中文
Earlier issues
Announcement
More
Progress in Chemistry 2009, Vol. 21 Issue (01): 217-226 Previous Articles   Next Articles

• Review •

Reductive Destruction of Environmental Pollutants by Hydrogenation Process

Yang Bo;Yu Gang**   

  1. (Department of Environmental Science and Engineering, POPs Research Centre, Tsinghua University, Beijing 100084, China)
  • Received: Revised: Online: Published:
  • Contact: Yu Gang E-mail:yg-den@Tsinghua.edu.cn
PDF ( 1806 ) Cited
Export

EndNote

Ris

BibTeX

The chemical hydrogenation possess the capacity of hydrodehalogenation, hydrodenitrification, hydrodesulfurization, and hydrodearomatization, which has been used environmentally to remove various typical organic or inorganic pollutants in gas or liquid phase. The pollutants treated by hydrogenation mainly include halogenated organic wastes, nitroarenes, organic sulfur compounds, polycyclic aromatic hydrocarbons, nitrates, sulfates, NOx, SO2, and heavy metal ions. So this review presents the wide scale of the hydrogenation applications in the reductive destruction of environmental pollutants studied mainly within past five years. The destruction principles of the above pollutants by hydrogenation are introduced. The effects of the reaction conditions on the reduction efficiency are discussed such as catalysts and supports, hydrogen donors, and pH. The advantages of the reductive destruction for pollutants by hydrogenation are evaluated on the basis of green chemistry practices. Based on the requirements of industrial application, the research trends for the future are proposed in order to further improve hydrogenation efficiency and energy conservation.

Contents
1 Introduction
2 Various hydrogen donors and their hydrogenating mechanisms
3 Removal of various pollutants with hydrogenation methods
3.1 Hydrodehalogenation
3.2 Hydrodenitrification
3.3 Removal of heavy metal ions with hydrogenation
3.4 Hydrodesulfurization
3.5 Hydrodearomatization
4 Conclusions and prospects

Key words: chemical hydrogenation, reductive destruction, environmental pollutants

CLC Number: 

