中文
Announcement
More
Progress in Chemistry 2009, Vol. 21 Issue (01): 121-127 Previous Articles   Next Articles

• Review •

Synthesis of Porous TiO2 Films by Anodic Oxidation

Chen Guohua;Zhao Fengming**   

  1. (Department of Applied Chemistry, Zhejiang University of Technology, Hangzhou 310014, China)
  • Received: Revised: Online: Published:
  • Contact: Zhao Fengming E-mail:zhaofm@zjut.edu.cn
PDF ( 1957 ) Cited
Export

EndNote

Ris

BibTeX

The various types of processes for synthesis of TiO2 films are discussed and evaluated respectively. The method of anodic oxidation is presented particularly in the aspects of the current development of the formation mechanism, the materials category and the affecting factors. The anodic oxidation has advantages over the other methods. Without the addition of fluoride, the pores are formed randomly and show no clear organization. With the addition of fluoride, self-organized nano-porous structure is produced and an ordered TiO2 nano-tube arrays is revealed. Furthermore, its simplicity and lower cost make it the promising anodic preparation in large production of porous TiO2 films.

Contents
1 Introduction
2 Synthetic methods of TiO2 films
3 TiO2 porous materials by anodic oxidation
3.1 Mechanism of TiO2 porous films by anodic oxidation
3.2 Synthesis of TiO2 porous films in different electrolyte
3.3 Effect of anodic voltage for synthesis of TiO2 porous films
4 Summary and expectation

CLC Number: 

