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Progress in Chemistry 2009, Vol. 21 Issue (05): 1060-1069 Previous Articles   Next Articles

• Review •

Applications and Techniques of Microwave Spectroscopy

Tang Shouyuan1; Xia Zhining1,2**; Fu Yujie3; Gou Qian2   

  1. (1. Bioengineering College, Chongqing University, Chongqing 400044, China; 2. Chemistry and Chemistry Engineering College, Chongqing University, Chongqing 400044, China; 3. Chemistry and Bioengineering College, Chongqing University of Technology, Chongqing 400050, China)
  • Received: Revised: Online: Published:
  • Contact: Xia Zhining E-mail:chem_lab_cqu@yahoo.com.cn
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Microwave spectroscopy is suitable for studying chemically and physically very interesting molecular systems, including weakly bound complexes, radicals, ions, and other transient species. Information on molecular structure, internal motions and intermolecular interactions are easily obtained. Advances and techniques of microwave spectrometer are outlined in this article. The instruments developed, including microwave absorption spectrometer, pulsed nozzle Fourier transform microwave spectrometer and chirped pulse Fourier transform microwave spectrometer, etc. are described. Complimentary techniques in supersonic expansions, external applied fields with Stark modulation, fast scan, chirped pulse and double resonance are reviewed. Pulsed nozzles with heating system, fast-mixing, electric discharge and laser ablation are discussed. Meanwhile, the applications and developments of microwave spectrometers in the field of analytical chemistry are also reviewed. Finally, future trends of microwave spectrometers are prospected.

Contents
1 Introduction
2 Principle and structure of microwave spectrometer
3 Techniques in microwave spectrometer
3.1 Microwave absorption spectrometer
3.2 Fourier transform microwave spectrometer
3.3 Double resonator techniques
3.4 Chirped pulse Fourier transform microwave spectrometer (CP-FTMW)
3.5 Microwave spectrometer for chemical analysis
4 Conclusions

Key words: microwave spectrometer, Fourier transform, rotational spectra, supersonic jet, fast scan, chirped pulse

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