[ 1 ] 　Laine D F , Cheng I F. Microchem. J . , 2007 , 85 (2) : 183 —193
[ 2 ] 　程荣(Cheng R) , 王建龙(Wang J L) , 张伟贤(Zhang W X) . 化学进展(Prog. Chem. ) , 2006 , 18 (1) : 93 —99
[ 3 ] 　Pirkanniemi K, Sillanpaa M. Chemosphere , 2002 , 48 (10) : 1047 —1060
[ 4 ] 　Conner W C , Falconer J L. Chem. Rev. , 1995 , 95 (3) : 759 —788
[ 5 ] 　Yang B , Yu G, Liu X T. Electrochim. Acta , 2006 , 52 ( 3 ) :1075 —1081
[ 6 ] 　Cheng H , Scott K, Christensen P A. J . Electrochem. Soc. , 2003 ,150 (2) : D17 —D24
[ 7 ] 　GrahamL J , Jovanovic G. Chem. Eng. Sci . , 1999 , 54 (15P16) :3085 —3093
[ 8 ] 　Zhu B W, Lim T T. Environ. Sci . Technol . , 2007 , 41 ( 21) :7523 —7529
[ 9 ] 　Agarwal S , Al-Abed S R , Dionysiou D D. Environ. Sci . Technol . ,2007 , 41 (10) : 3722 —3727
[10 ] 　Patel U , Suresh S. J . Colloid Interface Sci . , 2006 , 299 (1) : 249 —259
[11 ] 　Schrick B , Blough J L , Jones A D , et al . Chem. Mater. , 2002 , 14(12) : 5140 —5147
[12 ] 　Kopinke F D , Mackenzie K, Koehler R , et al . Appl . Catal . A-Gen. , 2004 , 271 (1P2) : 119 —128
[13 ] 　Ukisu Y, Kameoka S , Miyadera T. Appl . Catal . B-Environ. ,1998 , 18 (3P4) : 273 —279
[14 ] 　Lassova L , Lee H K, Hor T S A. J . Mol . Catal . A-Chem. , 1999 ,144 (3) : 397 —403
[15 ] 　Urbano F J , Marinas J M. J . Mol . Catal . A-Chem. , 2001 , 173 (1/2) : 329 —345
[16 ] 　郭睿(Guo R) , 蔡亚歧(Cai YQ) , 江桂斌(Jiang GB) 等. 化学进展(Prog. Chem. ) , 2006 , 18 (6) : 808 —813
[17 ] 　刘汉霞(Liu H X) , 张庆华(Zhang Q H) , 江桂斌(Jiang GB) 等.化学进展(Prog. Chem. ) , 2005 , 17 (3) : 554 —562
[18 ] 　Shin E J , Spiller A , Tavoularis G, et al . Phys. Chem. Chem.Phys. , 1999 , 1 (13) : 3173 —3181
[19 ] 　Shin E J , Keane M A. Chem. Eng. Sci . , 1999 , 54 (8) : 1109 —1120
[20 ] 　Aramendia M A , Borau V , Garcia I M, et al . Appl . Catal . B-Environ. , 2003 , 43 (1) : 71 —79
[21 ] 　Moreno J M, Aramendia M A , Marinas A , et al . Appl . Catal . B-Environ. , 2007 , 76 (1P2) : 34 —41
[22 ] 　Keane M A. J . Chem. Technol . Biotechnol . , 2005 , 80 ( 11 ) :1211 —1222
[23 ] 　Heinrichs B , Delhez P , Schoebrechts J P , et al . J . Catal . , 1997 ,172 (2) : 322 —335
[24 ] 　Simagina V , Likholobov V , Bergeret G, et al . Appl . Catal . B-Environ. , 2003 , 40 (4) : 293 —304
[25 ] 　Yuan G, Keane M A. Appl . Catal . B-Environ. , 2004 , 52 (4) :301 —314
[26 ] 　Chen N , Rioux R M, Ribeiro F H. Appl . Catal . A-Gen. , 2004 ,271 (1P2) : 85 —94
[27 ] 　Ukisu Y, Kameoka S , Miyadera T. Appl . Catal . B-Environ. ,2000 , 27 (2) : 97 —104
[28 ] 　杨波(Yang B) , 余刚( Yu G) , 张祖麟(Zhang Z L) . 化学进展(Prog. Chem. ) , 2006 , 18 (1) : 87 —92
[29 ] 　Park C , Menini C , Valverde J L , et al . J . Catal . , 2002 , 211 (2) :451 —463
[30 ] 　Yuan G, Keane M A. Chem. Eng. Sci . , 2003 , 58 (2) : 257 —267
[31 ] 　Yuan G, Keane M A. Ind. Eng. Chem. Res. , 2007 , 46 (3) :705 —715
[32 ] 　De Pedro ZM, Gomez2Sainero L M, Gonzalez-Serrano E , et al . Ind.Eng. Chem. Res. , 2006 , 45 (23) : 7760 —7766
[33 ] 　Vadlamannati L S , Kovalchuk V I , dpItri J L. Catal . Lett . , 1999 ,58 (4) : 173 —178
[34 ] 　Lowry GV , Reinhard M. Environ. Sci . Technol . , 1999 , 33 (11) :1905 —1910
[35 ] 　Lowry GV , Reinhard M. Environ. Sci . Technol . , 2000 , 34 (15) :3217 —3223
[36 ] 　Nutt MO , Heck KN , Alvarez P , et al . Appl . Catal . B-Environ. ,2006 , 69 (1P2) : 115 —125
[37 ] 　Concibido N C , Okuda T, Nishijima W, et al . Appl . Catal . B-Environ. , 2007 , 71 (1P2) : 64 —69
[38 ] 　Liu Z J , Arnold R G, Betterton E A , et al . Environ. Sci .Technol . , 2001 , 35 (21) : 4320 —4326
[39 ] 　Chen G, Betterton E A , Arnold R G, et al . J . Appl .Electrochem. , 2003 , 33 (2) : 161 —169
