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Progress in Chemistry 2008, Vol. 20 Issue (12): 1980-1986 Previous Articles   Next Articles

• Review •

Amphiphilic Dendritic Polymer

Su Jing; Zhang Ling**; Wu Qing**

  

  1. ( Institute of Polymer Science, Sun Yat-Sen University, Guangzhou 510275, China)
  • Received: Revised: Online: Published:
  • Contact: Zhang Ling; Wu Qing
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Recently, the research of dendritic polymers and their functionalization is one of the most considerable interest in the field of polymer science. The review deals with different dendritic polymers which are polyesters, polyglycerol, polyethylenimine hyperbranched polymers, poly(amidoamine), poly(propyleneimine) dendrimers. Amphiphilic dendritic polymers have been prepared via hydrophobic (hydrophilic) modification of a large number of reactive terminal groups of those dendritic polymers，and the methods of modification include amidation, esterification, Michael addition reaction and so on. Different from those dendritic polymers prepared via polycondensation, dendritic polyethylene have been obtained by “chain-walking” mechanism of coordination polymerization, which has attracted increasing attention. In this regard, amphiphilic dendritic polyethylene have been synthesized by copolymerizing ethylene with a comonomer or by tandem chain walking polymerization and atom transfer radical polymerization. Furthermore, the possible topics of amphiphilic dendritic polymer in the future investigation are discussed.
Key words: amphiphilic dendritic polymers, functionalization, unimolecular micelles, controlled synthesis

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Abstract

Amphiphilic Dendritic Polymer