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Progress in Chemistry 2009, Vol. 21 Issue (01): 235-243 Previous Articles   Next Articles

• Review •

Asymmetric Hybrid Electrochemical Cell/Capacitor

Xu Rui1 ;Tang Zilong1** ;Li Junrong2 ;Zhang Zhongtai1   

  1. (1. State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China|2. China Astronaut Center, Beijing 100094, China)
  • Received: Revised: Online: Published:
  • Contact: Tang Zilong E-mail:tzl@tsinghua.edu.cn
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The development of asymmetric hybrid electrochemical cell/capacitor (AHEC) has been driven by an ever-increasing demand on high energy and power density energy storage devices for electric vehicles (EV), potable electronic devices, as well as space and military applications. AHEC combine the merits of Li-ion batteries and supercapacitors, offering higher power density than lithium ion cells, and higher energy density than supercapacitors, as well as long charge-discharge cycling life, and low self-discharge rate. Here we present a brief historical review of the development of asymmetric hybrid electrochemical cell/capacitor, discuss the present situation and challenges that remain regarding the energy/power density and lifetime of the systems, and highlight ongoing research strategies on AHEC.

Contents
1 Introduction
2 Historical developments in asymmetric hybrid electrochemical cell/capacitor research
3 Present status and remaining challenges
4 Materials for asymmetric hybrid electrochemical cell/capacitor electrodes
4.1 Carbon materials
4.2 Metal materials
4.3 Metal oxides
4.4 Li-intercalation materials
4.5 Polymers
5 Conclusion

Key words: asymmetric hybrid electrochemical cell/capacitor, cells, capacitors

CLC Number: 

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