[40 ] 　Li T, Farrell J . Environ. Sci . Technol . , 2000 , 34 (1) : 173 —179
[41 ] 　Lien H L , Zhang W X. Chemosphere , 2002 , 49 (4) : 371 —378
[42 ] 　Bransfield S J , Cwiertny D M, Roberts A L , et al . Environ. Sci .Technol . , 2006 , 40 (5) : 1485 —1490
[43 ] 　Shin E J , Keane M A. Catal . Lett . , 1999 , 58 (2P3) : 141 —145
[44 ] 　Calvo L , Gilarranz M A , Casas J A , et al . Appl . Catal . B-Environ. , 2006 , 67 (1P2) : 68 —76
[45 ] 　Vincent T, Spinelli S , Guibal E. Ind. Eng. Chem. Res. , 2003 , 42(24) : 5968 —5976
[46 ] 　Chen G, Wang Z Y, Xia D G. Electrochim. Acta , 2004 , 50 (4) :933 —937
[47 ] 　Cheng I F , Fernando Q , Korte N. Environ. Sci . Technol . , 1997 ,31 (4) : 1074 —1078
[48 ] 　Chetty R , Christensen P A , Golding B T, et al . Appl . Catal . A-Gen. , 2004 , 271 (1P2) : 185 —194
[49 ] 　Murthy KV , Patterson PM, Keane MA. J . Mol . Catal . A-Chem. ,2005 , 225 (2) : 149 —160
[50 ] 　Gopinath R , Lingaiah N , Sreedhar B , et al . Appl . Catal . B-Environ. , 2003 , 46 (3) : 587 —594
[51 ] 　Santoro D , de Jong V , Louw R. Chemosphere , 2003 , 50 ( 9) :1255 —1260
[52 ] 　Jujjuri S , Ding E , Hommel E L , et al . J . Catal . , 2006 , 239 (2) :486 —500
[53 ] 　Babu N S , Lingaiah N , Gopinath R , et al . J . Phys. Chem. C ,2007 , 111 (17) : 6447 —6453
[54 ] 　Wu W H , Xu H. Catal . Commun. , 2004 , 5 (10) : 591 —595
[55 ] 　Janiak T, Blazejowski J . Chemosphere , 2002 , 48 (10) : 1097 —1102
[56 ] 　Ukisu Y, Miyadera T. J . Mol . Catal . A2Chem. , 1997 , 125 (2P3) :135 —142
[57 ] 　Scrivanti A , Vicentini B , Beghetto V , et al . Inorg. Chem.Commun. , 1998 , 1 (7) : 246 —248
[58 ] 　Cellier P P , Spindler J F , Tailefer M, et al . Tetrahedron Lett . ,2003 , 44 (38) : 7191 —7195
[59 ] 　Tsyganok A I , Otsuka K. Appl . Catal . B-Environ. , 1999 , 22 (1) :15 —26
[60 ] 　Schuth C , Reinhard M. Appl . Catal . B-Environ. , 1998 , 18 (3P4) :215 —221
[61 ] 　Sajiki H , Kume A , Hattori K, et al . Tetrahedron Lett . , 2002 , 43(40) : 7247 —7250
[62 ] 　Zinovyev S S , Shinkova N A , Perosa A , et al . Appl . Catal . B-Environ. , 2004 , 47 (1) : 27 —36
[63 ] 　Zinovyev S S , Shinkova N A , Perosa A , et al . Appl . Catal . B-Environ. , 2005 , 55 (1) : 39 —48
[64 ] 　Gao Y, Wang F D , Liao S J , et al . React . Funct . Polym. , 2000 ,44 (1) : 65 —69
[65 ] 　Pri-Bar I , James B R. J . Mol . Catal . A-Chem. , 2007 , 264 (1P2) :135 —139
[66 ] 　Forni P , Prati L , Rossi M. Appl . Catal . B-Environ. , 1997 , 14(1/2) : 49 —53
[67 ] 　Murena F , Gioia F. Appl . Catal . B-Environ. , 2002 , 38 (1) : 39 —50
[68 ] 　Ukisu Y, Miyadera T. Appl . Catal . A-Gen. , 2004 , 271 ( 1P2) :165 —170
[69 ] 　Tsyganok A I , Yamanaka I , Otsuka K. Chemosphere , 1999 , 39(11) : 1819 —1831
[70 ] 　Yang B , Yu G, Huang J . Environ. Sci . Technol . , 2007 , 41 (21) :7503 —7508
[71 ] 　Yang B , Yu G, Shuai D M. Chemosphere , 2007 , 67 (7) : 1361 —1367
[72 ] 　Engelmann M D , Doyle J G, Cheng I F. Chemosphere , 2001 , 43(2) : 195 —198
[73 ] 　Yu H , Kennedy E M, Uddin MA , et al . Ind. Eng. Chem. Res. ,2005 , 44 (10) : 3442 —3452
[74 ] 　Morato A , Alonso C , Medina F , et al . Appl . Catal . B-Environ. ,1999 , 23 (2P3) : 175 —185
[75 ] 　Bonarowska M, Malinowski A , Juszczyk W, et al . Appl . Catal . B-Environ. , 2001 , 30 (1P2) : 187 —193
[76 ] 　Shekar S C , Rao KS R , Sahle-Demessie E. Appl . Catal . A-Gen. ,2005 , 294 (2) : 235 —243
[77 ] 　Cabot P L , Centelles M, Segarra L , et al . J . Electrochem. Soc. ,2000 , 147 (10) : 3734 —3738
[78 ] 　Keane MA. J . Chem. Technol . Biotechnol . , 2007 , 82 (9) : 787 —795
