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Progress in Chemistry 2009, Vol. 21 Issue (04): 588-599 Previous Articles   Next Articles

• Review •

Metalloporphyrin-Based Supramolecular Catalysts

Yang Zaiwen1,3 ;Yang Jin2;  Huang Xiaojuan1;  Tang Ning2;  Wu Biao1**   

  1. (1.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute
    of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;
    2.College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China;
    3.Graduate University of Chinese Academy of Sciences, Beijing, 100049, China)
  • Received: Revised: Online: Published:
  • Contact: Wu Biao E-mail:wubiao@lzb.ac.cn
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Metalloporphyrin-based supramolecular catalyst is one of the most important research subjects in supramolecular catalysis. Supramolecular micro-reactors containing the metalloporphyrin backbone provide a specific micro-environment for the active sites in catalytic processes, which can greatly improve the selectivities and catalytic efficiencies of the catalysts. This review presents the recent progress in the design, structures and catalytic properties of metalloporphyrins as supramolecular catalysts from the aspects of the construction of supramolecular catalyst precursors (based on cyclodextrin, template, etc.) and their catalytic applications (in mimicking cytochrome P450 enzymes, electrocatalysis, photocatalysis, etc), as well as a perspective of the future development in this field.

Contents
1 Introduction
2 Metalloporphyrin-based supramolecular catalysts
2.1 Metalloporphyrin-based supramolecular catalysts based on cyclodextrin
2.2 Metalloporphyrin-based supramolecular catalysts in mimicking cytochrome P-450 enzymes
2.3 Metalloporphyrin-based supramolecular catalysts in electrocatalysis
2.4 Metalloporphyrin-based supramolecular catalysts based on template
2.5 Metalloporphyrin-based supramolecular catalysts in photocatalysis
2.6 Others
3 Conclusions

Key words: supramolecular chemistry, catalysis, metalloporphyrins, enzyme mimicking, recognition

CLC Number: 

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