中文
Announcement
More
Progress in Chemistry 2009, Vol. 21 Issue (01): 106-115 Previous Articles   Next Articles

• Review •

Photo-Driven Molecular Shuttles

Ms Xiang;Wang Qiaochun;Tian He**   

  1. (Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science & Technology, Shanghai 200237, China)
  • Received: Revised: Online: Published:
  • Contact: Tian He E-mail:tianhe@ecust.edu.cn
PDF ( 2982 ) Cited
Export

EndNote

Ris

BibTeX

Molecular shuttle, as a formidable challenge to construct motors and machines of nano-size dimension, have potential applications in areas such as nano-structured functional materials, molecular switches, molecular logic gates, memory devices, and so on. In this paper, the progress in photo-driven molecular shuttles is introduced. Co-conformational identifications of molecular shuttles, like using fluorescence spectra and circular dichroism spectra are mainly generalized. The methodology to construct novel photo-driven molecular shuttles, like the unidirectional synthesis of cyclodextrin [2]rotaxane and [1]rotaxane, rotaxane shuttles driven by light indirectly, [3]rotaxane shuttle and polyrotaxane, is elaborated. The potential functionality of molecular machine in such areas as molecular logic gates, the energy transfer of molecular shuttles, and the properties of molecular shuttles in non-solution media are reviewed, and the future development of molecular machine is prospected.

Contents
1 Introduction
2 Process in photo-driven molecular shuttles
2.1 Co-conformational identification of photo-driven molecular shuttles
2.2 Novel methodology to construct photo-driven rotaxane shuttles
2.3 Functionality of photo-driven molecular shuttles
3 Prospect

CLC Number: 