[ 1 ]  Gratzel M. Nature , 2001 , 414 : 338 —241
[ 2 ]  Pfaff G, Reynders P. Chem. Rev. , 1999 , 99 : 1963 —1977
[ 3 ]  Trapalis C C , Keivanidis P , Kordas G, et al . Thin Solid Films ,2003 , 433 (1/2) : 186 —192
[ 4 ]  Chen X B , Mao S S. Chem. Rev. , 2007 , 107 : 2891 —2959
[ 5 ]  Assen A. Mater. Chem. Phy. , 2002 , 76 : 274 —278
[ 6 ]  Yakovleva N M, Anicai L , Yakovlev A N , et al . Thin Solid Films ,2002 , 416 : 16 —23
[ 7 ]  Su Y C , Cui B Z, Martínez L , et al . Thin Solid Films , 2002 , 406 :64 —69
[ 8 ]  周圆( Zhou Y) , 李长虹(Li C H) . 电镀与精饰( Plating and Finishing) , 2007 , 29 (3) : 23 —26
[ 9 ]  姜妍彦(Jiang Y Y) , 钟萍(Zhong P) , 王承遇(Wang C Y) 等. 材料导报(Materials Review) , 2000 , 14 (6) : 38 —40
[10 ]  Piveteau I D , Girona M I , Achlapbach L. J . Mater. Sci . Mater.Med. , 1999 , 10 : 161 —167
[11 ]  Varghese O K, Gong D W, Paulose M, et al . Sensors and Actuators B : Chemical , 2003 , 93 : 338 —344
[12 ]  Prida V M, Hernandez V M, Cerverac M, et al . J . Magnetism and Magnetic Materials , 2005 , 294 : e69 —e72
[13 ]  Kim D S , Han S J , Kwak S Y. J . Colloid and Interface Science ,2007 , 316 : 85 —91
[14 ]  Pourmanda M, Taghavinia N. Materials Chemistry and Physics ,2008 , 107 : 449 —455
[15 ]  Shindea P S , Sadalec S B , Patilb P S , et al . Solar Energy Materials&Solar Cells , 2008 , 92 : 283 —290
[16 ]  Toku H , Pesso R S , Maciel H S , et al . Surface & Coatings Technology , 2008 , 202 : 2126 —2131.
[17 ]  Maekawa T, Kurosaki K, Tanaka T, et al . Surface & Coatings Technology , 2007 , 202 (13) : 3067 —3071
[18 ]  Radice S , Kerna P , Dietschb H , et al . J . Colloid and Interface Science , 2008 , 318 : 264 —270
[19 ]  Kern P , Schwaller P , Michler J . Thin Solid Films , 2006 , 494 :279 —286
[20 ]  Zwilling V. Surf . Interface Anal . , 1999 , 27 : 629 —637
[21 ]  王炜(Wang W) , 陶杰(Tao J ) , 章伟伟(Zhang WW) 等. 钛工业进展(Titanium Industry Progress) , 2005 , 22 (2) : 30 —33
[22 ]  王周成(Wang Z C) , 黄龙门(Wang L M) , 唐毅(Tang Y) . 厦门大学学报(自然科学版) ( Journal of Xiamen University (Natural Science) ) , 2006 , 45 (5) : 677 —682
[23 ]  田甜(Tian T) , 肖秀峰(Xiao X F) , 刘榕芳(Liu R F) . 传感技术学报(Chinese Journal of Sensors and Actuators) , 2006 , 19 (5) :2310 —2313
[24 ]  李贺(Li H) , 姚素微(Yao S W) , 张卫国(Zhang W G) 等. 无机材料学报(Journal of Inorganic Materials) , 2007 , 22 (2) : 349 —353
[25 ]  Jaeggi C , Kern P , Michler J , et al . Surface &Coatings Technology ,2005 , 200 : 1913 —1919.
[26 ]  Yang C L , Chen F L. Materials Chemistry and Physics , 2006 , 100 :268 —274
[27 ]  Capek D , Gigandet M P , Masmoudi M, et al . Surface & Coatings Technology , 2008 , 202 : 1379 —1384
[28 ]  Schweinsberg M, Kudelka S , Michaelis A , et al . Materials and Corrosion , 1998 , 49 : 161 —168
[29 ]  Wang S , Wu X H , Qin W, et al . Materials Letters , 2008 , 62 :1078 —1081
[30 ]  Aikaterini G M, Mamas I P. Electroanalysis , 2005 , 17 ( 20 ) :1878 —1885
[31 ]  Brunella M F , Diamanti M V , Pedeferri M P. Thin Solid Films ,2007 , 515 : 6309 —6313
[32 ]  Iwata T, Ishikawa M, Ichino R , et al . Surface and Coatings Technology , 2003 , 169P170 : 703 —706