[79 ] 　Bonin P ML , Edwards P , Bejan D , et al . Chemosphere , 2005 , 58(7) : 961 —967
[80 ] 　DpArino M, Pinna F , Strukul G. Appl . Catal . B-Environ. , 2004 ,53 (3) : 161 —168
[81 ] 　Gao WL , Guan N J , Chen J X, et al . Appl . Catal . B-Environ. ,2003 , 46 (2) : 341 —351
[82 ] 　Barrabés N , Just J , Dafinov A , et al . Appl . Catal . B-Environ. ,2006 , 62 (1P2) : 77 —85
[83 ] 　Yoshinaga Y, Akita T, Mikami I , et al . J . Catal . , 2002 , 207 (1) :37 —45
[84 ] 　Garron A , Epron F. Water Res. , 2005 , 39 (13) : 3073 —3081
[85 ] 　Wang Y, Qu J H , Wu R C , et al . Water Res. , 2006 , 40 (6) :1224 —1232
[86 ] 　Novakova J . Appl . Catal . B-Environ. , 2001 , 30 (3/4) : 445 —457
[87 ] 　孟赫(Meng H) , 王树东(Wang S D) , 付桂芝(Fu G Z) 等. 环境工程(Environmental Engineering) , 2002 , 20 (2) : 37 —39
[88 ] 　Yu Z K, Liao S J , Xu Y, et al . J . Mol . Catal . A-Chem. , 1997 ,120 (1P3) : 247 —255
[89 ] 　Vincent T, Guibal E. Environ. Sci . Technol . , 2004 , 38 ( 15) :4233 —4240
[90 ] 　Selvam P , Mohapatra S K, Sonavane S U , et al . Appl . Catal . B-Environ. , 2004 , 49 (4) : 251 —255
[91 ] 　Kumbhar P S , Sanchez-Valente J , Millet J M M, et al . J . Catal . ,2000 , 191 (2) : 467 —473
[92 ] 　Rodgers J D , Bunce N J . Water Res. , 2001 , 35 (9) : 2101 —2111
[93 ] 　Li Y P , Cao H B , Liu C M, et al . J . Hazard. Mater. , 2007 , 148(1/2) : 158 —163
[94 ] 　Ribeiro M A , Sato I M, Duarte C L , et al . Radiat . Phys. Chem. ,2004 , 71 (1/2) : 423 —426
[95 ] 　Unob F , Hagege A , Lakkis D , et al . Water Res. , 2003 , 37 (9) :2113 —2117
[96 ] 　Hunsom M, Pruksathorn K, Damronglerd S , et al . Water Res. ,2005 , 39 (4) : 610 —616
[97 ] 　Bejan D , Bunce N J . J . Appl . Electrochem. , 2003 , 33 (6) : 483 —489
[98 ] 　Wang T G, Xu H B. J . Hazard. Mater. , 2005 , 123 (1P3) : 176 —180
[99 ] 　Chen C L , Wang C H , Weng H S. Chemosphere , 2004 , 56 (5) :425 —431
[100 ]  梁勇(Liang Y) , 马智(Ma Z) , 潘志爽( Pan Z S) . 工业催化( Industrial Catalysis) , 2007 , 15 (5) : 55 —59
[101 ]  Paik S C , Chung J S. Appl . Catal . B2Environ. , 1995 , 5 ( 3) :233 —243
[102 ]  Paik S C , Chung J S. Appl . Catal . B2Environ. , 1996 , 8 ( 3) :267 —279
[103 ]  Pieulle L , Morelli X, Gallice P , et al . J . Mol . Biol . , 2005 , 354(1) : 73 —90
[104 ]  Contreras R , Cuevas-2Garcia R , Ramirez J , et al . Catal . Today ,2008 , 130 (2P4) : 320 —326
[105 ]  Nelkenbaum E , Dror I , Berkowitz B. Chemosphere , 2007 , 68 (2) :210 —217
[106 ]  Yuan T, Marshall W D. J . Hazard. Mater. , 2005 , 126 ( 1P3) :149 —157
[107 ]  Yuan T, Fournier A R , Proudlock R , et al . Environ. Sci .Technol . , 2007 , 41 (6) : 1983 —1988
[1] Yong Xie, Mingjie Han, Yuhao Xu, Chenyu Xiong, Ri Wang, Shanhong Xia. Inner Filter Effect for Environmental Monitoring [J]. Progress in Chemistry, 2021, 33(8): 1450-1460.
[2] Anrui Zhang, Yuejie Ai. Structure Control of Covalent Organic Frameworks(COFs) and Their Applications in Environmental Chemistry [J]. Progress in Chemistry, 2020, 32(10): 1564-1581.
[3] Li Huaijian Li Qiang Wang Wu Zhang Hongwei Li Li. 3-Nitrobenzanthrone in Environment [J]. Progress in Chemistry, 2010, 22(01): 220-224.
[4] Wang Yuan Zhang Pengyi. Human Exposure Pathways and Pollution Control Technology of Perfluorooctanoic Acid (PFOA) and Perfluorooctanyl Sulfonate (PFOS) [J]. Progress in Chemistry, 2010, 22(01): 210-219.
[5] . Freely Dissolved Concentration and Bioavailability of Environmental Pollutants [J]. Progress in Chemistry, 2009, 21(0203): 514-523.
[6] . Advances in the Determination of Environmental Pollutants by Immunosensors [J]. Progress in Chemistry, 2009, 21(0203): 492-502.