[ 1 ]  Balzani V , Venturi M, Credi A. Molecular Devices and Machines.Weinheim: Wiley2VCH , 2003
[ 2 ]  Tian H , Wang Q C. Chem. Soc. Rev. , 2006 , 35 : 361 —374
[ 3 ]  Kay E R , Leigh D A , Zerbetto F. Angew. Chem. Int . Ed. , 2007 ,46 : 72 —191
[ 4 ]  Balzani V , Credi A , Silvi S , Venturi M. Chem. Soc. Rev. , 2006 ,35 : 1135 —1149
[ 5 ]  Sindelar V , Silvi S , Kaifer A E. Chem. Commun. , 2006 , 2185 —2187
[ 6 ]  Sauvage J P. Chem. Commun. , 2005 , 1507 —1510
[ 7 ]  Wenz G, Han B H , Müller A. Chem. Rev. , 2006 , 106 : 782 —817
[ 8 ]  Credi A , Tian H. Adv. Funct . Mater. , 2007 , 17 : 679 —682
[ 9 ]  Liu Y, Ke C F , Zhang H Y, Wu W J , Shi J . J . Org. Chem. ,2007 , 72 : 280 —283
[10 ]  Shao X B , Jiang X K, Zhao X, Zhao C X, Chen Y, Li Z T. J .Org. Chem. , 2004 , 69 : 899 —907
[11 ]  Marlin D S , Cabrera D G, Leigh D A , Slawin A M Z. Angew.Chem. Int . Ed. , 2006 , 45 : 1385 —1390
[12 ]  Zhang C , Li S , Zhang J , Zhu K, Li N , Huang F. Org. Lett . ,2007 , 9 : 5553 —5556
[13 ]  Letinois-Halbes U , Hanss D , Beierle J M, Collin J P , Sauvage J P.Org. Lett . , 2005 , 7 : 5753 —5756
[14 ]  Jeppesen J O , Becher J , Stoddar J F. Org. Lett . , 2002 , 4 : 557 —560
[15 ]  Sauvage J P. Chem. Commun. , 2005 , 1507 —1510
[16 ]  Balzani V , Credi A , Mattersteig G, Matthews O A , Raymo F M,Stoddart J F , Venturi M, White A J P , Williams D J . J . Org.Chem. , 2000 , 65 : 1924 —1936
[17 ]  Stanier C A , Alderman S J , Claridge T D W, Anderson H L.Angew. Chem. Int . Ed. , 2002 , 41 : 1769 —1772
[18 ]  Li YJ , Li H , Li YL , Liu H B , Wang S , He X R , Wang N , Zhu D B. Org. Lett . , 2005 , 7 : 4835 —4838
[19 ]  Bottari G, Dehez F , Leigh D A , Nash P J , Pérez E M, Wong J K Y, Zerbetto F. Angew. Chem. Int . Ed. , 2003 , 42 : 5886 —5889
[20 ]  Laursen B W, Nygaard S , Jeppesen J O , Stoddart J F. Org. Letts. ,2004 , 6 : 4167 —4170
[21 ]  Ong W, Gómez-Kaifer M, Kaifer A E. Org. Lett . , 2002 , 4 :1791 —1794
[22 ]  Wurpel G W H , Brouwer A M, van Stokkum I H M, Farran A ,Leigh D A. J . Am. Chem. Soc. , 2001 , 123 : 11327 —11328
[23 ]  Grubert L , Jacobi D , Buck K, Abraham W, Mügge C , Krause E.Eur. J . Org. Chem. , 2001 , 20 : 3921 —3932
[24 ]  Iijima T, Vignon S A , Tseng H R , Jarrosson T, Sanders J K M,Marchioni F , Venturi M, Apostoli E , Balzani V , Stoddart J F.Chem. Eur. J . , 2004 , 10 : 6375 —6392
[25 ]  Poleschak I , Kern J M, Sauvage J P. Chem. Commun. , 2004 ,474 —476
[26 ]  Altieri A , Gatti F G, Kay E R , Leigh D A , Martel D , Paolucci F ,Slawin A M Z, Wong J K Y. J . Am. Chem. Soc. , 2003 , 125 :8644 —8654
[27 ]  Bottari G, Leigh D A , Perez E M. J . Am. Chem. Soc. , 2003 ,125 : 13360 —13361
[28 ]  Wang Q C , Qu D H , Ren J , Chen K, Tian H. Angew. Chem. Int .Ed. , 2004 , 43 : 2661 —2665
[29 ]  Pérez E M, Dryden D T F , Leigh D A , Teobaldi G, Zerbetto F. J .Am. Chem. Soc. , 2004 , 126 : 12210 —12211
[30 ]  Qu D H , Wang Q C , Ren J , Tian H. Org. Lett . , 2004 , 6 : 2085 —2088
[31 ]  Ma X, Wang Q C , Qu D H , Xu Y, Ji F Y, Tian H. Adv. Funct .Mater. , 2007 , 17 : 829 —837
[32 ]  Bottari G, Leigh D A , Pérez E M. J . Am. Chem. Soc. , 2003 ,125 : 13360 —13361