[33 ]  Das K, Bose S , Bandyopadhyay A. Acta Biomaterialia , 2007 , 3 :573 —585
[34 ]  Velten D , Biehl V , Aubertin F , et al . J . Biomed. Mater. Res. ,2002 , 59 : 18 —28
[35 ]  Zorn G, Lesman A , Gotman I. Surface & Coatings Technology ,2006 , 201 : 612 —618
[36 ]  Onoda K, Yoshikawa S. Applied Catalysis B : Environmental , 2008 ,89 : 277 —285
[37 ]  Onoda K, Yoshikawa S. J . Solid State Chemistry , 2007 , 180 :3425 —3433
[38 ]  Onoda K, Yoshikawa S. Ceramics International , 2008 , 34 : 1453 —1457
[39 ]  Oh H J , Lee J H , Kimc Y J . Materials Chemistry and Physics ,2008 , 109 (1) : 10 —14
[40 ]  Aggour M, Dittrich T, Belaidi A , et al . Phys. Stat . Sol . , 2005 , 2 (9) : 3344 —3348
[41 ]  Crawford GA , Chawla N , Das K, et al . Acta Biomaterialia , 2007 ,3 : 359 —367
[42 ]  Paramasivam I , Macak J M, Ghicov A , et al . Chemical Physics Letters , 2007 , 445 (4P6) : 233 —237
[43 ]  Tsuchiya H , Macak J M, Muller L , et al . J . Biomed. Mater. Res. ,2006 , 77A: 534 —541
[44 ]  Vitiello R P , Macak J M, Ghicov A , et al . Electrochem. Commun. ,2006 , 8 : 544 —548
[45 ]  Macak J M, Tsuchiya H , Berger S , et al . Chemical Physics Letters ,2006 , 428 : 421 —425
[46 ]  Macak J M, Barczuk P J , Tsuchiya H , et al . Electrochem.Commun. , 2005 , 7 : 1417 —1422
[47 ]  Tsuchiya H , Macak J M, Ghicov A , et al . Corrosion Science , 2005 ,47 : 3324 —3335
[48 ]  Macak J M, Stein F S , Schmuki P. Electrochem. Commun. , 2007 ,9 : 1783 —1787
[49 ]  Park Y J , Shin K H , Song H J . Applied Surface Science , 2007 ,253 : 6013 —6018
[50 ]  Das K, Bose S , Bandyopadhyay A. Acta Biomaterialia , 2007 , 3 :573 —585
[51 ]  Baea S , Shimb E , Yoon J . Solar Energy Materials & Solar Cells ,2008 , 92 : 402 —409
[52 ]  Raja K S , Mahajan V K, Misra M. J . Power Sources , 2006 , 159 :1258 —1265
[53 ]  Raja K S , Misra M, Mahajan V K. J . Power Sources , 2006 , 161 :1450 —1457
[54 ]  Bauer S , Kleber S , Schmuki P. Electrochem. Commun. , 2006 , 8 :1321 —1325
[55 ]  Ghicov A , Tsuchiya H , Macak J M. Electrochem. Commun. , 2005 ,7 : 505 —509
[56 ]  Yang Y, Wang X H , Li L T. Materials Science and Engineering B ,2008 , 149 (1) : 58 —62
[57 ]  Kang S H , Kim. Y, Kim H S. J . Industrial and Engineering Chemistry , 2008 , 14 : 52 —59
[58 ]  Mato S , Alcal G, Skeldon P , Thompson G E. Surf . Interface Anal . ,2003 , 35 : 477 —482
[59 ]  Habazaki H , Uozumi M, Konno H , et al . Electrochim. Acta , 2003 ,48 : 3257 —3266
[60 ]  Ruan C , Paulose M, Varghese O K. Solar Energy Materials & Solar Cells , 2006 , 90 : 1283 —1295
[61 ]  Si H Y, Sun Z H , Zhang H L. Colloids and Surfaces A:Physicochem. Eng. Aspects , 2008 , 313P314 : 604 —607
[62 ]  Balasundaram G, Yao C , Webster T J . J . Biomed Mater. Res. ,2008 , 84A: 447 —453
[63 ]  Oh S , Daraio C , Chen L H. J . Biomed Mater. Res. , 2006 , 78A:97 —103
[64 ]  Zhang Z H , Yuan Y, Fa Y. J . Electroanal . Chem. , 2007 , 610 :179 —185
[65 ]  Arakelyan V M, Aroutiounian V M, Shahnazaryan G E , et al .Renewable Energy , 2008 , 33 : 299 —303
