlmair C , Seshan K, Jentys A , Lercher J A. Catal . Today , 2002 ,75 : 413 —419
[1] Shuai Li, Na Zhu, Yangjian Cheng, Di Chen. Performance of Resistance to Sulfur Oxide and Regeneration over Copper-Based Small-Pore Zeolites Catalysts for the Selective Catalytic Reduction of NOx with NH3 [J]. Progress in Chemistry, 2023, 35(5): 771-779.
[2] Bin Jia, Xiaolei Liu, Zhiming Liu. Selective Catalytic Reduction of NOx by Hydrogen over Noble Metal Catalysts [J]. Progress in Chemistry, 2022, 34(8): 1678-1687.
[3] Xiaohan Wang, Caixia Liu, Chunfeng Song, Degang Ma, Zhenguo Li, Qingling Liu. Application of Metal-Organic Frameworks for Low-Temperature Selective Catalytic Reduction of NO with NH3 [J]. Progress in Chemistry, 2020, 32(12): 1917-1929.
[4] Li Panpan, Yu Feng, Zhu Mingyuan, Tang Changjin, Dai Bin, Dong Lin. Selective Catalytic Reduction De-NOx Catalysts [J]. Progress in Chemistry, 2016, 28(10): 1578-1590.
[5] . Reaction and Mechanism of Low-Temperature Selective Catalytic Reduction of NOx by NH3 over Manganese Oxide-based Catalysts [J]. Progress in Chemistry, 2010, 22(10): 1882-1900.
[6] Liu Jinqiang, Qian Chao, Chen Xinzhi. Nitration of Deactivated Aromatic Compounds [J]. Progress in Chemistry, 2009, 21(12): 2635-2641.
[7]

Ma Tao|Wang Rui**

. Catalytic Decomposition of NOx [J]. Progress in Chemistry, 2008, 20(06): 798-810.