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Progress in Chemistry 2009, Vol. 21 Issue (04): 629-636 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

Safety-Enhancing Additives for Lithium Ion Batteries

Chen Shiyu1,2 ; Wang Zhaoxiang2**; Zhao Hailei1**; Chen Liquan2   

  1. (1. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China; 2. Laboratory for Solid State Ionics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China)
  • Received: Revised: Online: Published:
  • Contact: Wang Zhaoxiang; Zhao Hailei E-mail:zxwang@aphy.iphy.ac.cn; hlzhao@mater.ustb.edu.cn
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Electrolyte plays important roles on the performances of lithium ion batteries (LIB). Much attention has been attracted to the investigation of functional additives to the organic electrolytes in recent years. This paper is intended to review the recent progresses on the study of safety-enhancing additives including flame retardants to the commercially avaliable carbonates-based electrolytes and overcharge protection(such as redox shuttles, potential-sensitive and temperature-sensitive) additives to the electrode as well as to the electrolytes for lithium ion batteries. The research status and the perspectives of each type of the additives are commented after an introduction to their operational mechanisms and electrochemical performances.

Contents
1 Introduction
2 Flame-retardant additives
2.1 Flame-retardant mechanism
2.2 Flame-retardant additives
3 Overcharge protection additives
3.1 Redox shuttle additives
3.2 Potential-sensitive additives
3.3 Temperature-sensitive additives
4 Conclusions

Key words: lithium-ion battery, additives, safety, flame retardants, overcharge protection

CLC Number: 

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