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Progress in Chemistry 2009, Vol. 21 Issue (04): 715-723 Previous Articles   Next Articles

• Review •

Fluorescent Probes for Sensing Magnesium Ions

Zhang Dengqing*   

  1. (College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China)
  • Received: Revised: Online: Published:
  • Contact: Zhang Dengqing E-mail:dqzhang@dhu.edu.cn
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Magnesium ion sensors are extensively required because this biologically most abundant divalent cation plays vital roles in many biological processes. This article outlines recent activities regarding the development of molecular sensors that can visualize the presence of magnesium ions through changes of their fluorescence properties. Eight different sensing systems are discussed: quinoline-based sensors, β-diketone-based sensors, crown ethers/polyethers-based sensors, carboxylic acid-based sensors, fluorescein/rhodamine-based sensors, complex-based sensors, polymer-based sensors and nanomaterial-based sensors. Typical examples are presented for each class and different fluorescent sensors for the detection of magnesium ions are summarized and compared.

Contents
1 Introduction
2 Quinoline-based ionophores
3 b-Diketone ionophores
3.1 Intramolecular charge transfer
3.2 Photoinduced electron transfer
4 Crown ethers/polyethers-based ionophores
5 Carboxylic acid-based ionophores
6 Fluorescein/rhodamine-based ionophores
7 Complex-based ionophores
8 Polymer-based ionophores
9 Nanomaterial-based ionophores
10 Other ionophores
11 Conclusion

Key words: magnesium ion, fluorescent probe, &beta, -diketone, crown ether

CLC Number: 

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