[33 ]  Wang Q C , Ma X, Qu D H , Tian H. Chem. Eur. J . , 2006 , 12 :1088 —1096
[34 ]  Ma X, Qu D H , Ji F Y, Wang Q C , Zhu L L , Xu Y, Tian H.Chem. Commun. , 2007 , 14 : 1409 —1411
[35 ]  Ma X, Wang Q C , Tian H. Tetrahedron Letters , 2007 , 48 : 7112 —7116
[36 ]  Saha S , Flood A H , Stoddart J F , Impellizzeri S , Silvi S , Venturi M, Credi A. J . Am. Chem. Soc. , 2007 , 129 : 12159 —12171
[37 ]  Zhou WD , Chen D G, Li J B , Xu J L , LüJ , Liu H B , Li YL.Org. Lett . , 2007 , 9 : 3929 —3932
[38 ]  Qu D H , Wang Q C , Ma X, Tian H. Chem. Eur. J . , 2005 , 11 :5929 —5937
[39 ]  Michels J J , O’Connell MJ , Taylor P N , Wilson J S , Cacialli F ,Anderson H L. Chem. Eur. J . , 2003 , 9 : 6167 —6176
[40 ]  Sardone L , Williams C C , Anderson H L , Marletta G, Cacialli F ,SamorìP. Adv. Funct . Mater. , 2007 , 17 : 927 —932
[41 ]  Peasw A R , Jeppesen J O , Stoddart J F , Luo Y, Collier C P , Heath J R. Acc. Chem. Res. , 2001 , 34 : 433 —444
[42 ]  Ball P. Nature , 2000 , 406 : 118 —120
[43 ]  Qu D H , Wang Q C , Tian H. Angew. Chem. Int . Ed. , 2005 , 44 :5296 —5299
[44 ]  Qu D H , Ji F Y, Wang Q C , Tian H. Adv. Mater. , 2006 , 18 :2035 —2038
[45 ]  Serreli V , Lee C F , Kay E R , Leigh D A. Nature , 2007 , 45 :523 —527
[46 ]  Leigh D A , Morales M F , Pérez E M, Wong J K Y, Saiz C G,Slawin A M Z, Carmichael AJ , Haddleton D M, Brouwer A M, Jan Buma W, Wurpel GW H , León S , Zerbetto F. Angew. Chem. Int .Ed. , 2005 , 44 : 3062 —3069
[47 ]  Collier C P , Mattersteig G, Wong EW, Lou Y, Beverly K, Sampaio K, Raymo F M, Stoddart J F , Heath J R. Science , 2000 , 289 :1172 —1175
[48 ]  Wong E W, Collier C P , Behloradsk?M, Raymo FM, Stoddart J F ,Heath J R. J . Am. Chem. Soc. , 2000 , 122 : 5831 —5840
[49 ]  Stewart D , Ohlberg D A A , Beck P A , Chen Y, Williams R S ,Jeppesen J O , Nielsen K A , Stoddart J F. Nano Lett . , 2004 , 4 :133 —136
[50 ]  Katz E , Lioubashevsky O , Willner I. J . Am. Chem. Soc. , 2004 ,126 : 15520 —15532
[51 ]  Cavallini M, Biscarni F , León S , Zerbetto F , Bottari G, Leigh D A.Science , 2003 , 299 : 531 —531
[52 ]  Feng M, Guo X F , Lin X, He X B , Ji W, Du S X, Zhang D Q ,Zhu D B , Gao H J . J . Am. Chem. Soc. , 2005 , 127 :15338 —15339
[53 ]  Saha S , Leung K C F , Nguyen T D , Stoddart J F , Zink J I. Adv.Funct . Mater. , 2007 , 17 : 685 —693
[54 ]  Berna J , Leigh D A , Lubomska M, Mendoza S M, Perez E M,Rudolf P , Teobaldi G, Zerbetto F. Nature Mat . , 2005 , 4 :704 —710
[55 ]  Zhu L L , Ma X, Ji F Y, Wang Q C , Tian H. Chem. Eur. J . ,2007 , 13 : 9216 —9222
[56 ]  Liu Y, Yu L , Chen Y, Zhao YL , Yang H. J . Am. Chem. Soc. ,2007 , 129 : 10656 —10657
[57 ]  Hwang I , Baek K, Jung M, Kim Y, Park K M, Lee D W,Selvapalam N , Kim K. J . Am. Chem. Soc. , 2007 , 129 :4170 —4171

[1] Xu Guohe, Li Jie, Deng Jinni, Yin Lv, Zheng Zhaohui, Ding Xiaobin. Molecular Shuttles Based on Host-Guest Recognition Driven by External-Stimuli [J]. Progress in Chemistry, 2015, 27(12): 1732-1742.
[2] Yang Zaiwen, Liu Xiangrong, Zhao Shunsheng, He Jinmei. Chemically Driven [2] Rotaxane Molecular Shuttles [J]. Progress in Chemistry, 2014, 26(12): 1899-1913.
Viewed
Full text


Abstract

Photo-Driven Molecular Shuttles