[66 ]  Chen X B , Schriver M, Suen T. Thin Solid Films , 2007 , 515 :8511 —8514
[67 ]  Hahn R , Macak J M, Schmuki P. Electrochem. Commun. , 2007 ,9 : 947 —952
[68 ]  Zwilling V , Ceretti E D , Forveille A B. Surf . Interface Anal . ,1999 , 27 : 629 —637
[69 ]  Zwilling V , Aucouturier M, Ceretti E D. Electrochim. Acta , 1999 ,45 : 921 —925
[70 ]  Chenga F T, Shia P G, Pang K H , et al . J . Alloys and Compounds ,2007 , 438 : 238 —242
[71 ]  Tsuchiya H , Macak J M, Taveira L , et al . Electrochem. Commun. ,2005 , 7 : 576 —580
[72 ]  Su Y, Zhang X W, Han S , et al . Electrochem. Commun. , 2007 ,9 : 2291 —2298
[73 ]  Su YL , Zhang XW, Zhou M H. J . Photochemistry and Photobiology A: Chemistry , 2007 , 185 (2P3) : 338 —344
[74 ]  Lei L , Su YL , Zhou M H. Materials Research Bulletin , 2007 , 42 :2230 —2236
[75 ]  Zhang H , Zhao H J , Zhang S. Chem. Phys. , 2008 , 9 : 117 —123
[76 ]  Mohapatra S K, Raja K S , Misra M, et al . Electrochimica Acta ,2007 , 53 : 590 —597
[77 ]  Zhang G, Huang H T, Zhang Y, Electrochem. Commun. , 2007 , 9 :2854 —2858
[78 ]  Raja K S , Gandhi T, Misra M. Electrochem. Commun. , 2007 , 9 :1069 —1076
[79 ]  Yang D J , Kim H G, Cho S J , et al . Materials Letters , 2008 , 62 :775 —779
[80 ]  Macak J M, Albu S P , Schmuki P. Phys. Stat . sol . , 2007 , 1 (5) :181 —183
[81 ]  Zlamal M, Macak J M, Schmuki P. Electrochem. Commun. , 2007 ,9 : 2822 —2826
[82 ]  Tsuchiya H , Berger S , Macak J M, et al . Electrochem. Commun. ,2007 , 9 : 545 —550
[83 ]  Macak J M, Tsuchiya H , Ghicov A. Electrochem. Commun. , 2005 ,7 : 1133 —1137
[84 ]  Hahn R , Stergiopoulus T, Macak J M. Phys. Stat . Sol . , 2007 , 1 (4) : 135 —137
[85 ]  Yu X F , Li YX, Wlodarski W. Sensors and Actuators B , 2007 , 127 (1) : 168 —178
[86 ]  Cai Q Y, Yang L X, Yu Y. Thin Solid Films , 2006 , 515 : 1802 —1806
[87 ]  Macak J M, Hildebrand H , Jahns U M. J . Electroanalytical Chemistry , 2008 , 621 (2) : 254 —266
[88 ]  Tsuchiya H , Macaka J M, Ghicov A. Electrochim. Acta , 2006 , 52 :94 —101
[89 ]  Ghicov A , Macak J M, Tsuchiya H , et al . Chem. Phy. Lett . ,2006 , 419 : 426 —429
[90 ]  Ghicov A , Tsuchiya H , Hahn R , et al . Electrochem. Commun. ,2006 , 8 : 528 —532
[91 ]  Macak J M, Schmuki P. Electrochim. Acta , 2006 , 52 : 1258 —1264
[92 ]  Macak J M, Sirotnal K, Schmuki P. Electrochim. Acta , 2005 , 50 :3679 —3684
[93 ]  Fini M, Cigada A , Rondelli G, et al . Biomaterials , 1999 , 20 :1587 —1594
[94 ]  Chenga F T, Shia T P , Man H C. Mater. Lett . , 2005 , 59 : 1516 —1520
[95 ]  Habazaki H , Oikawa Y, Fushimi K, et al . Electrochim. Acta ,2007 , 53 : 1775 —1781
[96 ]  Paramasivam I , Macak J M, Schmuki P , Electrochem. Commun. ,2008 , 10 : 71 —75
[97 ]  Macak J M, Aldabergerova S , Ghicov A. Phys. Stat . Sol . , 2006 ,203 (10) : R67 —R69
[98 ]  Albu S P , Ghicov A , Macak J M, et al . Phys. Stat . Sol . , 2007 , 1 (2) : R65 —R67
[99 ]  Huang H H , Pan S J , Lai Y L , et al . Scripta Materialia , 2004 , 51 :1017 —1021
[100 ]  Eswaramoorthi I , Hwang L P. Diamond & Related Materials , 2007 ,16 : 1571 —1578

[1] Shuaibing Yu, Zhaolu Wang, Xuliang Pang, Lei Wang, Lianzhi Li, Yingwu Lin. Peptide-Based Metal Ion Sensors [J]. Progress in Chemistry, 2021, 33(3): 380-393.
[2] Xin Ni, Yang Zhou, Ruiqin Tan, Yongbo Kuang. Fabrication and Modification of Ferrite Photocathodes for Photoelectrochemical Water Splitting [J]. Progress in Chemistry, 2020, 32(10): 1515-1534.
[3] Yukun Zhao, Yuanyuan Wang, Hongwei Ji, Wanhong Ma, Chuncheng Chen*, Jincai Zhao*. Photocatalytic Reductive Debromination of Polybrominated Diphenyl Ethers [J]. Progress in Chemistry, 2017, 29(9): 911-918.
[4] Zhang He, Zhang Chi, Song Ye. Fabrication of Anodic Titania Nanotube Arrays with Tunable Morphologies [J]. Progress in Chemistry, 2016, 28(6): 773-783.
[5] Wang Jing, Fan Haowen, Zhang He, Chen Qun, Liu Yi, Ma Weihua. Anodizing Process of Titanium and Formation Mechanism of Anodic TiO2 Nanotubes [J]. Progress in Chemistry, 2016, 28(2/3): 284-295.
[6] Zhang Lingfeng, Hu Zhongpan, Liu Xinying, Yuan Zhongyong. Noble-Metal-Free Co-Catalysts for TiO2-Based Photocatalytic H2-Evolution Half Reaction in Water Splitting [J]. Progress in Chemistry, 2016, 28(10): 1474-1488.
[7] Zhang Xiaodong, Yang Yang, Li Hongxin, Zou Xuejun, Wang Yuxin. Non-TiO2 Photocatalysts Used for Degradation of Gaseous VOCs [J]. Progress in Chemistry, 2016, 28(10): 1550-1559.
[8] Xie Yingjuan, Wu Zhijiao, Zhang Xiao, Ma Peijun, Piao Lingyu. Synthesis and Photocatalytic Mechanisms of the Mixed-Phase TiO2 Photocatalysts [J]. Progress in Chemistry, 2014, 26(07): 1120-1131.
[9] Jin Chao, Qin Yao, Yang Jinhu. Novel Non-TiO2 Semiconductor Photocatalysts [J]. Progress in Chemistry, 2014, 26(0203): 225-233.
[10] Hu Jinlin, Yang Qihao, Chen Jing, Wang Taiya, Lin He, Qian Haisheng. Synthesis and Applications of Mesoporous TiO2 Functional Nanomaterials [J]. Progress in Chemistry, 2013, 25(12): 2080-2092.
[11] Wang Yajun, Jiang Lijuan, Feng Changgen. Photocatalytic Reduction of Cr(Ⅵ) [J]. Progress in Chemistry, 2013, 25(12): 1999-2010.
[12] Song Yingpan, Feng Miao, Zhan Hongbing*. Application of Graphene Edge Effect in Electrochemical Biosensors [J]. Progress in Chemistry, 2013, 25(05): 698-706.
[13] Li Jing, Yang Xiaoying*. Applications of Novel Carbon Nanomaterials——Graphene and Its Derivatives in Biosensing [J]. Progress in Chemistry, 2013, 25(0203): 380-396.
[14] Qian Dongjin*, Fu Yanrong. Interfacial Self-Assembly of Viologen-Functionalized Ultrathin Films and Molecular Aggregates [J]. Progress in Chemistry, 2013, 25(01): 46-53.
[15] Wen Yanli, Lin Meihua, Pei Hao, Lu Na, Fan Chunhai. Electrochemical-Based MicroRNA Sensors [J]. Progress in Chemistry, 2012, (9): 1656-1664.